2-(3-苯甲酰基苯氧基)乙酸 | 76981-43-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-(3-苯甲酰基苯氧基)乙酸
• 英文名称: (3-Benzoyl-phenoxy)-acetic acid
• 英文别名: 2-(3-benzoylphenoxy)acetic acid
• CAS: 76981-43-6
• 化学式: C₁₅H₁₂O₄
• 分子量: 256.258
• InChiKey: CHEIRSAFNUUELX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  (3-Benzoyl-phenoxy)-acetic acid ethyl ester 在 水 、 sodium carbonate 作用下， 以 乙醇 为溶剂， 以88%的产率得到2-(3-苯甲酰基苯氧基)乙酸
  参考文献：
  名称：

  Astoin; Lepage; Fromantin, European Journal of Medicinal Chemistry, 1980, vol. 15, # 5, p. 457 - 462

  摘要：

  DOI：

文献信息

• [EN] SILSESQUIOXANE PHOTOINITIATORS<br/>[FR] PHOTO-INITIATEURS SILSESQUIOXANES
  申请人：BASF SE

  公开号：WO2010063612A1

  公开（公告）日：2010-06-10

  Photoinitiator compounds comprising both a photoactive moiety and an amine functionality, bonded to a polyhedral oligomeric silsesquioxane, which photoinitiator is represented by formula (1) or (1') wherein n is 2m; m is an integer of 2 to 30; the sum of n' + a is an integer 4-60; n' is an even-numbered integer; a is an even-or uneven-numbered integer; and for example different A C1-C12alkyl, or a photoactive moiety Q1, or a group of formula (2); E for example is a direct bond, L is linear or branched C1-C3alkylene, preferably propylene; R1 and R2 for example are a photoactive moiety Q, or C2-20alkyl; Q is for example a group of formula (4); Z2 is for example C1-C6alkylene which is unsubstituted or substituted by one or more OR6; and R6, R12, R13 and R14 for example are hydrogen; are especially suitable as low-migrating photoinitiators.

  具有光活性基团和胺基官能团的光引发剂化合物，与多面体寡聚硅氧烷结合，该光引发剂由公式（1）或（1'）表示，其中n为2m；m为2至30的整数；n'+a的总和为4-60的整数；n'为偶数整数；a为偶数或奇数整数；例如不同的A C1-C12烷基，或光活性基团Q1，或公式（2）的基团；例如E为直接键，L为线性或支链C1-C3烷基，优选丙烯基；例如R1和R2为光活性基团Q，或C2-20烷基；例如Q为公式（4）的基团；例如Z2为未取代或取代一个或多个OR6的C1-C6烷基；例如R6、R12、R13和R14为氢；特别适用于低迁移光引发剂。
• ASTOIN J.; LEPAGE F.; FROMANTIN J.-P.; POISSON M., EUR. J. MED. CHEM.-CHIM. THER., 1980, 15, NO 5, 457-462
  作者：ASTOIN J.、 LEPAGE F.、 FROMANTIN J.-P.、 POISSON M.

  DOI：——

  日期：——
• BLUE COLOUR FILTERS WITH ENHANCED CONTRAST
  申请人：BASF SE

  公开号：EP1984457B1

  公开（公告）日：2013-01-09
• METHOD FOR MANUFACTURING SECURITY ELEMENTS AND HOLOGRAMS
  申请人：BASF SE

  公开号：US20170028764A1

  公开（公告）日：2017-02-02

  The present invention relates to a method for forming a surface relief microstructure, especially an optically variable image (an optically variable device) on a transparent or translucent substrate and a product obtainable using the method. A further aspect of the invention is the use for the prevention of counterfeit or reproduction of a document of value and a method of forming a coating showing an angle dependent color change.
• [EN] WATER SOLUBLE PHOTOINITIATOR<br/>[FR] PHOTOINITIATEUR SOLUBLE DANS L'EAU
  申请人：ALBEMARLE CORP

  公开号：WO2007044184A1

  公开（公告）日：2007-04-19

  [EN] This invention provides both metal carboxylates and tertiary ammonium carboxylates, in which carboxylates a benzoylphenyl group is present. Also provided are photoinitiator compositions which comprise a) (i) at least one metal carboxylate, in which carboxylate a benzoylphenyl group is present, and/or (ii) at least one tertiary ammonium carboxylate, in which carboxylate a benzoylphenyl group is present; and b) at least one coinitiator comprising at least one benzoyl moiety and at least one aliphatic alcohol moiety. Processes for photopolymerization with these photoinitiator compositions are also provided.
  [FR] Cette invention concerne à la fois des carboxylates de métaux et des carboxylates d'ammonium tertiaire, lesquels carboxylates comprennent un groupe benzoylphényle. L'invention concerne également des compositions de photoinitiateur qui comprennent a) (i) au moins un carboxylate de métal, lequel carboxylate comprend un groupe benzoylphényle, et/ou (ii) au moins un carboxylate d'ammonium tertiaire, lequel carboxylate comprend un groupe benzoylphényle ; et b) au moins un co-initiateur comprenant au moins une entité benzoyle et au moins une entité alcool aliphatique. L'invention concerne également des procédés pour la photopolymérisation avec ces compositions de photoinitiateur.