5,12-dihydro-5,12-dioxo-2-naphthacenecarboxylic acid | 793716-65-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 并四苯
• 英文名称: 5,12-dihydro-5,12-dioxo-2-naphthacenecarboxylic acid
• 英文别名: 5,12-Dioxotetracene-2-carboxylic acid
• CAS: 793716-65-1
• 化学式: C₁₉H₁₀O₄
• 分子量: 302.286
• InChiKey: DFLGNDOXPUPADT-UHFFFAOYSA-N

物化性质

• 沸点：
  600.9±44.0 °C(Predicted)
• 密度：
  1.469±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  23
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  71.4
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  5,12-dihydro-5,12-dioxo-2-naphthacenecarboxylic acid 在 氯化亚砜 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 5,12-dihydro-5,12-dioxo-N-(2'-hydroxyethyl)-2-naphthacenecarboxamide
  参考文献：
  名称：

  Synthesis and Study of Naphthacenedione (TQ) as a Photosensitizer for One-Electron Oxidation of DNA

  摘要：

  (GRAPHICS)Photosensitizers; are useful for the study of one-electron oxidation of DNA. Most such photosensitizers; absorb light in the UV spectral region. We report the synthesis and investigation of a 5,12-naphthacenedione (TO) derivative as a DNA photosensitizer. Irradiation of a TQ-linked duplex with visible light results in reaction of the DNA that is characteristic of one-electron oxidation. The results from TO sensitization are identical, within experimental error, with that of a well-studied anthraquinone derivative.

  DOI：

  10.1021/ol048407m
• 作为产物：
  描述：

  5,12-naphthacenequinone-2-carboxaldehyde 在 水 chromium(VI) oxide 、 硫酸 、 溶剂黄146 作用下， 以 丙酮 为溶剂， 反应 7.0h， 以49%的产率得到5,12-dihydro-5,12-dioxo-2-naphthacenecarboxylic acid
  参考文献：
  名称：

  Synthesis and Study of Naphthacenedione (TQ) as a Photosensitizer for One-Electron Oxidation of DNA

  摘要：

  (GRAPHICS)Photosensitizers; are useful for the study of one-electron oxidation of DNA. Most such photosensitizers; absorb light in the UV spectral region. We report the synthesis and investigation of a 5,12-naphthacenedione (TO) derivative as a DNA photosensitizer. Irradiation of a TQ-linked duplex with visible light results in reaction of the DNA that is characteristic of one-electron oxidation. The results from TO sensitization are identical, within experimental error, with that of a well-studied anthraquinone derivative.

  DOI：

  10.1021/ol048407m

文献信息

• 补锂剂及制备方法、隔膜及制备方法、电池
  申请人：深圳海辰储能科技有限公司

  公开号：CN116813499B

  公开（公告）日：2024-01-02

  本发明涉及一种补锂剂及其制备方法、隔膜及其制备方法、电池和用电装置。该补锂剂，其特征在于，包括多元蒽醌类化合物，所述多元蒽醌类化合物的结构通式如式（I）所示：#imgabs0#（I）；A为#imgabs1#；Ar1和Ar2分别独立选自未取代或被R取代的环原子数为6～20的芳基；R选自卤素、烷基、烷氧基、卤代烷基、羧基、酯基、氰基、羟基或氨基；n选自3至6中任一整数；*表示连接位点。该补锂剂富含锂且结构稳定，将其用于电池隔膜，在电池常规放电电压下便能够将补锂剂中的锂释放出来，从而达到对锂离子电池补锂的效果，显著提高锂离子电池的能量密度。
• Synthesis and Study of Naphthacenedione (TQ) as a Photosensitizer for One-Electron Oxidation of DNA
  作者：Lezah W. Roberts、Gary B. Schuster

  DOI：10.1021/ol048407m

  日期：2004.10.1

  (GRAPHICS)Photosensitizers; are useful for the study of one-electron oxidation of DNA. Most such photosensitizers; absorb light in the UV spectral region. We report the synthesis and investigation of a 5,12-naphthacenedione (TO) derivative as a DNA photosensitizer. Irradiation of a TQ-linked duplex with visible light results in reaction of the DNA that is characteristic of one-electron oxidation. The results from TO sensitization are identical, within experimental error, with that of a well-studied anthraquinone derivative.