1,8-perinaphthalene-(3H,7H)-naphthol<1,8-de>-1,2-dithiepin | 75574-98-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,8-perinaphthalene-(3H,7H)-naphthol<1,8-de>-1,2-dithiepin
• 英文别名: 3H,7H-naphtho<1,8-de>-1,2-dithiepin；3H,7H-naphtho(1,8-de)-1,2-dithiepin；11,12-dithiatricyclo[7.4.1.05,14]tetradeca-1,3,5(14),6,8-pentaene
• CAS: 75574-98-0
• 化学式: C₁₂H₁₀S₂
• 分子量: 218.343
• InChiKey: GSNROYHKXDJENG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,8-双(溴甲基)萘 在 sodium hydroxide 、 三氯化铁 作用下， 以 乙醚 、 乙醇 、 水 、 溶剂黄146 、 异丙醇 为溶剂， 反应 62.0h， 生成 1,8-perinaphthalene-(3H,7H)-naphthol<1,8-de>-1,2-dithiepin
  参考文献：
  名称：

  Molecules with a helix structure. 3. Sulfur-bridged peri-naphthalenes: synthesis, conformational analysis, and photoelectron spectroscopy of the mono-, di-, and trisulfides of 1,8-dimethylnaphthalene

  摘要：

  DOI：

  10.1021/ja00391a029

文献信息

• Redox-active reversible electrode and secondary battery using the same
  申请人：Oyama Noboru

  公开号：US20070026310A1

  公开（公告）日：2007-02-01

  A redox-active reversible electrode has a redox-active film on a surface of an electrically conductive substrate. The redox-active film includes a redox-active sulfur-containing substance which has at least one aromatic ring and a ring containing at least one disulfide bond, with a side of the disulfide-containing ring constituting a side of the aromatic ring, and which has a property that it is capable of reversibly releasing and receiving one or more electrons per disulfide-containing ring without the disulfide-containing ring being opened.