phenyl diethylamidophenylphosphonite | 24102-75-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyl diethylamidophenylphosphonite
• CAS: 24102-75-8
• 化学式: C₁₆H₂₀NO₂P
• 分子量: 289.314
• InChiKey: QJLQWRRVLNDUSA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.93
• 重原子数：
  20.0
• 可旋转键数：
  6.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  29.54
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  diphenyl-N,N-diethylphosphoramidite 生成 phenyl diethylamidophenylphosphonite
  参考文献：
  名称：

  Pudovik,A.N.; Krupnov,V.K., Journal of general chemistry of the USSR, 1969, vol. 39, p. 1851

  摘要：

  DOI：

文献信息

• Oxidation of phenylphosphonites with aqueous hydrogen peroxide
  作者：A. T. Teleshev、E. N. Mishina、D. A. Ganin、V. Yu. Mishina、I. V. Abrashina、E. E. Nifant’ev、A. S. Kononihin、I. A. Popov、E. N. Nikolaev

  DOI：10.1134/s1070363212080087

  日期：2012.8

  An effective route to the oxidation of organic derivatives of trivalent phosphorus with an aqueous solution of hydrogen peroxide was considered. Phenylphosphonites, including those having a hydrolytically unstable phosphorus-nitrogen bond were involved into the oxidation. The identification of oxidation products, the phenylphosphonates, was carried out using the method of ion cyclotron resonance mass spectrometry with Fourier transform combined with electrospray ionization, and by P-31 and H-1 NMR spectroscopy. The influence of an effective antioxidant of natural origin, quercetin, on the oxidation was demonstrated.