[Ag(dppb)2](methanesulfonate) | 1167983-53-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ag(dppb)2](methanesulfonate)
• CAS: 1167983-53-0
• 化学式: CH₃O₃S*C₅₆H₅₆AgP₄
• 分子量: 1055.92
• InChiKey: WYLMTQFQDLJYBC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  11.22
• 重原子数：
  66.0
• 可旋转键数：
  8.0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  57.2
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  [Ag(dppp)(O3SMe)]2 以 二氯甲烷 为溶剂， 生成 [Ag(dppb)2](methanesulfonate)
  参考文献：
  名称：

  Silver(I) methanesulfonate complexes containing diphosphine ligands: Spectroscopic and structural characterization

  摘要：

  1:1 and 2:1 adducts of diphosphine ligands R2P(R')(n)PR2 (dppm: R = Ph, R' = CH2, n = 1; dppe: R = Ph, R' = CH2, n = 2; dppp: R = Ph, R' = CH2, n = 3; dppb: R = Ph, R' = CH2, n = 4; dppf: R = Ph, R' = ferrocenyl, n = 1) with silver( I) methanesulfonate have been synthesized and characterized both in solution (H-1, P-31 NMR) and in the solid state (IR, single crystal X-ray structure analysis). The two different stoichiometries have been found to depend on the molar ratio of ligand to metal employed and the nature of the diphosphine ligand. In AgO3SMe: dppp, dppb (1:1)(2), in the [Ag(P boolean AND P)(2)Ag] arrays, the silver atoms are also bridged by anion oxygen atoms, in disparate fashion commensurate with the different Ag center dot center dot center dot Ag distances. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.02.036