N,N'-bis(3-benzylaminopropyl)ethylenediamine | 140840-10-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis(3-benzylaminopropyl)ethylenediamine
• 英文别名: N'-benzyl-N-[2-[3-(benzylamino)propylamino]ethyl]propane-1,3-diamine
• CAS: 140840-10-4
• 化学式: C₂₂H₃₄N₄
• 分子量: 354.539
• InChiKey: IUGPOLWISAWAMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  26
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  48.1
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N-二甲基甲酰胺二甲基缩醛 、 N,N'-bis(3-benzylaminopropyl)ethylenediamine 以 乙醇 为溶剂， 反应 2.0h， 以91%的产率得到4,5-Dibenzyl-1,2,3,4,5,6,7,8,9,10-decahydro-4,5,8a,10a-tetraaza-phenanthrene
  参考文献：
  名称：

  Cetinkaya, Engin; Hitchcock, Peter B.; Jasim, Hatam A., Journal of the Chemical Society. Perkin transactions I, 1992, # 5, p. 561 - 568

  摘要：

  DOI：
• 作为产物：
  描述：

  1,12-bis(benzylidene)-1,5,8,12-tetraazadodecane 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 反应 2.0h， 生成 N,N'-bis(3-benzylaminopropyl)ethylenediamine
  参考文献：
  名称：

  Bernardo, M. Alexandra; Guerrero, Jose A.; Garcia-Espana, Enrique, Journal of the Chemical Society. Perkin transactions II, 1996, # 11, p. 2335 - 2342

  摘要：

  DOI：

文献信息

• One pot symmetrical and dissymmetrical regiospecific ω,ω′-bis mono N-alkylation of linear tetraamines via their chromium, molybdenum or tungsten tricarbonyl complexes
  作者：Nathalie Le Bris、Jean-Jacques Yaouanc、Jean-Claude Clément、Henri Handel、Hervé des Abbayes

  DOI：10.1016/s0040-4039(00)73926-8

  日期：1993.1

  Dissymmetric ω, ω′-N-dialkylated linear tetraamines have been obtained after the successive reactions of two aldehydes and subsequent reduction and removal of the M(CO)3 protection.

  在两个醛连续反应并随后还原和去除M（CO）3保护后，获得不对称的ω，ω'-N-二烷基化线性四胺。
• Polyamides and Amidoamines From Selectively Modified Amine Amines
  申请人：Raymond Williams Rene Edouard

  公开号：US20120237774A1

  公开（公告）日：2012-09-20

  The present disclosure provides polyamides and amidoamine curing agents including the reaction product of (1) a modified amine component comprising at least one multifunctional amine of structure 1: wherein R 1 is selected from C 1 -C 16 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups; R 2 and R 4 are hydrogen, R 3 is R 1 or hydrogen, X, Y, and Z are independently selected from C 2 -C 10 alkylene, hexylene and cycloalkylene groups, n=0, 1, 2, 3, 4, 5, 6, or 7; and (2) a fatty acid component. Exemplary fatty acid components include at least one of monomer fatty acids, dimer fatty acids, trimer fatty acids, polymer fatty acids, esters of monomer, dimer, trimer, and polymer fatty acids and combinations thereof. The method for making the curing agents and articles formed therefrom are also disclosed.
• US8513376B2
  申请人：——

  公开号：US8513376B2

  公开（公告）日：2013-08-20
• [EN] POLYAMIDES AND AMIDOAMINES FROM SELECTIVELY MODIFIED AMINE AMINES<br/>[FR] POLYAMIDES ET AMIDOAMINES OBTENUS À PARTIR D'AMINE AMINES SÉLECTIVEMENT MODIFIÉES
  申请人：AIR PROD & CHEM

  公开号：WO2012125240A2

  公开（公告）日：2012-09-20

  The present disclosure provides polyamides and amidoamine curing agents including the reaction product of (1) a modified amine component comprising at least one multifunctional amine of structure 1: wherein R1 is selected from C1 - C16 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups; R2 and R4 are hydrogen, R3 is R1 or hydrogen, X, Y, and Z are independently selected from C2 - C10 alkylene, hexylene and cycloalkylene groups, n=0, 1, 2, 3, 4, 5, 6, or 7; and (2) a fatty acid component. Exemplary fatty acid components include at least one of monomer fatty acids, dimer fatty acids, trimer fatty acids, polymer fatty acids, esters of monomer, dimer, trimer, and polymer fatty acids and combinations thereof. The method for making the curing agents and articles formed therefrom are also disclosed.