N-(4-tert-butylphenyl)-1-[4-[7-tert-butyl-3,5,9-tris[4-[(4-tert-butylphenyl)iminomethyl]phenyl]pyren-1-yl]phenyl]methanimine | 1422738-49-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: N-(4-tert-butylphenyl)-1-[4-[7-tert-butyl-3,5,9-tris[4-[(4-tert-butylphenyl)iminomethyl]phenyl]pyren-1-yl]phenyl]methanimine
• CAS: 1422738-49-5
• 化学式: C₈₈H₈₆N₄
• 分子量: 1199.68
• InChiKey: BQOHDUCRQHARJI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.1
• 重原子数：
  92
• 可旋转键数：
  17
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  49.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-叔丁基苯胺 、 7-tert-butyl-1,3,5,9-tetrakis(4-formylphenyl)pyrene 以 二氯甲烷 为溶剂， 反应 48.0h， 以50%的产率得到N-(4-tert-butylphenyl)-1-[4-[7-tert-butyl-3,5,9-tris[4-[(4-tert-butylphenyl)iminomethyl]phenyl]pyren-1-yl]phenyl]methanimine
  参考文献：
  名称：

  Blue-Emitting Butterfly-Shaped 1,3,5,9-Tetraarylpyrenes: Synthesis, Crystal Structures, and Photophysical Properties

  摘要：

  The first example of aryl-functionalized, butterfly-shaped, highly fluorescent and stable blue-emitting monomers, namely, 7-tert-butyl-1,3,5,9-tetrakis(p-R-phenyl)pyrenes, were synthesized by the Suzuki-Miyaura cross-coupling reaction from a novel bromide precursor of 1,3,5,9-tetrabromo-7-tert-butylpyrene. The crystal structures and optical and electronic properties have been investigated.

  DOI：

  10.1021/ol4002653

文献信息

• Blue-Emitting Butterfly-Shaped 1,3,5,9-Tetraarylpyrenes: Synthesis, Crystal Structures, and Photophysical Properties
  作者：Xing Feng、Jian-Yong Hu、Fumitaka Iwanaga、Nobuyuki Seto、Carl Redshaw、Mark R. J. Elsegood、Takehiko Yamato

  DOI：10.1021/ol4002653

  日期：2013.3.15

  The first example of aryl-functionalized, butterfly-shaped, highly fluorescent and stable blue-emitting monomers, namely, 7-tert-butyl-1,3,5,9-tetrakis(p-R-phenyl)pyrenes, were synthesized by the Suzuki-Miyaura cross-coupling reaction from a novel bromide precursor of 1,3,5,9-tetrabromo-7-tert-butylpyrene. The crystal structures and optical and electronic properties have been investigated.