苯酚,4-(1,7,7-三甲基二环[2.2.1]庚-2-基)- | 4488-58-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯酚,4-(1,7,7-三甲基二环[2.2.1]庚-2-基)-
• 英文名称: 4-Isobornyl-phenol
• 英文别名: p-Isobornylphenol；para-isobornylphenol；4-(1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl)phenol；4-(1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl)phenol
• CAS: 4488-58-8；17152-81-7
• 化学式: C₁₆H₂₂O
• 分子量: 230.35
• InChiKey: DUDPYRGZUMHGFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,7,7-trimethyl-2-phenoxybicyclo[2.2.1]heptane 生成 苯酚,4-(1,7,7-三甲基二环[2.2.1]庚-2-基)-
  参考文献：
  名称：

  Nalimowa I. Ju., Kutschin A. W., Spirikhin L. W., Lesokhimija i organ. sintes, (1994) , S 37

  摘要：

  DOI：

文献信息

• Alkylation of phenol by β-pinene in the presence of aluminum phenolate
  作者：I. Yu. Chukicheva、O. A. Shumova、A. V. Kuchin

  DOI：10.1007/s10600-012-0154-z

  日期：2012.3

  The alkylation of phenol by β-pinene using Al(OPh)3 as a catalyst was studied. It was found that the composition of the products depended on the ratio of starting materials. The principal products were chromane-type ethers with an equimolar ratio of starting materials and an excess of phenol. ortho-Alkylated phenol and an ether with a terpene substituent of bornyl structure were formed with a two-fold

  以Al(OPh)3为催化剂，研究了β-蒎烯对苯酚的烷基化反应。发现产品的组成取决于原料的比例。主要产品是具有等摩尔比的起始原料和过量苯酚的色烷型醚。邻烷基化苯酚和具有冰片基结构萜烯取代基的醚与两倍过量的β-蒎烯形成。
• Rearrangement of bornyl phenyl ether
  作者：I. Yu. Chukicheva、O. A. Shumova、A. V. Kutchin

  DOI：10.1134/s1070428013070233

  日期：2013.7
• Nalimowa I. Ju., Kutschin A. W., Spirikhin L. W., Lesokhimija i organ. sintes, (1994) , S 37
  作者：Nalimowa I. Ju., Kutschin A. W., Spirikhin L. W.

  DOI：——

  日期：——
• URETHANE ADHESIVE COMPOSITION
  申请人：The Yokohama Rubber Co., LTD.

  公开号：US20220002599A1

  公开（公告）日：2022-01-06

  An object of the present invention is to provide a urethane adhesive composition excellent in adhesion durability for an olefin resin. The present invention is a urethane adhesive composition containing a urethane prepolymer having an isocyanate group, an isocyanurate compound of pentamethylene diisocyanate and/or hexamethylene diisocyanate, and a secondary aminosilane compound.