3,4-dibromo-2,2-dimethyl-hexane | 859773-14-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 英文名称: 3,4-dibromo-2,2-dimethyl-hexane
• 英文别名: 3,4-Dibrom-2,2-dimethyl-hexan；3,4-Dibromo-2,2-dimethylhexane
• CAS: 859773-14-1
• 化学式: C₈H₁₆Br₂
• 分子量: 272.023
• InChiKey: LJXOSVQYXHFGRU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  反式-2,2-二甲基-3-己烯 在 溴 作用下， 生成 3,4-dibromo-2,2-dimethyl-hexane
  参考文献：
  名称：

  Electrophilic additions to multiple bonds. 2. Medium effect on bromine additions to alkenes

  摘要：

  DOI：

  10.1021/jo00443a008

文献信息

• Epoxidation of olefins by β-bromoalkoxydimethylsulfonium ylides
  作者：George Majetich、Joel Shimkus、Yang Li

  DOI：10.1016/j.tetlet.2010.10.068

  日期：2010.12

  Olefins can be converted to their respective epoxides in a one-pot procedure by dissolving the olefin in anhydrous DMSO, adding NBS to the reaction mixture to generate a beta-bromoalkoxydimethylsulfonium ylide, and then adding DBU to the reaction mixture. A large variety of alkenes were successfully epoxidized with yields largely dependent on the structure of the alkene. Most importantly, the facial selectivity of this one-pot process is the opposite of that observed when using traditional epoxidizing reagents. Electron-poor alkenes are not epoxidized under these conditions. (C) 2010 Published by Elsevier Ltd.
• The nucleophilic contribution of the solvent in olefin bromination. I. Steric inhibition to nucleophilic solvation in alkene bromination via brominium ions
  作者：Marie Francoise Ruasse、Ben Li Zhang

  DOI：10.1021/jo00191a031

  日期：1984.8
• Schurman; Boord, Journal of the American Chemical Society, 1933, vol. 55, p. 4932
  作者：Schurman、Boord

  DOI：——

  日期：——