Methyl 3-[2-[3-[2-[3-[2-[[2-(anthracen-9-ylmethylamino)-2-oxoacetyl]amino]ethyl-[3-[2-[bis[3-[2-[bis(3-methoxy-3-oxopropyl)amino]ethylamino]-3-oxopropyl]amino]ethylamino]-3-oxopropyl]amino]propanoylamino]ethyl-[3-[2-[bis(3-methoxy-3-oxopropyl)amino]ethylamino]-3-oxopropyl]amino]propanoylamino]ethyl-(3-methoxy-3-oxopropyl)amino]propanoate | 865532-06-5

分子结构分类

有机化合物 - 苯类化合物 - 蒽

中文名称

——

中文别名

——

英文名称

Methyl 3-[2-[3-[2-[3-[2-[[2-(anthracen-9-ylmethylamino)-2-oxoacetyl]amino]ethyl-[3-[2-[bis[3-[2-[bis(3-methoxy-3-oxopropyl)amino]ethylamino]-3-oxopropyl]amino]ethylamino]-3-oxopropyl]amino]propanoylamino]ethyl-[3-[2-[bis(3-methoxy-3-oxopropyl)amino]ethylamino]-3-oxopropyl]amino]propanoylamino]ethyl-(3-methoxy-3-oxopropyl)amino]propanoate

英文别名

methyl 3-[2-[3-[2-[3-[2-[[2-(anthracen-9-ylmethylamino)-2-oxoacetyl]amino]ethyl-[3-[2-[bis[3-[2-[bis(3-methoxy-3-oxopropyl)amino]ethylamino]-3-oxopropyl]amino]ethylamino]-3-oxopropyl]amino]propanoylamino]ethyl-[3-[2-[bis(3-methoxy-3-oxopropyl)amino]ethylamino]-3-oxopropyl]amino]propanoylamino]ethyl-(3-methoxy-3-oxopropyl)amino]propanoate

CAS

865532-06-5

化学式

C₈₁H₁₂₇N₁₅O₂₄

mdl

——

分子量

1694.99

InChiKey

UWZASBXCWTUYPP-UHFFFAOYSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

-2.4
重原子数：

120
可旋转键数：

73
环数：

3.0
sp3杂化的碳原子比例：

0.63
拓扑面积：

466
氢给体数：

8
氢受体数：

31

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	3-({2-[3-({2-[(Anthracen-9-ylmethyl)-aminooxalyl]-amino}-ethyl)-(2-{2-[bis-(2-methoxycarbonyl-ethyl)-amino]-ethylcarbamoyl}-ethyl)-amino]-propionylamino}-ethyl)-(2-methoxycarbonyl-ethyl)-amino)-propionic acid methyl ester	326895-44-7	C₄₅H₆₃N₇O₁₂	894.035

反应信息

作为反应物：

描述：

Methyl 3-[2-[3-[2-[3-[2-[[2-(anthracen-9-ylmethylamino)-2-oxoacetyl]amino]ethyl-[3-[2-[bis[3-[2-[bis(3-methoxy-3-oxopropyl)amino]ethylamino]-3-oxopropyl]amino]ethylamino]-3-oxopropyl]amino]propanoylamino]ethyl-[3-[2-[bis(3-methoxy-3-oxopropyl)amino]ethylamino]-3-oxopropyl]amino]propanoylamino]ethyl-(3-methoxy-3-oxopropyl)amino]propanoate 、 alkaline earth salt of/the/ methylsulfuric acid 以邻二氯苯为溶剂，反应 1.0h，以21%的产率得到

参考文献：

名称：

Reversible Binding of C60 to an Anthracene Bearing a Dendritic Poly(amidoamine) Substituent to give a Water-Soluble Fullerodendrimer This work was partly supported by The Nissan Science Foundation, The Japan Space Forum Foundation, Grant-in-Aid for COE Research (No. 10CE2003), and Priority-Area-Research (B) (No. 12129205) by the Ministry of Education, Science, Sports, and Culture of Japan.

摘要：

DOI：

10.1002/1521-3773(20020301)41:5<817::aid-anie817>3.0.co;2-r
作为产物：

描述：

以甲醇为溶剂，反应 12.0h，以87%的产率得到Methyl 3-[2-[3-[2-[3-[2-[[2-(anthracen-9-ylmethylamino)-2-oxoacetyl]amino]ethyl-[3-[2-[bis[3-[2-[bis(3-methoxy-3-oxopropyl)amino]ethylamino]-3-oxopropyl]amino]ethylamino]-3-oxopropyl]amino]propanoylamino]ethyl-[3-[2-[bis(3-methoxy-3-oxopropyl)amino]ethylamino]-3-oxopropyl]amino]propanoylamino]ethyl-(3-methoxy-3-oxopropyl)amino]propanoate

参考文献：

名称：

Reversible Binding of C60 to an Anthracene Bearing a Dendritic Poly(amidoamine) Substituent to give a Water-Soluble Fullerodendrimer This work was partly supported by The Nissan Science Foundation, The Japan Space Forum Foundation, Grant-in-Aid for COE Research (No. 10CE2003), and Priority-Area-Research (B) (No. 12129205) by the Ministry of Education, Science, Sports, and Culture of Japan.

摘要：

DOI：

10.1002/1521-3773(20020301)41:5<817::aid-anie817>3.0.co;2-r

点击查看最新优质反应信息

文献信息

Photoresponsive Dendrimers: Syntheses and Characterizations of Anthracenes Bearing Dendritic Substituents

作者：Yutaka Takaguchi、Tomoyuki Tajima、Kazuchika Ohta、Jiro Motoyoshiya、Hiromu Aoyama

DOI：10.1246/cl.2000.1388

日期：2000.12

A new photoreactive anthracenyl dendron undergoes a reversible photocyclization to form a dendrimer.

一种新的具有光活性的蒽基树枝状化合物经过可逆的光环化作用形成树枝状聚合物。
Reversible Binding of C60 to an Anthracene Bearing a Dendritic Poly(amidoamine) Substituent to give a Water-Soluble Fullerodendrimer This work was partly supported by The Nissan Science Foundation, The Japan Space Forum Foundation, Grant-in-Aid for COE Research (No. 10CE2003), and Priority-Area-Research (B) (No. 12129205) by the Ministry of Education, Science, Sports, and Culture of Japan.

作者：Yutaka Takaguchi、Tomoyuki Tajima、Kazuchika Ohta、Jiro Motoyoshiya、Hiromu Aoyama、Takatsugu Wakahara、Takeshi Akasaka、Mamoru Fujitsuka、Osamu Ito

DOI：10.1002/1521-3773(20020301)41:5<817::aid-anie817>3.0.co;2-r

日期：2002.3.1

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