3'-Hydroxy-2-methyl-acrylanilid | 14473-49-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3'-Hydroxy-2-methyl-acrylanilid
• 英文别名: 3'-Hydroxymethacrylanilid；3'-hydroxy-2-methylacrylanilide；3-methacryloylaminophenol；N-(3-hydroxyphenyl)methacrylamide；N-(3-hydroxyphenyl)-2-methylprop-2-enamide
• CAS: 14473-49-5
• 化学式: C₁₀H₁₁NO₂
• 分子量: 177.203
• InChiKey: VAVZHSBOROHMQD-UHFFFAOYSA-N

物化性质

• 熔点：
  171-173 °C
• 沸点：
  387.5±34.0 °C(Predicted)
• 密度：
  1.190±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  49.3
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  叔辛基异氰酸酯 、 3'-Hydroxy-2-methyl-acrylanilid 在 三乙胺 作用下， 以 正己烷 、 乙酸乙酯 、 苯 为溶剂， 生成 3'-(1,1,3,3-tetramethylbutylcarbamoyloxy)-2-methylacrylanilide
  参考文献：
  名称：

  Meta-bifunctional benzenes and herbicidal compositions

  摘要：

  通式##EQU1##中的元双功能化合物，其中A选自##EQU2##这些化合物具有除草活性。

  公开号：

  US03979202A1
• 作为产物：
  描述：

  3-氨基苯酚 、 甲基丙烯酸酐 在 ice 、 水 、 乙腈 作用下， 以 水 为溶剂， 反应 2.0h， 生成 3'-Hydroxy-2-methyl-acrylanilid
  参考文献：
  名称：

  Radiation-sensitive mixture containing novel polymers embodying units

  摘要：

  本发明公开了一种辐射敏感混合物，其包含具有酸可解侧基的聚合物粘合剂和在辐射下形成强酸的化合物。本发明还公开了合成聚合物粘合剂所使用的α，β-不饱和羧酸的新型酰胺。本发明还公开了一种基底和根据本发明的辐射敏感混合物的层构成的正向或负向作用的辐射敏感记录材料。

  公开号：

  US05326840A1

文献信息

• RESIST COMPOSITION, PATTERNING PROCESS, AND BARIUM, CESIUM AND CERIUM SALTS
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20170115566A1

  公开（公告）日：2017-04-27

  A resist composition comprising a base resin comprising acid labile group-containing recurring units and preferably acid generator-containing recurring units, and a sodium, magnesium, potassium, calcium, rubidium, strontium, yttrium, cesium, barium or cerium salt of α-fluorinated sulfonic acid bonded to an alkyl, alkenyl, alkynyl or aryl group exhibits a high resolution and sensitivity and forms a pattern of satisfactory profile with minimal LWR after exposure and development.

  一种抗蚀组合物包括基树脂，其中包含含酸敏感基团的重复单元，最好包含含酸发生剂的重复单元，以及与烷基、烯基、炔基或芳基结合的α-氟磺酸的钠、镁、钾、钙、铷、锶、钇、铯、钡或铈盐，表现出高分辨率和灵敏度，并在曝光和显影后形成具有最小LWR的满意轮廓图案。
• COATING COMPOSITION
  申请人：Houlihan Francis

  公开号：US20100119972A1

  公开（公告）日：2010-05-13

  Developable bottom antireflective coating compositions are provided.

  提供可开发底部防反射涂层组合物。
• Bottom Antireflective Coating Compositions
  申请人：Houlihan Francis M.

  公开号：US20090104559A1

  公开（公告）日：2009-04-23

  Developable bottom antireflective coating compositions are provided.

  提供可开发底部防反射涂层组合物。
• Element for photographic use containing crosslinkable polymers having
  申请人：Eastman Kodak Company

  公开号：US04207109A1

  公开（公告）日：1980-06-10

  Copolymers containing an acrylamidophenol as a crosslinking site and the corresponding crosslinked polymers are disclosed. The acrylamidophenol unit can be copolymerized with a wide variety of other monomers to provide crosslinkable and crosslinked polymers with useful properties. The acrylamidophenol unit provides for crosslinking at low pH with conventional crosslinking agents. The acrylamidophenol monomer unit is present in the copolymer from about 0.5 to 50 percent by weight and has the formula: ##STR1## wherein: x is 1 or 0, L is a linking group, R represents hydrogen or methyl, and R.sup.1 through R.sup.5 are independently selected from the group consisting of hydrogen, hydroxy, alkyl from 1 to 6 carbon atoms and aryl from 6 to 10 carbon atoms; with the proviso that at least one of R.sup.1 through R.sup.5 is hydroxy and at least one of the positions ortho or para to said hydroxy has a hydrogen atom attached thereto. The remainder of the polymer can comprise from 50 to 99.5 percent by weight of at least one additional polymerized ethylenically unsaturated monomer. Elements, particularly photographic elements, comprising a support having coated thereon either the crosslinked or uncrosslinked polymer are also disclosed.

  本发明披露了含有丙烯酰胺基酚交联位点的共聚物及相应的交联聚合物。丙烯酰胺基酚单元可以与各种其他单体共聚，以提供具有有用性能的可交联和交联聚合物。丙烯酰胺基酚单元提供了在低pH值下使用传统交联剂进行交联的能力。丙烯酰胺基酚单体单元在共聚物中的含量为重量的0.5％至50％，其化学式为：##STR1## 其中：x为1或0，L为连接基团，R代表氢或甲基，R.sup.1至R.sup.5分别独立地选择自羟基，碳数为1至6的烷基和碳数为6至10的芳基的群组中的一种；但须满足R.sup.1至R.sup.5中的至少一个为羟基，并且至少一个与该羟基正交或对位的位置上有一个氢原子附着。聚合物的剩余部分可以由重量为50％至99.5％的至少一种其他聚合乙烯不饱和单体聚合而成。本发明还披露了包括涂覆有交联或未交联聚合物的支撑物的元素，特别是摄影元素。
• Crosslinkable polymers containing acrylamidophenol units
  申请人：Eastman Kodak Company

  公开号：US04283504A1

  公开（公告）日：1981-08-11

  Copolymers containing an acrylamidophenol as a crosslinking site and the corresponding crosslinked polymers are disclosed. The acrylamidophenol unit can be copolymerized with a wide variety of other monomers to provide crosslinkable and crosslinked polymers with useful properties. The acrylamidophenol unit provides for crosslinking at low pH with conventional crosslinking agents. The acrylamidophenol monomer unit is present in the copolymer from about 0.5 to 50 percent by weight and has the formula: ##STR1## wherein: x is 1 or 0, L is a linking group, R represents hydrogen or methyl, and R.sup.1 through R.sup.5 are independently selected from the group consisting of hydrogen, hydroxy, alkyl from 1 to 6 carbon atoms and aryl from 6 to 10 carbon atoms; with the proviso that at least one of R.sup.1 through R.sup.5 is hydroxy and at least one of the positions ortho or para to said hydroxy has a hydrogen atom attached thereto. The remainder of the polymer can comprise from 50 to 99.5 percent by weight of at least one additional polymerized ethylenically unsaturated monomer. Elements, particularly photographic elements, comprising a support having coated thereon either the crosslinked or uncrosslinked polymer are also disclosed.

  本发明公开了含有丙烯酰胺基苯酚交联位点的共聚物和相应的交联聚合物。丙烯酰胺基苯酚单元可以与各种其他单体共聚，以提供具有有用性能的交联聚合物。丙烯酰胺基苯酚单元可在低pH值下与传统的交联剂进行交联。丙烯酰胺基苯酚单体单元在共聚物中的含量为约0.5至50重量％，其化学式为：##STR1## 其中：x为1或0，L为连接基团，R代表氢或甲基，R.sup.1至R.sup.5独立地选自羟基、碳数为1至6的烷基和碳数为6至10的芳基，但须满足R.sup.1至R.sup.5中至少有一个是羟基，并且至少有一个邻位或对位于所述羟基的氢原子附着。聚合物的其余部分可以包括50至99.5重量％的至少一种其他聚合的乙烯基不饱和单体。本发明还公开了包括支撑体的元素，特别是照片元素，其上涂有交联或未交联的聚合物。