N-(1-butylcyclohexyl)hydroxylamine | 114635-73-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(1-butylcyclohexyl)hydroxylamine
• CAS: 114635-73-3
• 化学式: C₁₀H₂₁NO
• 分子量: 171.283
• InChiKey: FPKAWTGMMKSQHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  32.3
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(1-butylcyclohexyl)hydroxylamine 在 三乙胺 作用下， 以 四氢呋喃 、 乙酸乙酯 为溶剂， 反应 25.0h， 生成 2-butyl-1-azacycloheptene
  参考文献：
  名称：

  Carbon-to-nitrogen rearrangement in N-(arylsulfonoxy)amines as a route to azacyclic compounds

  摘要：

  DOI：

  10.1021/jo00249a034
• 作为产物：
  描述：

  1-butyl-1-nitrocyclohexane 在 氯化铵 、 锌 作用下， 以80%的产率得到N-(1-butylcyclohexyl)hydroxylamine
  参考文献：
  名称：

  Carbon-to-nitrogen rearrangement in N-(arylsulfonoxy)amines as a route to azacyclic compounds

  摘要：

  DOI：

  10.1021/jo00249a034

文献信息

• CROSSLINKABLE RUBBER COMPOSITION AND CROSSLINKED RUBBER
  申请人：Zeon Corporation

  公开号：EP2902437A1

  公开（公告）日：2015-08-05

  A cross-linkable rubber composition containing a carboxyl group-containing nitrile rubber (A) with an iodine value of 120 or less, a polyamine cross-linking agent (B), and a specific basic cross-linking accelerator (C) is provided. The basic cross-linking accelerator (C) is preferably dicyclopentylamine or dicyclohexylamine.

  提供了一种可交联橡胶组合物，其中包含碘值在 120 或以下的含羧基丁腈橡胶（A）、多胺交联剂（B）和特定的碱性交联促进剂（C）。碱性交联促进剂（C）最好是二环戊胺或二环己胺。
• CROSS-LINKABLE NITRILE RUBBER COMPOSITION AND CROSS-LINKED RUBBER
  申请人：Zeon Corporation

  公开号：EP3101065A1

  公开（公告）日：2016-12-07

  A cross-linkable nitrile rubber composition comprising a carboxyl group-containing nitrile rubber (A) with an iodine value of 120 or less, polyamine cross-linking agent (B), and at least one compound (C) selected from an aliphatic alcohol (c1) having 1 to 9 carbon atoms, hydroxyl group-containing aromatic compound (c2), and nitrogen-containing heterocyclic compound (c3) is provided.

  本发明提供了一种可交联丁腈橡胶组合物，该组合物包含碘值在 120 或以下的含羧基丁腈橡胶（A）、多胺交联剂（B）以及至少一种选自具有 1 至 9 个碳原子的脂肪醇（c1）、含羟基的芳香族化合物（c2）和含氮杂环化合物（c3）的化合物（C）。
• NITRILE-GROUP-CONTAINING COPOLYMER RUBBER, CROSSLINKABLE RUBBER COMPOSITION, AND CROSSLINKED RUBBER
  申请人：Zeon Corporation

  公开号：EP3176190A1

  公开（公告）日：2017-06-07

  A nitrile group-containing copolymer rubber containing α,β-ethylenically unsaturated nitrile monomer units in a ratio of 10 to 60 wt% and having a Z-average radius of gyration of 100 nm or more is provided. Preferably, the nitrile group-containing copolymer rubber of the present invention has an iodine value of 120 or less. Further, preferably, the nitrile group-containing copolymer rubber of the present invention has a plasticity number of 14 to 90. According to the present invention, it is possible to provide a nitrile group-containing copolymer rubber able to give a cross-linked rubber excellent in tensile stress, compression set resistance, and low heat buildup property.

  本发明提供了一种含腈基团的共聚橡胶，它含有α，β-乙烯基不饱和腈单体单元，其比例为 10 至 60 wt%，Z 平均回转半径为 100 nm 或更大。优选地，本发明的含腈基共聚橡胶的碘值为 120 或更低。此外，优选地，本发明的含腈基共聚橡胶的塑性数为 14 至 90。根据本发明，可以提供一种含腈基团的共聚橡胶，该橡胶能够提供一种在拉伸应力、抗压缩永久变形和低热积聚特性方面性能优异的交联橡胶。
• CROSSLINKABLE NITRILE RUBBER COMPOSITION AND RUBBER CROSSLINKED PRODUCT
  申请人：Zeon Corporation

  公开号：EP3208302A1

  公开（公告）日：2017-08-23

  A cross-linkable nitrile rubber composition comprising a nitrile rubber (a) containing 0.1 to 15 wt% of α,β-ethylenically unsaturated nitrile monomer units, 1 to 10 wt% of α,β-ethylenically unsaturated dicarboxylic acid monoester monomer units, 40 to 75 wt% of α,β-ethylenically unsaturated monocarboxylic acid ester monomer units, and 20 to 58.9 wt% of diene monomer units and/or α-olefin monomer units, and a polyamine-based cross-linking agent (b), wherein a ratio of content of the polyamine-based cross-linking agent (b) with respect to 100 parts by weight of the nitrile rubber (a) is 0.1 to 20 parts by weight is provided.

  一种可交联丁腈橡胶组合物，包括含有 0.1 至 15 wt％的α，β-乙烯基不饱和丁腈单体单元、1 至 10 wt％的α，β-乙烯基不饱和二羧酸单酯单体单元、40 至 75 wt％的α，β-乙烯基不饱和单羧酸酯单体单元以及 20 至 58.9 wt%的二烯单体单元和/或 α-烯烃单体单元，以及聚胺基交联剂 (b)，其中聚胺基交联剂 (b) 相对于 100 份（重量）丁腈橡胶 (a) 的含量比为 0.1 至 20 份（重量）。
• NITRILE RUBBER COMPOSITION, HIGHLY SATURATED NITRILE RUBBER LATEX COMPOSITION, AND CROSSLINKED RUBBER
  申请人：Zeon Corporation

  公开号：EP3225658A1

  公开（公告）日：2017-10-04

  A nitrile rubber composition comprising a highly saturated nitrile rubber (A) containing α,β-ethylenically unsaturated nitrile monomer units in a ratio of 8 to 60 wt% and having an iodine value of 120 or less and an alkylated phenol compound (B), wherein a ratio of content of the alkylated phenol compound (B) with respect to a total of the highly saturated nitrile rubber (A) and the alkylated phenol compound (B) is 0.01 to 1 wt%, and a difference (η2-η1) between a plasticity number η2 after storage at 70°C for 7 days in a state of an aqueous dispersion by being dispersed in water and a plasticity number η1 before the storage is 12 or less is provided.

  一种丁腈橡胶组合物，包括含有α，β-乙烯基不饱和丁腈单体单元的高饱和丁腈橡胶(A)，其比例为8至60重量％，且碘值为120或更低，以及烷基化苯酚化合物(B)，其中烷基化苯酚化合物(B)的含量与高饱和丁腈橡胶(A)和烷基化苯酚化合物(B)的总含量之比为0.01至1 wt%，且在70°C下以分散于水中的水分散状态储存7天后的塑性数η2与储存前的塑性数η1之间的差值(η2-η1)为12或更小。