n-octadecyltriphenylstannane | 200618-75-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: n-octadecyltriphenylstannane
• CAS: 200618-75-3
• 化学式: C₃₆H₅₂Sn
• 分子量: 603.519
• InChiKey: XLYLTFMLNFTJHU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.42
• 重原子数：
  37
• 可旋转键数：
  20
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-octadecylmagnesium bromide 、 三苯基氯化锡 在 H₂O 作用下， 以 乙醚 为溶剂， 生成 n-octadecyltriphenylstannane
  参考文献：
  名称：

  Structural relationships in the homologous series of alkyltriphenylstannane compounds of formula Ph3Sn(CH2)n−1CH3, with n even and in the range 4–14 and 18

  摘要：

  The solid state structures of several compounds in the homologous series of alkyltriphenylstannanes of general formula Ph3Sn(CH2)(n-1)CH3 have been determined. For it in the range 4-10 the structures are monoclinic with space group P21/c. For n greater than 10 they are, instead, triclinic with space group P (1) over bar. The structural difference between the two classes is attributable to a change in the degree of control over the packing of the molecules exerted by the triphenylstannyl entity on the one hand and the alkyl chain on the other. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.07.024

文献信息

• Structural relationships in the homologous series of alkyltriphenylstannane compounds of formula Ph3Sn(CH2)n−1CH3, with n even and in the range 4–14 and 18
  作者：Gillian M. Allan、R. Alan Howie、John N. Low、Janet M.S. Skakle、James L. Wardell、Solange M.S.V. Wardell

  DOI：10.1016/j.poly.2005.07.024

  日期：2006.2

  The solid state structures of several compounds in the homologous series of alkyltriphenylstannanes of general formula Ph3Sn(CH2)(n-1)CH3 have been determined. For it in the range 4-10 the structures are monoclinic with space group P21/c. For n greater than 10 they are, instead, triclinic with space group P (1) over bar. The structural difference between the two classes is attributable to a change in the degree of control over the packing of the molecules exerted by the triphenylstannyl entity on the one hand and the alkyl chain on the other. (c) 2005 Elsevier Ltd. All rights reserved.