bis(5-bromosalicylaldehydato)diaquomanganese(II) | 532382-75-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 芳基卤化物
• 英文名称: bis(5-bromosalicylaldehydato)diaquomanganese(II)
• 英文别名: [Mn(Brsal)2(H2O)2]；5-bromo-2-formylphenolate;manganese(2+);dihydrate
• CAS: 532382-75-5
• 化学式: C₁₄H₁₂Br₂MnO₆
• 分子量: 490.992
• InChiKey: JDSDBNCSXNXOMS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  bis(5-bromosalicylaldehydato)diaquomanganese(II) 、 bis(acetophenone)ethylenediamine 以 乙醇 为溶剂， 以78.8%的产率得到bis(5-bromosalicylaldehydato)(bis(acetophenone)ethylenediamine)manganese(II) monohydrate
  参考文献：
  名称：

  Synthesis, Spectral, and Biocidal Studies of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) Mixed‐Ligand Complexes

  摘要：

  Complexes of transition metals with salicylaldehyde (saIH) or 5-bromosalicylaldehyde (Br-salH) in I : 2 molar ratio, have the compositions [M(H2O)(2)(sal)(2)] . H2O (1) or [M(H2O)(2)(Br-sal)(2)] . H2O (2), respectively. The Schiff base derived from ethylenediamine and acetophenone in I : I molar ratio in alcoholic solution yields his(acetophenone)ethylenediamine (acphen). Further reaction of (1) or (2) with acphen in alcohol yielded mixed-ligand complexes of the type [M(sal)(2)acphen] or [M(Br-sal)(2) acphen], respectively. All of these complexes are Soluble in ethanol and methanol. They were characterized on the basis of elemental analyses, magnetic measurements, infrared spectra, electronic spectra, and thermogravimetric analyses. All of these complexes have been screened for their antimicrobial activity against bacteria] strands using the agar diffusion method.

  DOI：

  10.1081/sim-120037513