tris(hexafluoroacetylacetonato)(1,3-propylenebis(diphenylphosphine oxide))europium(III) | 676251-07-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris(hexafluoroacetylacetonato)(1,3-propylenebis(diphenylphosphine oxide))europium(III)
• CAS: 676251-07-3
• 化学式: C₄₂H₂₉EuF₁₈O₈P₂
• 分子量: 1217.57
• InChiKey: GVHUYFCBOJMAAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氘代甲醇 、 tris(hexafluoroacetylacetonato)(1,3-propylenebis(diphenylphosphine oxide))europium(III) 以 氘代丙酮 为溶剂， 生成 tris(hexafluoroacetylacetonato-d1)(1,3-propylenebis(diphenylphosphine oxide))europium(III)
  参考文献：
  名称：

  High lasing oscillation efficiency of Eu(III) complexes having remarkably sharp emission band

  摘要：

  Luminescent Eu(III) complexes with bis-phosphine oxide ligands were synthesized. Geometric structures of novel Eu(III) complexes were determined by single-crystal X-ray diffraction. One of the Eu(III) complexes showed remarkably sharp red emission and large stimulated emission cross-section (full width at half maximum (FWHM) = 2.1 nm, stimulated emission cross-section = 1.80 x 10(-20) cm(2)). The sharpness of the emission bands of the Eu(III) complexes was discussed in terms of the symmetry of the geometrical structure. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2004.12.144
• 作为产物：
  描述：

  tris(hexafluoroacetylacetonato)europium(III) dihydrate 、 1,3-bis(diphenylphosphoryl)propane 以 甲醇 为溶剂， 生成 tris(hexafluoroacetylacetonato)(1,3-propylenebis(diphenylphosphine oxide))europium(III)
  参考文献：
  名称：

  High lasing oscillation efficiency of Eu(III) complexes having remarkably sharp emission band

  摘要：

  Luminescent Eu(III) complexes with bis-phosphine oxide ligands were synthesized. Geometric structures of novel Eu(III) complexes were determined by single-crystal X-ray diffraction. One of the Eu(III) complexes showed remarkably sharp red emission and large stimulated emission cross-section (full width at half maximum (FWHM) = 2.1 nm, stimulated emission cross-section = 1.80 x 10(-20) cm(2)). The sharpness of the emission bands of the Eu(III) complexes was discussed in terms of the symmetry of the geometrical structure. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2004.12.144

文献信息

• Novel luminescent Eu(III) complex with remarkably narrow emission band
  作者：Kazuki Nakamura、Yasuchika Hasegawa、Yuji Wada、Shozo Yanagida

  DOI：10.1016/j.cplett.2004.09.089

  日期：2004.11

  In order to fabricate a high-power laser medium using Eu(III) complex, strong-luminescent Eu(III) complexes with low vibrational ligands were synthesized. One of the Eu(III) complex showed remarkably sharp red emission and large stimulated emission cross-section. The value of stimulated emission cross-section was the same order as the values of Nd-glass laser for practical use. (C) 2004 Elsevier B.V. All rights reserved.