(2'-Me3SiCH2-4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine(1-))lutetium(III)(2,4,6-triphenylanilide)(CH2SiMe3) | 1010100-63-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2'-Me3SiCH2-4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine(1-))lutetium(III)(2,4,6-triphenylanilide)(CH2SiMe3)
• CAS: 1010100-63-6
• 化学式: C₅₉H₇₅LuN₄Si₂
• 分子量: 1071.41
• InChiKey: TVTPXSUQKAGTBA-YEPRCSLYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (2'-Me3SiCH2-4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine(1-))lutetium(III)(2,4,6-triphenylanilide)(CH2SiMe3) 以 氘代苯 为溶剂， 以0%的产率得到(2'-Me3SiCH2-4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine(1-))lutetium(III)(=NC6H2-2,4,6-Ph3)
  参考文献：
  名称：

  Lutetium Alkyls Supported by a Dearomatized and Functionalized Terpyridine Ligand: Preparation of Fluorinated Anilide Complexes

  摘要：

  Lutetium alkyl complexes supported by a monoanionic, tridentate ligand system formed by the dearomatization and junctionalization of a 2,2':6',2 ''-terpyridine have been reacted with 2,4,6-triphenylaniline or the fluorinated anilines 4-F-C6H4NH2 and C6F5NH2 to give both terminal mono(amide) and bis(amide) lutetium(III) complexes, which have been fully characterized. Both [Bu-t(3)(2'-Me3SiCH2)tpy]Lu[NH(2,4,6-Ph-3-C6H2)](2) (3) and [Bu-t(3)(2'-Me3SiCH2)tPy](C5Me5)Lu(NHC6F5) (7) have been structurally characterized. The fluorinated anilide complexes [Bu-t(3)(2'-Me3SiCH2)tpy](C5Me5)Lu(NHArF) (Ar-F = 4-F-C6H4 (6), C6F5 (7)) provide rare examples of lutetium organofluorine complexes, with 7 featuring an intramolecular F center dot center dot center dot H-C interaction that is present in both solid state and solution.

  DOI：

  10.1021/om701076n
• 作为产物：
  描述：

  (2'-CH2SiMe3-4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine(1-))lutetium(III)(CH2SiMe3)2 、 (2'-Me3SiCH2-4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine(1-))lutetium(III)(2,4,6-triphenylanilide)2 以 甲苯 为溶剂， 以78%的产率得到(2'-Me3SiCH2-4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine(1-))lutetium(III)(2,4,6-triphenylanilide)(CH2SiMe3)
  参考文献：
  名称：

  Lutetium Alkyls Supported by a Dearomatized and Functionalized Terpyridine Ligand: Preparation of Fluorinated Anilide Complexes

  摘要：

  Lutetium alkyl complexes supported by a monoanionic, tridentate ligand system formed by the dearomatization and junctionalization of a 2,2':6',2 ''-terpyridine have been reacted with 2,4,6-triphenylaniline or the fluorinated anilines 4-F-C6H4NH2 and C6F5NH2 to give both terminal mono(amide) and bis(amide) lutetium(III) complexes, which have been fully characterized. Both [Bu-t(3)(2'-Me3SiCH2)tpy]Lu[NH(2,4,6-Ph-3-C6H2)](2) (3) and [Bu-t(3)(2'-Me3SiCH2)tPy](C5Me5)Lu(NHC6F5) (7) have been structurally characterized. The fluorinated anilide complexes [Bu-t(3)(2'-Me3SiCH2)tpy](C5Me5)Lu(NHArF) (Ar-F = 4-F-C6H4 (6), C6F5 (7)) provide rare examples of lutetium organofluorine complexes, with 7 featuring an intramolecular F center dot center dot center dot H-C interaction that is present in both solid state and solution.

  DOI：

  10.1021/om701076n