2-(Bromobenzyl)styrene | 161041-06-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(Bromobenzyl)styrene
• 英文别名: 1-[Bromo(phenyl)methyl]-2-ethenylbenzene
• CAS: 161041-06-1
• 化学式: C₁₅H₁₃Br
• 分子量: 273.172
• InChiKey: SCIUOEJDCYHAOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  二甲胺 、 2-(Bromobenzyl)styrene 在 氢氧化钾 作用下， 以 苯 为溶剂， 以53%的产率得到2-<2-(N,N-Dimethylamino)benzyl>styrene
  参考文献：
  名称：

  Generation, Detection, and Reaction of Ammonium Ylides in Reactions of [2-[(Dimethylamino)alkyl]phenyl]phenylcarbenes

  摘要：

  Generation of diphenylcarbene (DPC) bearing a 2-(N,N-dimethylamino)methyl group in CHCl3 produced (N,N-dimethylamino)phenylisoindolium chloride and dichlorocarbene, which was trapped by added cyclohexene, while DPC having a 2-(N,N-dimethylamino)ethyl group afforded not only 3-phenyl-4-(N,N-dimethylamino)indane but also 2-[2-(N,N-dimethylamino)benzyl]styrene.

  DOI：

  10.1021/jo00110a037
• 作为产物：
  描述：

  phenyl(2-vinylphenyl)methanol 在 吡啶 、 三溴化磷 作用下， 以 苯 为溶剂， 反应 1.0h， 以96%的产率得到2-(Bromobenzyl)styrene
  参考文献：
  名称：

  Generation, Detection, and Reaction of Ammonium Ylides in Reactions of [2-[(Dimethylamino)alkyl]phenyl]phenylcarbenes

  摘要：

  Generation of diphenylcarbene (DPC) bearing a 2-(N,N-dimethylamino)methyl group in CHCl3 produced (N,N-dimethylamino)phenylisoindolium chloride and dichlorocarbene, which was trapped by added cyclohexene, while DPC having a 2-(N,N-dimethylamino)ethyl group afforded not only 3-phenyl-4-(N,N-dimethylamino)indane but also 2-[2-(N,N-dimethylamino)benzyl]styrene.

  DOI：

  10.1021/jo00110a037

文献信息

• Generation, Detection, and Reaction of Ammonium Ylides in Reactions of [2-[(Dimethylamino)alkyl]phenyl]phenylcarbenes
  作者：Hideo Tomioka、Sumiyo Yamada、Katsuyuki Hirai

  DOI：10.1021/jo00110a037

  日期：1995.3

  Generation of diphenylcarbene (DPC) bearing a 2-(N,N-dimethylamino)methyl group in CHCl3 produced (N,N-dimethylamino)phenylisoindolium chloride and dichlorocarbene, which was trapped by added cyclohexene, while DPC having a 2-(N,N-dimethylamino)ethyl group afforded not only 3-phenyl-4-(N,N-dimethylamino)indane but also 2-[2-(N,N-dimethylamino)benzyl]styrene.