N-[1-diethoxyphosphoryl-2,2-bis[(4-methylphenyl)sulfanyl]ethenyl]benzamide | 1092342-22-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[1-diethoxyphosphoryl-2,2-bis[(4-methylphenyl)sulfanyl]ethenyl]benzamide
• CAS: 1092342-22-7
• 化学式: C₂₇H₃₀NO₄PS₂
• 分子量: 527.645
• InChiKey: NNZJWSNKQAKQFM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  35
• 可旋转键数：
  11
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  115
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N-[1-diethoxyphosphoryl-2,2-bis[(4-methylphenyl)sulfanyl]ethenyl]benzamide 在 silver carbonate 作用下， 以 1,4-二氧六环 为溶剂， 反应 8.0h， 以78%的产率得到
  参考文献：
  名称：

  Synthesis and some properties of 4-phosphorylated derivatives of 5-mercapto-1,3-oxazoles

  摘要：

  Various approaches to the synthesis of new derivatives of diethyl 5-mercapto-2-R-1,3-oxazole-4-ylphosphonates were considered. The behavior of these compounds in the presence of mineral acids and alkalis resulting in the synthesis of previously unknown 5-mercapto-2-R-1,3-oxazole-4-ylphosphonic acids was studied.

  DOI：

  10.1134/s1070363213010088
• 作为产物：
  描述：

  diethyl (1-benzamido-2,2-dichlorovinyl)phosphonate 、 4-甲苯硫酚 在 三乙胺 作用下， 以 乙腈 为溶剂， 反应 8.0h， 以70%的产率得到N-[1-diethoxyphosphoryl-2,2-bis[(4-methylphenyl)sulfanyl]ethenyl]benzamide
  参考文献：
  名称：

  Synthesis and some properties of 4-phosphorylated derivatives of 5-mercapto-1,3-oxazoles

  摘要：

  Various approaches to the synthesis of new derivatives of diethyl 5-mercapto-2-R-1,3-oxazole-4-ylphosphonates were considered. The behavior of these compounds in the presence of mineral acids and alkalis resulting in the synthesis of previously unknown 5-mercapto-2-R-1,3-oxazole-4-ylphosphonic acids was studied.

  DOI：

  10.1134/s1070363213010088

文献信息

• Synthesis and some properties of 4-phosphorylated derivatives of 5-mercapto-1,3-oxazoles
  作者：K. M. Kondratyuk、E. I. Lukashuk、A. V. Golovchenko、A. N. Vasilenko、V. S. Brovarets

  DOI：10.1134/s1070363213010088

  日期：2013.1

  Various approaches to the synthesis of new derivatives of diethyl 5-mercapto-2-R-1,3-oxazole-4-ylphosphonates were considered. The behavior of these compounds in the presence of mineral acids and alkalis resulting in the synthesis of previously unknown 5-mercapto-2-R-1,3-oxazole-4-ylphosphonic acids was studied.