1,2,4,5-benzenetetracarboxylate | 7242-86-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2,4,5-benzenetetracarboxylate
• 英文别名: 1,2,4,5-btec；1,2,4,5-tetracarboxylatobenzene；1,2,4,5-BTC；Benzene-1,2,4,5-tetracarboxylate
• CAS: 7242-86-6
• 化学式: C₁₀H₂O₈
• 分子量: 250.121
• InChiKey: CYIDZMCFTVVTJO-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  161
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  ethylenediamine nickel(II) 、 1,2,4,5-benzenetetracarboxylate 以 水 为溶剂， 生成 hexaaqua-μ-{1,2,4,5-benzenetetracarboxylato(4-)}-bis(ethylenediamine)dinickel(II) tetrahydrate
  参考文献：
  名称：

  Poleti, D.; Stojakovic, D. R.; Prelesnik, B. V., Acta Crystallographica, Section C: Crystal Structure Communications, 1988, vol. 44, p. 242 - 245

  摘要：

  DOI：

文献信息

• A series of novel metal–organic coordination polymers constructed from the new 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole spacer and aromatic carboxylates: Synthesis, crystal structures, and luminescence properties
  作者：Jiayin Sun、Daojun Zhang、Li Wang、Renchun Zhang、Junjie Wang、Ying Zeng、Jinling Zhan、Jianing Xu、Yong Fan

  DOI：10.1016/j.jssc.2013.08.024

  日期：2013.10

  Using bifunctional organic ligand 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (HL) and different aromatic carboxylates as secondary ligands, four novel metal-organic coordination polymers, [Zn(L)(1,4-bdc)0.5] (1), [Zn1.5(L)(2,5-pydc)] (2), [Zn(HL)(1,2,4,5-btec)0.5] (3), and [Cd(HL)(1,2,4,5-btec)0.5] (4) (1,4-bdc, 1,4-benzenedicarboxylate; 2,5-pydc, 2,5-pyridinedicarboxylate; 1,2,4,5-btec, 1,2,4,5-benz

  使用双官能有机配体5-（4-咪唑-1-基-苯基）-2H-四唑（HL）和不同的芳族羧酸盐作为辅助配位体，四新颖金属有机配位聚合物，[锌（L）（1,4- BDC）0.5（1），[锌1.5（L）（2,5- pydc）]（2），[锌（HL）（1,2,4,5- BTEC）0.5 ]（3）和[镉（HL）（1,2,4,5- BTEC）0.5（4）（1,4-BDC，1,4-苯二甲酸，2,5- pydc，2,5-吡啶二羧酸; 1,2,4- ，5- BTEC，1,2,4,5- benzenetetracarboxylate）已经被成功地合成和分析。化合物1采用了2D [锌（L）] Ñ层由μ内置3-L桥接配体和Zn（II）离子，其通过柱1,4-BDC进一步连接2-配体以形成2倍互穿DMC框架。化合物2的三维网络可以简化为一种罕见的2-节点（3,6） -连接的RTL（金红石）的拓扑结构。化合物3具有其通过阶梯链连
• Hydrothermal synthesis and crystal structure of two luminescent three-dimensional supramolecular complexes generated from mixed ligands
  作者：Xinxin Xu、Ying Lu、Enbo Wang、Ying Ma、Xiuli Bai

  DOI：10.1016/j.molstruc.2006.04.029

  日期：2006.12

  Two 3D metal-organic supramolecular complexes [Zn-2(btec)(2, 2'-bpy)(2)(H2O)(2)] (1), [Cd-2(dpa)(2)(phen)(2)(H2O)(2)](2) have been prepared by hydrothermal reaction and characterized by IR and single-crystal X-ray diffraction analysis. The 3D architectures of 1 and 2 both possess rectangular cavities. Furthermore, compounds I and 2 both show intense photoluminescent properties at room temperature. (c) 2006 Elsevier B.V. All rights reserved.
• Moderately strong intramolecular magnetic exchange interaction between the copper(II) ions separated by 11.25 .ANG. in [L2Cu2(OH2)2(.eta.-terephthalato)](ClO4)2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)
  作者：Phalguni. Chaudhuri、Karen. Oder、Karl. Wieghardt、Stefan. Gehring、Wolfgang. Haase、Bernhard. Nuber、Johannes. Weiss

  DOI：10.1021/ja00219a051

  日期：1988.5
• Ionothermal synthesis and characterization of a 3-D (4,8)-connected porous anionic metal–organic framework entrapped with 1-D [K2(H2O)6] chains
  作者：Wen-Juan Ji、Quan-Guo Zhai、Man-Cheng Hu、Shu-Ni Li、Yu-Cheng Jiang、Yan Wang

  DOI：10.1016/j.inoche.2008.10.005

  日期：2008.12

  A novel metal-organic coordination polymer, namely, [K-2(H2O)(6)][Cd-3(1,2,4,5-BTC)(2)]}(n) (1) (1,2,4,5-BTC = 1,2,4,5-benzenetetracarboxylate), was synthesized in an ionothermal reaction by using an ionic liquid 1-ethyl-3-methylimidazolium bromide ([EMIM]Br) as solvent. Complex 1 features a novel 3-D (4.8)-connected porous anionic architecture constructed by linking trinuclear Cd subunits with 1,2,4.5-BTC4- ligands, which are further filled with 1-D [K-2(H2O)(6)] cationic chains. (c) 2008 Published by Elsevier B.V.
• Poleti, D.; Stojakovic, D. R.; Prelesnik, B. V., Acta Crystallographica, Section C: Crystal Structure Communications, 1988, vol. 44, p. 242 - 245
  作者：Poleti, D.、Stojakovic, D. R.、Prelesnik, B. V.、Herak, R. M.

  DOI：——

  日期：——