N-methyl-N-(pentacosa-10,12-diyn)-propylamine | 1251457-02-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-methyl-N-(pentacosa-10,12-diyn)-propylamine
• 英文别名: N-methyl-N-propylpentacosa-10,12-diyn-1-amine
• CAS: 1251457-02-9
• 化学式: C₂₉H₅₃N
• 分子量: 415.747
• InChiKey: IXAHAKUAJXAFAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.9
• 重原子数：
  30
• 可旋转键数：
  22
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  10,12-二十五碳二炔酸 在 4-二甲氨基吡啶 、 lithium aluminium tetrahydride 、 sodium carbonate 、 三乙胺 作用下， 以 四氢呋喃 、 二氯甲烷 、 乙腈 为溶剂， 反应 25.75h， 生成 N-methyl-N-(pentacosa-10,12-diyn)-propylamine
  参考文献：
  名称：

  Fine-Tuning the Morphology of Self-Assembled Nanostructures of Propargyl Ammonium-Based Amphiphiles

  摘要：

  N-Methyl-N-(pentacosa-10,12-diyn)-propargylamine organizes itself into an unusual supramolecular pH- and thermo-responsive system. Studies have showed that submillimetric length hollow laths form this unique structure in the presence of hydrochloric acid. Specific chemical modifications on the initial molecule and small-angle neutron scattering experiments were performed to understand the structure of this system. Our results allow us to suggest a possible structure of the laths.

  DOI：

  10.1021/jp104911e

文献信息

• Fine-Tuning the Morphology of Self-Assembled Nanostructures of Propargyl Ammonium-Based Amphiphiles
  作者：Emmanuelle Morin、Jean-Michel Guenet、David D. Díaz、Jean-Serge Remy、Alain Wagner

  DOI：10.1021/jp104911e

  日期：2010.10.7

  N-Methyl-N-(pentacosa-10,12-diyn)-propargylamine organizes itself into an unusual supramolecular pH- and thermo-responsive system. Studies have showed that submillimetric length hollow laths form this unique structure in the presence of hydrochloric acid. Specific chemical modifications on the initial molecule and small-angle neutron scattering experiments were performed to understand the structure of this system. Our results allow us to suggest a possible structure of the laths.