3-(2,2'-bipyridine-6-yl)-4-phenyl-5-[6-(4-tert-butylphenyl)pyridine-2-yl]-1,2,4-triazole | 908344-01-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 3-(2,2'-bipyridine-6-yl)-4-phenyl-5-[6-(4-tert-butylphenyl)pyridine-2-yl]-1,2,4-triazole
• 英文别名: 2-(4-tert-butylphenyl)-6-[4-phenyl-5-(6-pyridin-2-ylpyridin-2-yl)-1,2,4-triazol-3-yl]pyridine
• CAS: 908344-01-4
• 化学式: C₃₃H₂₈N₆
• 分子量: 508.626
• InChiKey: VDXUPKPAALQZPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  39
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  69.4
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  3-(2,2'-bipyridine-6-yl)-4-phenyl-5-(6-bromopyridine-2-yl)-1,2,4-triazole 、 4-叔丁基苯硼酸 在 四(三苯基膦)钯 potassium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 3.0h， 以81%的产率得到3-(2,2'-bipyridine-6-yl)-4-phenyl-5-[6-(4-tert-butylphenyl)pyridine-2-yl]-1,2,4-triazole
  参考文献：
  名称：

  COMPOUND HAVING TRIAZOLE RING STRUCTURE SUBSTITUTED WITH PYRIDYL GROUP AND ORGANIC ELECTROLUMINESCENT DEVICE

  摘要：

  公开号：

  EP1942107B1

文献信息

• BIPIRIDINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE ELEMENT CONTAINING THE SAME
  申请人：Kimura Masato

  公开号：US20100327265A1

  公开（公告）日：2010-12-30

  The present invention provides a new bipyridine derivative which is suitable for an electron transport material of an organic electronics element and which has bipyridyl central rings as a core, and further provides an organic electroluminescence element containing the derivative. The bipyridine derivative is expressed by the following general formula. (where A 1 , A 2 : represent an aromatic heterocyclic group (except for a carbazolyl group) and an aromatic hydrocarbon group and the aromatic heterocyclic group may be combined; a, b=1 or 2; Ar 1 , Ar 2 : represent a divalent or trivalent aromatic hydrocarbon group which may be substituted by hydrogen atom, an alkyl group, a cycloalkyl group, or an alkoxy group; B 1 , B 2 : represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, an aromatic hydrocarbon group, or an aromatic heterocyclic group; and ring E 1 , ring E 2 : represent a pyridine ring, and may have hydrogen atom, an alkyl group, a cycloalkyl group, or an alkoxy group.), which is used as an electron transport material.

  本发明提供了一种新的联吡啶衍生物，适用于有机电子元件的电子传输材料，并且以联吡啶中心环为核心，并进一步提供了含有该衍生物的有机电致发光元件。该联吡啶衍生物由以下通用公式表示（其中A1、A2：表示芳香杂环基团（除了羰基苯胺基团）和芳香烃基团，芳香杂环基团可以结合；a、b=1或2；Ar1、Ar2：表示可以被氢原子、烷基基团、环烷基基团或烷氧基取代的二价或三价芳香烃基团；B1、B2：表示氢原子、烷基基团、环烷基基团、烷氧基、芳香烃基团或芳香杂环基团；环E1、环E2：表示吡啶环，并且可能带有氢原子、烷基基团、环烷基基团或烷氧基），该衍生物用作电子传输材料。
• ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE, AND LIGHTING DEVICE
  申请人：KONICA MINOLTA, INC.

  公开号：US20160285008A1

  公开（公告）日：2016-09-29

  An object of the present invention is to provide an organic electroluminescent element which has a high luminous efficiency and an excellent driving voltage and exhibits excellent stability, and a display device and a lighting device that are equipped with the organic electroluminescent element. The organic electroluminescent element of the present invention is an organic electroluminescent element which includes at least an electron injection layer, an electron transport layer, and a luminous layer between a positive electrode and a negative electrode and in which the electron injection layer contains an electride, the electron transport layer contains an organic compound having a nitrogen atom, at least one of the nitrogen atoms has a lone pair of electrons that does not participate in aromaticity, and the lone pair of electrons does not coordinate a metal.
• COMPOUND HAVING TRIAZOLE RING STRUCTURE SUBSTITUTED WITH PYRIDYL GROUP AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：EP1942107B1

  公开（公告）日：2014-03-05