苯酸异癸酯 | 120657-54-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯酸异癸酯
• 中文别名: 8-甲基壬基苯甲酸酯
• 英文名称: isodecyl benzoate
• 英文别名: 8-methylnonyl benzoate
• CAS: 120657-54-7
• 化学式: C₁₇H₂₆O₂
• 分子量: 262.392
• InChiKey: HNDYULRADYGBDU-UHFFFAOYSA-N

物化性质

• LogP：
  6.554 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  19
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  异十醇 、 苯甲酰氯 在 三乙胺 作用下， 反应 2.0h， 生成 苯酸异癸酯
  参考文献：
  名称：

  [EN] ASYMMETRIC CYCLIC DIESTER COMPOUNDS
  [FR] COMPOSÉS DIESTERS CYCLIQUES ASYMÉTRIQUES

  摘要：

  本文披露了作为增塑剂有用的化合物及其合成方法。一般来说，该发明包括混合烷基/芳基不对称环状二酯，其中芳基和烷基酯基连接到环状结构的邻位碳上。该发明还包括制备这类化合物的合成过程。这些不对称环状二酯与其他增塑剂的混合物被证明在增塑聚合物中具有用途。

  公开号：

  WO2011071674A1

文献信息

• SUNSCREEN COSMETIC COMPOSITION
  申请人：Shiseido Company, Limited

  公开号：EP1944012A1

  公开（公告）日：2008-07-16

  The present invention is a sunscreen cosmetic comprising 2,4-bis [[4-(2-ethylhexyloxy)-2-hydroxy] phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine and a specific benzotriazole derivative. Also, the present invention is a sunscreen cosmetic comprising a specific benzotriazole derivative and a specific alkylaryl 1,3-propanedione silicone derivative. An object of the present invention is to provide a sunscreen cosmetic that exhibits superior UV-A absorption capacity and excellent stability and also sufficiently dissolves 2,4-bis [[4-(2-ethylhexyloxy)-2-hydroxy] phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine, which has low solubility and crystallizes easily. Another object is to provide a sunscreen cosmetic that can synergistically improve the ultraviolet absorption capacity of conventional ultraviolet absorbents.

  本发明是一种防晒化妆品，包括2,4-双[[4-(2-乙基己氧基)-2-羟基]苯基]-6-(4-甲氧基苯基)-1,3,5-三嗪和一种特定的苯并三唑衍生物。此外，本发明是一种防晒化妆品，包括一种特定的苯并三唑衍生物和一种特定的烷基芳基1,3-丙二酮硅氧烷衍生物。本发明的目的是提供一种具有优越的UV-A吸收能力和优异稳定性的防晒化妆品，同时充分溶解2,4-双[[4-(2-乙基己氧基)-2-羟基]苯基]-6-(4-甲氧基苯基)-1,3,5-三嗪，该化合物溶解度低且容易结晶。另一个目的是提供一种可以协同改善传统紫外线吸收剂的紫外线吸收能力的防晒化妆品。
• [EN] PROCESSES FOR THE PRODUCTION OF ESTERS<br/>[FR] PROCÉDÉS DE PRODUCTION D'ESTERS
  申请人：EXXONMOBIL CHEM PATENTS INC

  公开号：WO2012025308A1

  公开（公告）日：2012-03-01

  A process for production of C4 to C15 esters by the esterification of a carboxylic acid or anhydride with a C4 to C15 alcohol including forming a reaction mixture of the acid or anhydride and the C4 to C15 alcohol including a stoichiometric excess of the alcohol and bringing the mixture to reaction temperature by providing an energy supply to the reaction to cause the mixture to react wherein initially the energy supply is reduced to reduce foaming and optionally the energy supply is subsequently increased to enhance reaction time.

  通过将羧酸或酐与C4至C15醇酯化，生产C4至C15酯的工艺包括形成酸或酐和C4至C15醇的反应混合物，其中包括醇的化学计量过剩，并通过向反应提供能量供应使混合物达到反应温度以引起混合物反应的步骤，其中最初减少能量供应以减少起泡，随后可选择增加能量供应以增强反应时间。
• TETRAHYDROFURAN DERIVATIVES AND USE THEREOF AS PLASTICIZERS
  申请人：BASF SE

  公开号：US20160075671A1

  公开（公告）日：2016-03-17

  The invention relates to tetrahydrofuran derivatives of general formula (I), wherein X stands for *—(C═O)—O—, *—(CH2)n-O—, or *—(CH2)n-O—(C═O)—, wherein * represents the point of bonding to the tetrahydrofuran ring and n has the value 0, 1, or 2; and R1 and R2 are selected independently of each other from among C4-C5 alkyl and C5-C6 cycloalkyl, wherein the cycloalkyl groups are unsubstituted or can be substituted by at least one C1-C10 alkyl group, a plasticizer composition that contains said tetrahydrofuran derivatives, molding masses that contain a thermoplastic polymer or an elastomer and such a tetrahydrofuran derivative. The invention further relates to a method for producing said tetrahydrofuran derivatives, and to the use of said tetrahydrofuran derivatives

  该发明涉及一般式(I)的四氢呋喃衍生物，其中X代表*—(C═O)—O—、*—(CH2)n-O—或*—( )n-O—(C═O)—，其中*代表与四氢呋喃环的连接点，n的值为0、1或2；R1和R2分别从C4-C5烷基和C5-C6环烷基中独立选择，其中环烷基可以是未取代的或可以被至少一个C1-C10烷基基团取代，含有所述四氢呋喃衍生物的增塑剂组合物，含有热塑性聚合物或弹性体以及该四氢呋喃衍生物的成型物料。该发明还涉及制备所述四氢呋喃衍生物的方法，以及使用所述四氢呋喃衍生物。
• 2,5-FURAN DICARBOXYLATE DERIVATIVES, AND USE THEREOF AS PLASTICIZERS
  申请人：Grass Michael

  公开号：US20120220507A1

  公开（公告）日：2012-08-30

  The invention relates to mixtures of isononyl furan-2,5-dicarboxylate of formula (I), methods for producing said mixtures of isononyl furan-2,5-dicarboxylate of formula (I), compositions containing mixtures of isononyl furan-2,5-dicarboxylate of formula (I), uses of the mixtures of isononyl furan-2,5-dicarboxylate of formula (I) as plasticizers, and uses of the aforementioned compositions containing isononyl furan-2,5-dicarboxylate of formula (I).

  该发明涉及式(I)的异壬基呋喃-2,5-二羧酸酯的混合物，制备该异壬基呋喃-2,5-二羧酸酯混合物的方法，含有该异壬基呋喃-2,5-二羧酸酯混合物的组合物，以及将该异壬基呋喃-2,5-二羧酸酯混合物用作增塑剂的用途，以及含有该异壬基呋喃-2,5-二羧酸酯的前述组合物的用途。
• [EN] A PLASTICIZER COMPOSITION COMPRISING DI(2-ETHYLHEXYL) TEREPHTHALATE<br/>[FR] COMPOSITION DE PLASTIFIANT COMPRENANT DU TÉRÉPHTALATE DE DI(2-ÉTHYLHEXYLE)
  申请人：BASF SE

  公开号：WO2015126391A1

  公开（公告）日：2015-08-27

  A plasticizer composition is disclosed that includes di(2-ethylhexyl) terephthalate, and which is substantially free of a di-ester according to Formula I: (I), where R1 is a straight-chain or branched alkyl group having from 1 to 13 carbon atoms, and where R1 is different than 2-ethylhexane. The plasticizer composition may be used in a plastisol composition, a powder coating composition, a molding composition, and various other compositions. A method of preparing an aromatic di- ester is also disclosed. The method may prepare the plasticizer composition.

  本发明揭示了一种塑化剂组合物，包括二(2-乙基己基)对苯二甲酸酯，且该组合物基本不含有根据公式I的二酯，其中R1是具有1到13个碳原子的直链或支链烷基，且R1不同于2-乙基己烷。该塑化剂组合物可用于浆料组合物、粉末涂料组合物、模塑组合物和各种其他组合物中。本发明还揭示了一种制备芳香族二酯的方法。该方法可以制备塑化剂组合物。