碘三(三苯基胂)铜(I) | 104957-53-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 碘三(三苯基胂)铜(I)
• 英文名称: iodotris(triphenylarsine)copper(I)
• 英文别名: iodocopper;triphenylarsane
• CAS: 104957-53-1
• 化学式: C₅₄H₄₅As₃CuI
• 分子量: 1109.17
• InChiKey: WCJGMGMHASFJFZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  7.49
• 重原子数：
  59.0
• 可旋转键数：
  12.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  碘三(三苯基胂)铜(I) 、 N-(Ethoxycarbonyl)-4-chlorobenzenethiocarboxamide 以 苯 为溶剂， 以45%的产率得到[CuI(N-carboethoxy-4-chlorobenzene thioamide)(AsPh3)2]
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF COPPER(I) COMPLEXES OF N-CARBOETHOXY-4-CHLOROBENZENE AND N-CARBOETHOXY-4-BROMOBENZENE THIOAMIDES (Hcct AND Hcbt)

  摘要：

  Reactions of [Cu(EPh3)(3)X] with the title ligands yield [Cu(EPh3)(2)(LH)X] (LH = Hcct and Hcbt). Twelve complexes have been prepared and characterized on the basis of analytical, IR, electronic and NMR spectral and magnetic measurements. These complexes have a tetrahedral structure with the aromatic ligand bonded to copper(l) through sulfur.

  DOI：

  10.1081/sim-120016465

文献信息

• Substitution reactions of [CuI(AsPh3)3X] (X = Cl, Br or I) with 3-phenyl-2-thioxoimidazolidin-4-one (ptiH) and 5-mercapto-1-phenyl-1,2,3-4-tetrazole (mptH)
  作者：Ramsharan Singh、S.K. Dikshit

  DOI：10.1016/s0277-5387(00)81756-8

  日期：1993.4

  Reactions of [Cu(AsPh3)3X] with the title ligands yield [Cu(AsPh3)2(LH)X][GRAPHICS]These complexes have been characterized on the basis of analytical, IR, electronic (UV-vis), H-1 NMR, conductivity and magnetic measurements. In all cases there is a distorted tetrahedral environment around copper(I), and the ligands (LH) bind through the thione sulphur atom to copper(I).