1,1,5,5-四氯戊烷 | 17655-64-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 1,1,5,5-四氯戊烷
• 英文名称: 1,1,5,5-Tetrachlor-pentan
• 英文别名: 1,1,5,5-Tetrachloropentane
• CAS: 17655-64-0
• 化学式: C₅H₈Cl₄
• 分子量: 209.931
• InChiKey: HLBIYQWEHNPODY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,1,5-三氯-1-戊烯 在 三氯化铁 作用下， 生成 1,1,5,5-四氯戊烷
  参考文献：
  名称：

  Introduction of the CCl2=CHCH2 grouping into unsaturated molecules containing a 2,2-dichlorovinyl group

  摘要：

  DOI：

  10.1007/bf00843803

文献信息

• Zwitterion-functionalized multicomponent copolymers and associated polymer blends and membranes
  申请人：General Electric Company

  公开号：US10851241B2

  公开（公告）日：2020-12-01

  Multicomponent copolymers including two or more types of repeat units is presented. In one example, the multicomponent copolymer includes at least one repeat unit AC having a structure (I), at least one repeat unit DC having a structure (II), and at least one repeat unit BC having a structure (III) or (V). The multicomponent copolymer may be cross-linked via a cross-linking agent. A polymer blend including the multicomponent copolymer or a cross-linked copolymer and a second polymer is also provided. The multicomponent copolymer may be a random or a block copolymer. The structural units of the multicomponent copolymers provide improved, tunable properties, such as improved biocompatibility and hydrophilicity, protein fouling, and mechanical properties, to the copolymers and/or the membranes fabricated from the copolymers.

  本文介绍了包括两种或多种类型重复单元的多组分共聚物。在一个例子中，多组分共聚物包括至少一个具有结构（I）的重复单元 AC、至少一个具有结构（II）的重复单元 DC 和至少一个具有结构（III）或（V）的重复单元 BC。多组分共聚物可通过交联剂进行交联。还可提供一种聚合物混合物，包括多组分共聚物或交联共聚物和第二种聚合物。多组分共聚物可以是无规共聚物或嵌段共聚物。多组分共聚物的结构单元为共聚物和/或用共聚物制造的膜提供了改进的可调特性，如改进的生物相容性和亲水性、蛋白质堵塞和机械特性。
• Rearrangement of polychloroalkyl radicals with the 1,5-migration of hydrogen during the reduction of 1,1,1,5-tetrachloro- and 1,1,1-trichloropentanes
  作者：T. T. Vasil'eva、L. N. Goncharova、R. Kh. Freidlina

  DOI：10.1007/bf01152729

  日期：1977.5
• Reactivity of certain hydrogen donors and olefins with respect to ?,?-dichloroalkyl radicals
  作者：L. V. Il'inskaya、R. G. Gasanov

  DOI：10.1007/bf00961494

  日期：1990.8

  The rate constants of hydrogen splitting from hydrogen donors (DH) by the ClCH2(CH2)3CCl2 radicals (R1) were determined by the method of competitive kinetics in the temperature range of 413-433 K. As a competing reaction with splitting of hydrogen from the DH, the isomerization of radicals R1 into ClCH(CH2)3CCl2H radicals with 1,5-migration of hydrogen was chosen, for which log k (sec-1) = 9.343 - 10.56/2,303RT (kcal/mole) was calculated. It was found that the relative reactivities are similar of R1 and (CH3)3CO radicals (R4) in splitting hydrogen from HD. This makes it possible to predict the values of analogous constants for radicals R1 from known rate constants of splitting hydrogen from various DH by radicals R4. The rate constants of the addition of Cl(CH2)2CCl2 radicals (R2) to alpha-methylstyrene and methyl methacrylate were determined. Taking into account the data in [7], where the same constants were determined for styrene, methyl acrylate, acrylonitrile and vinyl methyl ketone, the existence of a linear dependence was shown of the logarithm of the rate constant of the addition of radicals R2 to olefins on the polar properties of the above-enumerated olefins.
• MAILLARD B.; KHARRAT A.; GARDRAT C., NOUV. J CHIM., 10,(1986) N 4-5, 259-264
  作者：MAILLARD B.、 KHARRAT A.、 GARDRAT C.

  DOI：——

  日期：——
• ZWITTERION-FUNCTIONALIZED MULTICOMPONENT COPOLYMERS AND ASSOCIATED POLYMER BLENDS AND MEMBRANES
  申请人：Cytiva Sweden AB

  公开号：EP3794056A1

  公开（公告）日：2021-03-24