9,10-diisopropoxyanthracene | 134767-44-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9,10-diisopropoxyanthracene
• 英文别名: 9,10-Di(propan-2-yloxy)anthracene；9,10-di(propan-2-yloxy)anthracene
• CAS: 134767-44-5
• 化学式: C₂₀H₂₂O₂
• 分子量: 294.393
• InChiKey: IXYPOJJOFMWNSH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  diphenyliodonium hexafluorophosphate 、 9,10-diisopropoxyanthracene 以 乙腈 为溶剂， 生成 10-Isopropoxy-10-phenyl-10H-anthracen-9-one
  参考文献：
  名称：

  Sahyun, M. R. V.; Vogel, Dennis E.; Sharma, Devendra K., Molecular Crystals and Liquid Crystals (1969-1991), 1991, vol. 194, p. 325 - 330

  摘要：

  DOI：

文献信息

• SULFONIUM SALT, HEAT- OR PHOTO-ACID GENERATOR, HEAT- OR PHOTO-CURABLE COMPOSITION, AND CURED PRODUCT THEREOF
  申请人：SAN APRO LTD.

  公开号：US20190284134A1

  公开（公告）日：2019-09-19

  The sulfonium salt does not contain a toxic metal and exhibits higher cationic polymerization performance and crosslinking performance than a tetrakis(pentafluorophenyl)borate salt. The heat- or photo-acid generator contains the sulfonium salt. The sulfonium salt is formed of a sulfonium cation selected from a group represented by general formulas (1), (9), (10) and (11) described below and a gallate anion represented by formula (a). The heat- or photo-acid generator contains the sulfonium salt. The heat- or energy ray-curable composition contains the acid generator and a cationically polymerizable compound. A cured product can be obtained by curing the same.

  硫铵盐不含有毒金属，表现出比四(五氟苯基)硼酸盐更高的阳离子聚合性能和交联性能。热或光酸发生剂含有硫铵盐。硫铵盐由下面描述的通用公式(1)、(9)、(10)和(11)所代表的一组硫铵阳离子和由公式(a)代表的镓酸根阴离子形成。热或光酸发生剂含有硫铵盐。热或能量射线固化组合物含有酸发生剂和阳离子聚合性化合物。通过固化可以获得固化产品。
• SULFONIUM SALT, PHOTOACID GENERATOR, PHOTOCURABLE COMPOSITION, AND CURED PRODUCT THEREOF
  申请人：SAN-APRO LTD.

  公开号：US20190300476A1

  公开（公告）日：2019-10-03

  A sulfonium salt is formed of a sulfonium cation selected from a group indicated by general formulas (1), (2), and (3) and a gallate anion represented by formula (a). A photoacid generator is characterized in that said sulfonium salt is contained therein. An energy-ray curable composition contains the acid generator and a cationic polymerizable compound. A cured product is formed by curing these substances.

  一种磺胺盐由通式（1）、（2）和（3）所示的一组磺胺阳离子以及由式（a）表示的没食子酸根阴离子组成。一种光酸发生剂的特征在于其中含有该磺胺盐。一种能量射线固化组合物包含该酸发生剂和一个阳离子可聚合化合物。通过固化这些物质形成一个固化产物。
• SULFONIUM SALT, PHOTOACID GENERATOR, AND PHOTOSENSITIVE COMPOSITION
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20170305848A1

  公开（公告）日：2017-10-26

  A novel sulfonium salt having high sensitivity with respect to active energy rays, a photoacid generator including the sulfonium salt, and a photosensitive composition containing the photoacid generator. The sulfonium salt is represented by formula (a1). In the formula, R 1 and R 2 each independently represent the group that is represented by formula (a2) or an alkyl group that may be substituted by a halogen atom, R 1 and R 2 are bonded to each other and may form a ring with the sulfur atom within the formula, R 3 is the group represented by formula (a3) or the group represented by formula (a4), A 1 represents S or the like, X − represents a monovalent anion, and R 1 and R 2 are not both an alkyl group which may be substituted with a halogen atom. In formulas (a2) to (a4), the ring Z 1 represents an aromatic hydrocarbon ring, R 4 , R 6 , R 9 , and R 10 each represents a specific monovalent group, R 5 , R 7 , and R 8 each represents a specific divalent group, A 2 and A 3 each represents S or the like, m1 represents an integer of 0 or more, and n1 and n2 each represent 0 or more.

  一种对活性能量射线具有高敏感度的新型磺鎓盐，包括该磺鎓盐的光酸发生剂以及含有该光酸发生剂的光敏组合物。该磺鎓盐由公式（a1）表示。在该公式中，R1和R2分别表示由公式（a2）表示的基团或可能被卤素原子取代的烷基基团，R1和R2彼此相连并且可以与公式中的硫原子形成环，R3表示由公式（a3）表示的基团或由公式（a4）表示的基团，A1表示S或类似物，X-表示一价阴离子，且R1和R2不同时为可能被卤素原子取代的烷基基团。在公式（a2）到（a4）中，环Z1表示芳香族碳氢环，R4、R6、R9和R10各自表示特定的一价基团，R5、R7和R8各自表示特定的二价基团，A2和A3各自表示S或类似物，m1表示0或更多的整数，n1和n2各自表示0或更多。
• SULFONIUM SALT, HEAT- OR PHOTO-ACID GENERATOR, HEAT-CURABLE OR PHOTOCURABLE COMPOSITION, AND CURED PRODUCT THEREOF
  申请人：San-Apro Ltd.

  公开号：EP3492476A1

  公开（公告）日：2019-06-05

  Provided are the following: a sulfonium salt which does not contain a toxic metal and which exhibits higher cationic polymerization performance and crosslinking performance than a tetrakis(pentafluorophenyl)borate salt; a heat- or photo-acid generator characterized by containing the sulfonium salt; an energy ray-curable composition which uses a cationic polymerization initiator (acid generator) because a cured product obtained using the heat- or photo-acid generator contains no residual strong acid following a heat resistance test and therefore does not cause corrosion of a member and does not cause the problem of reduced transparency as a result of resin degradation; and a cured product of the composition. The present invention is a sulfonium salt formed of a sulfonium cation selected from a group represented by general formulas (1), (9), (10) and (11) described below and a gallate anion represented by formula (a); a heat- or photo-acid generator characterized by containing the sulfonium salt; a heat- or energy ray-curable composition which contains the acid generator and a cationically polymerizable compound; and a cured product obtained by curing same.

  提供了以下内容：一种锍盐，它不含有毒金属，与四(五氟苯基)硼酸盐相比，具有更高的阳离子聚合性能和交联性能； 一种热或光酸发生器，其特征在于含有该锍盐；一种使用阳离子聚合引发剂（酸发生器）的能量射线固化组合物，因为使用该热或光酸发生器获得的固化产物在耐热试验后不含残留强酸，因此不会导致构件腐蚀，也不会导致因树脂降解而透明度降低的问题；以及该组合物的固化产物。本发明是一种由选自下述通式(1)、(9)、(10)和(11)所代表的锍阳离子和由式(a)所代表的没食子酸阴离子形成的锍盐；一种热或光酸发生器，其特征在于含有该锍盐；一种热或能量射线固化组合物，其中含有该酸发生器和阳离子可聚合化合物；以及一种通过固化该组合物而获得的固化产品。
• Sulfonium salt, photoacid generator, and photosensitive composition
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US10059662B2

  公开（公告）日：2018-08-28

  A novel sulfonium salt having high sensitivity with respect to active energy rays, a photoacid generator including the sulfonium salt, and a photosensitive composition containing the photoacid generator. The sulfonium salt is represented by formula (a1). In the formula, R1 and R2 each independently represent the group that is represented by formula (a2) or an alkyl group that may be substituted by a halogen atom, R1 and R2 are bonded to each other and may form a ring with the sulfur atom within the formula, R3 is the group represented by formula (a3) or the group represented by formula (a4), A1 represents S or the like, X− represents a monovalent anion, and R1 and R2 are not both an alkyl group which may be substituted with a halogen atom. In formulas (a2) to (a4), the ring Z1 represents an aromatic hydrocarbon ring, R4, R6, R9, and R10 each represents a specific monovalent group, R5, R7, and R8 each represents a specific divalent group, A2 and A3 each represents S or the like, m1 represents an integer of 0 or more, and n1 and n2 each represent 0 or more.

  一种对活性能量射线具有高灵敏度的新型锍盐，一种包括该锍盐的光酸发生器，以及一种含有该光酸发生器的光敏组合物。锍盐用式（a1）表示。在该式中，R1 和 R2 各自独立地代表由式（a2）表示的基团或可被卤素原子取代的烷基，R1 和 R2 相互键合并可与式中的硫原子形成环，R3 是由式（a3）表示的基团或由式（a4）表示的基团，A1 代表 S 或类似物，X- 代表一价阴离子，且 R1 和 R2 并非都是可被卤素原子取代的烷基。在式 (a2) 至 (a4) 中，环 Z1 代表芳香烃环，R4、R6、R9 和 R10 各代表特定的一价基团，R5、R7 和 R8 各代表特定的二价基团，A2 和 A3 各代表 S 或类似物，m1 代表 0 或以上的整数，n1 和 n2 各代表 0 或以上。