(1-hydroxy-9,10-dioxo-9,10-dihydro-[2]anthryl)-acetic acid | 501661-95-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: (1-hydroxy-9,10-dioxo-9,10-dihydro-[2]anthryl)-acetic acid
• 英文别名: (1-Hydroxy-9,10-dioxo-9,10-dihydro-[2]anthryl)-essigsaeure；2-(1-Hydroxy-9,10-dioxoanthracen-2-yl)acetic acid
• CAS: 501661-95-6
• 化学式: C₁₆H₁₀O₅
• 分子量: 282.252
• InChiKey: CXQXBBPQPHBITA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  91.7
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  (1-hydroxy-9,10-dioxo-9,10-dihydro-[2]anthryl)-acetic acid 生成 1-羟基-2-甲基蒽醌
  参考文献：
  名称：

  Accumulation in Dasuopu ice core in Qinghai-Tibet Plateau and solar activity

  摘要：

  The time series of accumulation in recent 300 years correlated well with solar activity in Dasuopu ice core. Results of spectrum analysis on the accumulation time series of the Dasuopu ice core shows that there are some periods that coincide with the periods of solar activity. By comparing the long-time change trend of the accumulation in the Dasuopu ice core with various kinds of indexes of solar activity intensity, a negative correlation is found between the trend and solar activity.

  DOI：

  10.1007/bf02884987
• 作为产物：
  描述：

  1-羟基蒽醌 在 sodium hydroxide 、 sodium dithionite 作用下， 生成 (1-hydroxy-9,10-dioxo-9,10-dihydro-[2]anthryl)-acetic acid
  参考文献：
  名称：

  Accumulation in Dasuopu ice core in Qinghai-Tibet Plateau and solar activity

  摘要：

  The time series of accumulation in recent 300 years correlated well with solar activity in Dasuopu ice core. Results of spectrum analysis on the accumulation time series of the Dasuopu ice core shows that there are some periods that coincide with the periods of solar activity. By comparing the long-time change trend of the accumulation in the Dasuopu ice core with various kinds of indexes of solar activity intensity, a negative correlation is found between the trend and solar activity.

  DOI：

  10.1007/bf02884987

文献信息

• Observation of heavy atom effects in the development of water soluble caged 4-hydroxy-trans-2-nonenal
  作者：Paul B. Jones、Robert G. Brinson、Saurav J. Sarma、Salwa Elkazaz

  DOI：10.1039/b810954k

  日期：——

  anthraquinonyl chromophore to achieve water solubility, we studied the photochemistry of various substituents to understand their effect on the photochemistry. We observed a significant heavy atom effect that severely reduced the rate of oxidative cleavage of the alkoxy group. Based on the results of our substituent study, we designed a new caged 4-HNE that is soluble under physiological conditions, and

  在我们研究1-烷氧基-9,10-蒽醌的光化学过程中，我们开发了第二代笼状的4-羟基-反式-2-壬烯醛（4-HNE）。当我们优化蒽醌基生色团以达到水溶性时，我们研究了各种取代基的光化学，以了解它们对光化学的影响。我们观察到了显着的重原子效应，该效应严重降低了烷氧基的氧化裂解速率。根据我们对取代基的研究结果，我们设计了一种新的笼状4-HNE，该笼在生理条件下可溶，并且可以高产率光化学释放4-HNE。
• Marschalk, Bulletin de la Societe Chimique de France, 1942, vol. <5> 9, p. 801,803
  作者：Marschalk

  DOI：——

  日期：——
• Marschalk, Bulletin de la Societe Chimique de France, 1942, vol. <5> 9, p. 826,829
  作者：Marschalk

  DOI：——

  日期：——