2-phenyl-1-methylene-3[13C]-cyclopropane | 552848-77-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-phenyl-1-methylene-3[13C]-cyclopropane
• 英文别名: 3-(13C)-2-phenyl-1-methylenecyclopropane；(2-methylidenecyclopropyl)benzene
• CAS: 552848-77-8
• 化学式: C₁₀H₁₀
• 分子量: 131.178
• InChiKey: UZXGMTRQCZEMNP-CDYZYAPPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-bromo-1-methyl-2-phenyl-3[13C]cyclopropane 在 t-butoxide 作用下， 以 二甲基亚砜 为溶剂， 反应 24.0h， 以47%的产率得到2-phenyl-1-methylene-3[13C]-cyclopropane
  参考文献：
  名称：

  Ni-complex-catalysed addition polymerisation of 2-phenyl-1-methylenecylopropane to afford a polymer with cyclopropylidene groupsElectronic supplementary information (ESI) available: full details of the experimental procedures, DSC and TG profile of I. See http://www.rsc.org/suppdata/cc/b1/b111697e/

  摘要：

  π-烯丙基镍络合物引发了 2-苯基-1-亚甲基环丙烷的加成聚合反应，生成了一种具有三元环的聚合物。

  DOI：

  10.1039/b111697e

文献信息

• Pd-Catalyzed Ring-Opening Copolymerization of 2-Aryl-1-methylenecyclopropanes with CO to Afford Polyketones via Alternating Insertion of the Two Monomers and C−C Bond Activation of the Three-Membered Ring
  作者：Sunwook Kim、Daisuke Takeuchi、Kohtaro Osakada

  DOI：10.1021/ja017460s

  日期：2002.2.1

  Pd-bpy complexes catalyze the ring-opening copolymerization of 2-aryl-1-methylenecyclopropanes with CO, affording the new polyketones composed of ring-opened structural units only. Kinetic and isotope-labeling studies revealed the mechanism of the reaction, which involves 1,2-insertion of the cyclic monomer followed by beta-alkyl elimination of the three-membered ring of the polymer chain.
• Ni-complex-catalysed addition polymerisation of 2-phenyl-1-methylenecylopropane to afford a polymer with cyclopropylidene groupsElectronic supplementary information (ESI) available: full details of the experimental procedures, DSC and TG profile of I. See http://www.rsc.org/suppdata/cc/b1/b111697e/
  作者：Daisuke Takeuchi、Kohtaro Osakada

  DOI：10.1039/b111697e

  日期：2002.3.7

  π-Allyl-nickel complexes initiated addition polymerisation of 2-phenyl-1-methylenecyclopropane to give a polymer with three-membered rings; the formed polymer showed a high Tg and negligible thermal decomposition up to 300 °C.

  π-烯丙基镍络合物引发了 2-苯基-1-亚甲基环丙烷的加成聚合反应，生成了一种具有三元环的聚合物。