(1-Isopropenyl-4-methyl-hex-5-enyl)-phenyl-amine | 145913-59-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (1-Isopropenyl-4-methyl-hex-5-enyl)-phenyl-amine
• 英文别名: Benzenamine, N-[4-methyl-1-(1-methylethenyl)-5-hexenyl]-；N-(2,6-dimethylocta-1,7-dien-3-yl)aniline
• CAS: 145913-59-3
• 化学式: C₁₆H₂₃N
• 分子量: 229.365
• InChiKey: ARFQQSJVXUYCQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  苯胺 、 天然橡胶 在 bis(acetylacetonato)palladium(II) 、 三丁基,三丁酯 作用下， 以 乙腈 为溶剂， 反应 32.0h， 生成 N-(2-methylbut-2-en-1-yl)aniline 、 N-(2,7-Dimethyl-2,7-octadienyl)aniline 、 ((E)-2,6-Dimethyl-octa-2,7-dienyl)-phenyl-amine 、 (1-Isopropenyl-4-methyl-hex-5-enyl)-phenyl-amine
  参考文献：
  名称：

  Reaction between isoprene and aniline on complex palladium catalysts

  摘要：

  Isoprene and aniline have been reacted on the catalytic system Pd(acac)2-Ph3P to form a mixture of isomeric telomers: N-(dimethyloctadien-2,7-yl-1)anilines and N-(dimethyloctadien-1,7-yl-3)anilines but on the catalytic system Pd(acac)2-Ph3P-CF3COOH the main product is a mixture of N-(methylbuten-2-yl)aniline adducts. The reaction between N-methylaniline and isoprene on the latter catalyst also gives a mixture of N-methyl and N-(methylbuten-2-yl)aniline adducts.

  DOI：

  10.1007/bf00864336

文献信息

• Reaction between isoprene and aniline on complex palladium catalysts
  作者：E. A. Petrushkina、L. I. Zakharkin

  DOI：10.1007/bf00864336

  日期：1992.8

  Isoprene and aniline have been reacted on the catalytic system Pd(acac)2-Ph3P to form a mixture of isomeric telomers: N-(dimethyloctadien-2,7-yl-1)anilines and N-(dimethyloctadien-1,7-yl-3)anilines but on the catalytic system Pd(acac)2-Ph3P-CF3COOH the main product is a mixture of N-(methylbuten-2-yl)aniline adducts. The reaction between N-methylaniline and isoprene on the latter catalyst also gives a mixture of N-methyl and N-(methylbuten-2-yl)aniline adducts.