N-苄基-7H-嘌呤-2-胺 | 1456-46-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并嘧啶类
• 中文名称: N-苄基-7H-嘌呤-2-胺
• 英文名称: N-(phenylmethyl)-aminopurine
• 英文别名: L -benzylaminopurine；2-benzylaminopurine；Benzylamino- purine；benzylaminopurin；N-benzyl-7H-purin-2-amine
• CAS: 1456-46-8
• 化学式: C₁₂H₁₁N₅
• 分子量: 225.253
• InChiKey: WYXYBEOWQBGFQB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  66.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  蔗糖 、 、 1-萘乙酸 、 N-苄基-7H-嘌呤-2-胺 、 盐酸大观霉素 生成 大观霉素
  参考文献：
  名称：

  Method of plastid transformation in asteraceae, vector for use therein and plants thus obtained

  摘要：

  本发明涉及一种植物种类质体基因组转化的方法，特别是菊科植物种类，包括以下步骤：提供携带感兴趣的DNA序列的转化载体；将包括质体的植物材料进行转化处理，以使质体接收转化载体；将经过处理的植物材料放置在无选择剂的培养基中一段时间；随后将植物材料放置在含有选择剂的培养基中；并刷新含有选择剂的培养基，以使质体获得感兴趣的DNA的植物材料生长成转化体。

  公开号：

  US20060248608A1
• 作为产物：
  描述：

  苯甲醇钠 、 2-氨基嘌呤 反应 17.0h， 以63%的产率得到N-苄基-7H-嘌呤-2-胺
  参考文献：
  名称：

  Mechanism of Formation of N2-Benzylguanine in the Reaction of 2-Amino-6-chloropurine with Sodium Benzyl Oxide, and Benzylation of Nucleic Acid Bases.

  摘要：

  研究了 2-氨基-6-氯嘌呤与大量过量（12-13 摩尔当量）氧化苄基钠在 130°C 的苄醇中反应生成 N2-苄基鸟嘌呤的机理，分离出了反应中间体 N2、O6-二苄基鸟嘌呤，并讨论了其可能的生成机理。此外，利用这种氧化苄钠体系，还促进了核酸碱基氨基的苄化反应。

  DOI：

  10.1248/cpb.44.1395

文献信息

• AZOLE DERIVATIVE, INTERMEDIATE COMPOUND, METHOD FOR PRODUCING AZOLE DERIVATIVE, AGRICULTURAL OR HORTICULTURAL CHEMICAL AGENT, AND PROTECTIVE AGENT FOR INDUSTRIAL MATERIAL
  申请人：Kureha Corporation

  公开号：US20200288714A1

  公开（公告）日：2020-09-17

  It is provided a plant disease controlling agent having low toxicity to human and animals and excellent handling safety, and showing excellent controlling effects on various plant diseases and high antibiotic action to plant disease germs. A compound represented by the following the general formula (I), or an N-oxide or agrochemically acceptable salt thereof.

  提供一种植物病害控制剂，对人类和动物毒性低，具有出色的操作安全性，在各种植物病害上显示出优秀的控制效果，并对植物病原菌具有高抗生素作用。 由以下一般式（I）表示的化合物，或其N-氧化物或农药可接受的盐。
• [EN] PYRIDINE COMPOUND, PESTICIDAL COMPOSITION AND METHOD OF CONTROLLING PEST<br/>[FR] COMPOSÉ DE PYRIDINE, COMPOSITION PESTICIDE ET PROCÉDÉ DE LUTTE CONTRE LES NUISIBLES
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2009066786A1

  公开（公告）日：2009-05-28

  A pyridine compound represented by the following general formula (1); the pyridine compound in which R1 is a C1-C3 fluoroalkyl group or a C1-C3 fluoroalkoxy group; the pyridine compound in which R2 is a hydrogen atom; the pyridine compound in which R2 is a group represented by Q1; a pesticidal composition containing the pyridine compound as an active ingredient; and a method of controlling a pest including applying an effective amount of the pyridine compound to the pest or a place where the pest inhabits, are provided.

  以下是通用公式（1）表示的吡啶化合物；其中R1是C1-C3氟烷基或C1-C3氟烷氧基的吡啶化合物；其中R2是氢原子的吡啶化合物；其中R2是由Q1表示的基团的吡啶化合物；包含所述吡啶化合物作为活性成分的杀虫剂组合物；以及一种控制害虫的方法，包括向害虫或害虫栖息地施加有效量的吡啶化合物。
• HYDRAZONYL GROUP-CONTAINING CONDENSED HETEROCYCLIC COMPOUND OR SALT THEREOF, AGRICULTURAL AND HORTICULTURAL INSECTICIDE COMPRISING THE COMPOUND, AND METHOD FOR USING THE INSECTICIDE
  申请人：Nihon Nohyaku Co., Ltd.

  公开号：US20190177319A1

  公开（公告）日：2019-06-13

  An object of the present invention is to develop and provide a novel agricultural and horticultural insecticide in view of the still immense damage caused by insect pests etc. and the emergence of insect pests resistant to existing insecticides in crop production in the fields of agriculture, horticulture and the like. Provided is a hydrazonyl group-containing condensed heterocyclic compound or a salt thereof, preferably a condensed heterocyclic compound represented by the general formula (1): wherein R 1 represents, for example, an alkyl group, R 2 represents, for example, a hydrogen atom, R 3 and R 4 each represent, for example, an alkyl group, a haloalkyl group or an acyl group, A 1 represents, for example, a nitrogen atom, A 2 represents, for example, N-Me or an oxygen atom, A 3 represents, for example, a carbon atom or a nitrogen atom, A 4 represents, for example, C—H, m represents, for example, 2, and n represents, for example, 1}, or a salt thereof; an agricultural and horticultural insecticide comprising the compound or a salt thereof as an active ingredient; and a method for using the insecticide.

  本发明的一个目的是开发并提供一种新型农艺和园艺杀虫剂，鉴于昆虫害虫等造成的损害仍然巨大，以及在农业、园艺等领域作物生产中出现的对现有杀虫剂具有抗性的昆虫害虫。 提供了一种含有肼酰基的稠合杂环化合物或其盐，优选为通式(1)表示的稠合杂环化合物： 其中R1代表例如烷基，R2代表例如氢原子，R3和R4各自代表例如烷基、卤代烷基或酰基，A1代表例如氮原子，A2代表例如N-Me或氧原子，A3代表例如碳原子或氮原子，A4代表例如C—H，m代表例如2，n代表例如1}，或其盐；一种包含该化合物或其盐作为活性成分的农艺和园艺杀虫剂；以及使用该杀虫剂的方法。
• HETEROARYLAZOLE COMPOUND AND PEST CONTROL AGENT
  申请人：Nippon Soda Co., Ltd.

  公开号：US20210380556A1

  公开（公告）日：2021-12-09

  An object of the present invention is to provide a heteroaryl azole compound that is excellent in pest control activity, particularly, insecticidal activity and/or miticidal activity, is excellent in safety, and may be industrially advantageously synthesized. The compound of the present invention is a compound represented by the formula (I), an N-oxide compound, stereoisomer, tautomer or hydrate thereof or a salt of any of these compounds. In the formula (I), A represents CH or a nitrogen atom; B 1 represents CX 1 or a nitrogen atom; X 1 , X 2 and X 3 each independently represent a hydrogen atom, a substituted or unsubstituted C1-6 alkyl group, a substituted or unsubstituted C2-6 alkenyl group, or the like; R 1 represents a substituted or unsubstituted C1-6 alkylthio group, a substituted or unsubstituted C1-6 alkylsulfinyl group, or the like; R 2 represents a substituted or unsubstituted C1-6 alkyl group; and R represents a substituted or unsubstituted C1-6 alkyl group.

  本发明的一个目的是提供一种在害虫控制活性方面表现出色，特别是在杀虫活性和/或杀螨活性方面表现出色，安全性优秀，并且可以在工业上有利地合成的杂环芳醇类化合物。本发明的化合物是由式（I）表示的化合物，其N-氧化物化合物，立体异构体，互变异构体或其水合物，或这些化合物的任何盐。在式（I）中，A代表CH或氮原子；B1代表CX1或氮原子；X1，X2和X3分别独立地代表氢原子，取代或未取代的C1-6烷基基团，取代或未取代的C2-6烯基基团，或类似物；R1代表取代或未取代的C1-6烷基硫基团，取代或未取代的C1-6烷基亚硫氧基团，或类似物；R2代表取代或未取代的C1-6烷基基团；R代表取代或未取代的C1-6烷基基团。
• IMINO DERIVATIVES, PROCESS FOR PREPARATION THEREOF, AND INSECTICIDES CONTAINING SAME
  申请人：Kagabu Shinzo

  公开号：US20120277440A1

  公开（公告）日：2012-11-01

  To provide a novel imino derivative capable of being an insecticide compound which is excellent in characteristics such as sustained effects and a broad spectrum. An imino derivative represented by Formula (A) shown below: wherein “Ar” represents a heterocyclic group which may have a substituent on the ring, “X” represents a sulfur atom or CH 2 , NR; “R” represents a hydrogen atom or an alkyl group; “Ya” is selected from “C(═S)NR 1 R 2 ”, “C(═S)SR 3 ”, “C(═O)SR 4 ”, “C(═S)OR 4 ”, “SO 2 Z α ”, and “OZ β ”; and, each of “R 1 ” to “R 4 ”, “Z α ”, and “Z β ” represents a hydrogen atom or a certain substituent; is provided.

  提供一种新型亚胺衍生物，能够作为杀虫剂化合物，具有持久效果和广谱特性。以下是由下式（A）表示的亚胺衍生物： 其中，“Ar”代表可能在环上有取代基的杂环基团，“X”代表硫原子或CH2，NR；“R”代表氢原子或烷基； “Ya”选自“C(═S)NR1R2”，“C(═S)SR3”，“C(═O)SR4”，“C(═S)OR4”，“SO2Zα”，和“OZβ”；每个“R1”到“R4”，“Zα”，和“Zβ”代表氢原子或某种取代基； 已提供。