4-Benzoyl-benzenediazonium; chloride | 3286-16-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-Benzoyl-benzenediazonium; chloride
• 英文别名: 4-Benzoylbenzene-1-diazonium chloride；4-benzoylbenzenediazonium;chloride
• CAS: 3286-16-6
• 化学式: C₁₃H₉N₂O*Cl
• 分子量: 244.68
• InChiKey: YBCJACKEWXMCOG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.41
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  45.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-Benzoyl-benzenediazonium; chloride 在 吡啶 作用下， 生成 1-(4-benzoyl-phenyl)-3-acetyl-3-methyltriazene
  参考文献：
  名称：

  Substituent effects on13C and15N chemical shifts in triazenes studied by principal components multivariate data analysis

  摘要：

  AbstractPrincipal components analysis was applied to the 13C and 15N chemical shift data on a series of fifteen 1‐(para‐substituted‐phenyl)‐3‐acetyl‐3‐methyltriazenes. It was found that the halogen‐substituted triazenes formed a class, based on substituent effects, which was different from the remaining eleven triazenes. A one‐component model described the halogen class, whereas a two‐component model was necessary for a description of the second class. In the second class, substituents tended to cluster to form groups depending on their electronic character.

  DOI：

  10.1002/omr.1270210710
• 作为产物：
  描述：

  4-氨基二苯甲酮 在 sodium nitrite 作用下， 以 盐酸 为溶剂， 生成 4-Benzoyl-benzenediazonium; chloride
  参考文献：
  名称：

  Substituent effects on13C and15N chemical shifts in triazenes studied by principal components multivariate data analysis

  摘要：

  AbstractPrincipal components analysis was applied to the 13C and 15N chemical shift data on a series of fifteen 1‐(para‐substituted‐phenyl)‐3‐acetyl‐3‐methyltriazenes. It was found that the halogen‐substituted triazenes formed a class, based on substituent effects, which was different from the remaining eleven triazenes. A one‐component model described the halogen class, whereas a two‐component model was necessary for a description of the second class. In the second class, substituents tended to cluster to form groups depending on their electronic character.

  DOI：

  10.1002/omr.1270210710

文献信息

• Gold promoted arylative cyclization of alkynoic acids with arenediazonium salts
  作者：Ulises A. Carrillo-Arcos、Susana Porcel

  DOI：10.1039/c7ob02447a

  日期：——

  Alkynoic acids derived from salicylic acid and analogues undergo arylative cyclization with arenediazonium salts promoted by gold in the absence of external ligands. The reaction is thermally induced and proceeds even in the absence of light. A difference in regioselectivity has been found compared with that observed in the cycloisomerization process of the same type of compounds.

  在没有外部配体的情况下，衍生自水杨酸和类似物的炔酸与金所促进的槟榔二唑鎓盐进行芳基环化。该反应是热诱导的，甚至在不存在光的情况下也可以进行。与在相同类型化合物的环异构化过程中观察到的相比，发现了区域选择性的差异。
• SUZUKI, NOBUTAKE;AZUMA, TERUKAZU;NOMOTO, TATEO;IZAWA, YASUJI, CHEM. AND IND., 1985, N 20, 698-699
  作者：SUZUKI, NOBUTAKE、AZUMA, TERUKAZU、NOMOTO, TATEO、IZAWA, YASUJI

  DOI：——

  日期：——
• Substituent effects on13C and15N chemical shifts in triazenes studied by principal components multivariate data analysis
  作者：W. J. Dunn、C. Lins、G. Kumar、T. Manimaran、S. Grigoras、U. Edlund、S. Wold

  DOI：10.1002/omr.1270210710

  日期：1983.7

  AbstractPrincipal components analysis was applied to the 13C and 15N chemical shift data on a series of fifteen 1‐(para‐substituted‐phenyl)‐3‐acetyl‐3‐methyltriazenes. It was found that the halogen‐substituted triazenes formed a class, based on substituent effects, which was different from the remaining eleven triazenes. A one‐component model described the halogen class, whereas a two‐component model was necessary for a description of the second class. In the second class, substituents tended to cluster to form groups depending on their electronic character.
• Murakami, Yasuoki; Tani, Masanobu; Tanaka, Kenjiro, Chemical and pharmaceutical bulletin, 1988, vol. 36, p. 2023 - 2035
  作者：Murakami, Yasuoki、Tani, Masanobu、Tanaka, Kenjiro、Yokoyama, Yuusaku

  DOI：——

  日期：——