Mn(2-O-3-OMe-5-BrC6H3CHNCH2CH2CH2NCHC6H3-2-O-3-OMe-5-Br)2(H2O)(EtOH)ClO4 | 263351-09-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Mn(2-O-3-OMe-5-BrC6H3CHNCH2CH2CH2NCHC6H3-2-O-3-OMe-5-Br)2(H2O)(EtOH)ClO4
• CAS: 263351-09-3
• 化学式: C₂₁H₂₆Br₂MnN₂O₆*ClO₄
• 分子量: 716.644
• InChiKey: AOLORGUATKSWGH-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-bis(5-bromo-3-methoxysalicylidene)propylene-1,3-diamine 以 甲醇 、 乙醇 为溶剂， 生成 Mn(2-O-3-OMe-5-BrC6H3CHNCH2CH2CH2NCHC6H3-2-O-3-OMe-5-Br)2(H2O)(EtOH)ClO4
  参考文献：
  名称：

  Synthesis and structural characterisation of new manganese(II) and (III) complexes. Study of their photolytic and catalase activity and X-ray crystal structure of [Mn(3-OMe, 5-Br-salpn)(EtOH)(H2O)]ClO4

  摘要：

  New [(MnL)-L-II(H2O)(2)] and [(MnL)-L-III(H2O)(2)]ClO4 complexes, where L are substituted N,N'-bis(salicylidene)propane-1,3-diamine (H(2)salpn) ligands have been prepared and thoroughly characterised by elemental analysis, IR and mass spectroscopy, conductivity and magnetic measurements at room temperature (and, in the case of 1, at variable temperature). Cyclic and normal pulse voltammetry measurements were also performed. All these studies support an octahedral geometry around the metal with the Schiff base in the equatorial plane acting as tetradentate and solvent molecules in the axial positions. Crystallographic characterisation of 6 confirms this geometry and shows a supramolecular structure involving pi-pi stacking and hydrogen bonding interactions. The ability to split water by these complexes and their catalase activity has also been studied. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00321-6