N-(1-chloroethenyl)-N,N'-bis(2-methoxyphenyl)ethanimidamide | 88046-76-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(1-chloroethenyl)-N,N'-bis(2-methoxyphenyl)ethanimidamide
• 英文别名: N-(1-chloro-vinyl)-N,N'-bis-(2-methoxy-phenyl)-acetamidine；N-(1-Chlor-vinyl)-N,N'-bis-(2-methoxy-phenyl)-acetamidin
• CAS: 88046-76-8
• 化学式: C₁₈H₁₉ClN₂O₂
• 分子量: 330.814
• InChiKey: YITPKNLSUOJRJP-XSFVSMFZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.97
• 重原子数：
  23.0
• 可旋转键数：
  5.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  34.06
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  N-(1-chloroethenyl)-N,N'-bis(2-methoxyphenyl)ethanimidamide 在 氢氧化钾 、 三氯氧磷 作用下， 反应 8.0h， 生成 6-ethoxy-1-(2-methoxyphenyl)-2-(2-methoxyphenylimino)-1,2-dihydropyridine
  参考文献：
  名称：

  Meth-Cohn, Otto; Westwood, Keith T., Journal of the Chemical Society. Perkin transactions I, 1983, p. 2089 - 2092

  摘要：

  DOI：
• 作为产物：
  描述：

  2-乙酰氨基苯甲醚 在 五氯化磷 作用下， 反应 1.0h， 以88%的产率得到N-(1-chloroethenyl)-N,N'-bis(2-methoxyphenyl)ethanimidamide
  参考文献：
  名称：

  Meth-Cohn, Otto; Westwood, Keith T., Journal of the Chemical Society. Perkin transactions I, 1983, p. 2089 - 2092

  摘要：

  DOI：

文献信息

• METH-COHN, O.;WESTWOOD, K. T., J. CHEM. SOC. PERKIN TRANS., 1983, N 9, 2089-2092
  作者：METH-COHN, O.、WESTWOOD, K. T.

  DOI：——

  日期：——
• Taxonomic Characterization of New Alkaliphilic and Alkalitolerant Methanotrophs from Soda Lakes of the Southeastern Transbaikal Region and description of Methylomicrobium buryatense sp.nov.
  作者：Marina Kaluzhnaya、Valentina Khmelenina、Bulat Eshinimaev、Natalia Suzina、Dimitry Nikitin、Alexander Solonin、Ju-Ling Lin、Ian McDonald、Colin Murrell、Yuri Trotsenko

  DOI：10.1078/0723-2020-00028

  日期：2001.1

  Five strains of obligate methanotrophic bacteria (4G, 5G, 6G, 7G and 5B) isolated from bottom sediments of Southeastern Transbaikal soda lakes (pH 9.5-10.5) are taxonomically described. These bacteria are aerobic, Gram-negative monotrichous rods having tightly packed cup-shaped structures on the outer cell wall surface (S-layers) and Type I intracytoplasmic membranes. All the isolates possess particulate methane monooxygenase (pMMO) and one strain (5G) also contains soluble methane monooxygenase (sMMO). They assimilate methane and methanol via the ribulose monophosphate pathway (Rump). The isolates are alkalitolerant or facultatively alkaliphilic, able to grow at pH 10.5-11.0 and optimally at pH 8.5-9.5. These organisms are obligately dependent on the presence of sodium ions in the growth medium and tolerate up to 0.9-1.4 M NaCl or 1 M NaHCO3. Although being mesophilic, all the isolates are resistant to heating (80 degreesC, 20 min), freezing and drying. Their cellular fatty acids profiles primarily consist of C-16:1. The major phospholipids are phosphatidylethanolamine and phosphatidylglycerol. The main quinone is Q-8. The DNA G+C content ranges from 49.2-51.5 mol %. Comparative 16S rDNA sequencing showed that the newly isolated methanotrophs are related to membres of the Methylomicrobium genus. However, they differ from the known members of this genus by DNA-DNA relatedness. Based on pheno- and genotypic characteristics, we propose a new species of the genus Methylomicrobium Methylomicrobium buryatense sp. nov.
• Meth-Cohn, Otto; Westwood, Keith T., Journal of the Chemical Society. Perkin transactions I, 1983, p. 2089 - 2092
  作者：Meth-Cohn, Otto、Westwood, Keith T.

  DOI：——

  日期：——