3-苯基己二酸 | 56376-63-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 苯丙酸
• 中文名称: 3-苯基己二酸
• 英文名称: 3-phenyl-adipic acid
• 英文别名: 3-Phenyl-adipinsaeure；3-Phenyladipic acid；3-phenylhexanedioic acid
• CAS: 56376-63-7
• 化学式: C₁₂H₁₄O₄
• 分子量: 222.241
• InChiKey: FVQKPAFDGMJTDG-UHFFFAOYSA-N

物化性质

• 熔点：
  146 °C
• 沸点：
  394.5±22.0 °C(Predicted)
• 密度：
  1.246±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-苯基己二酸 、 碘甲烷 以 N,N-二甲基甲酰胺 为溶剂， 生成 3-Phenyl-hexanedioic acid dimethyl ester
  参考文献：
  名称：

  Curulli, Antonella; Feroci, Marta; Inesi, Achille, Journal of Chemical Research, Miniprint, 1993, # 12, p. 3320 - 3338

  摘要：

  DOI：
• 作为产物：
  描述：

  4-苯基环己酮 在 氧气 、 高氯酸四乙基铵 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以50%的产率得到3-苯基己二酸
  参考文献：
  名称：

  Curulli, Antonella; Feroci, Marta; Inesi, Achille, Journal of Chemical Research, Miniprint, 1993, # 12, p. 3320 - 3338

  摘要：

  DOI：

文献信息

• Pentafluorophenyl Esters of Dicarboxylic Acids
  作者：Peter Imming、Myung-Hee Jung

  DOI：10.1002/ardp.19953280116

  日期：——

  Di‐ and half‐esters of various dicarboxylic acids and dicarboxylic monoamides with pentafluorophenol were prepared. Their syntheses, properties, and spectroscopic data are reported.

  制备了各种二羧酸和二羧酸单酰胺与五氟苯酚的二酯和半酯。报告了它们的合成、性质和光谱数据。
• A New Modulated Oxidative Ring Cleavage of <i>α</i>-Nitrocycloalkanones by Oxone®: Synthesis of <i>α</i>,<i>ω</i>-Dicarboxylic Acids and <i>α</i>,<i>ω</i>-Dicarboxylic Acid Monomethyl Esters
  作者：Roberto Ballini、Massimo Curini、Francesco Epifano、Maria Carla Marcotullio、Ornelio Rosati

  DOI：10.1055/s-1998-5740

  日期：1998.10

  By the appropriate choice of the reaction conditions Oxone® produces the ring cleavage of α-nitrocycloalkanones affording good yields of α,ω-dicarboxylic acids and α,ω-dicarboxylic acid monomethyl esters, respectively, regardless the ring size and/or the presence of an alkyl group as substituent.

  通过适当选择反应条件，Oxone®能够实现α-硝基环烷酮的环裂解，分别得到良好产率的α,ω-二羧酸和α,ω-二羧酸单甲酯，无论环的大小和/或是否存在烷基作为取代基。
• REUSABLE PRINT MEDIUM AND METHOD OF MANUFACTURING THEREOF
  申请人：OCE TECHNOLOGIES B.V.

  公开号：US20130137805A1

  公开（公告）日：2013-05-30

  The present invention relates to a reusable print medium comprising a substrate and a sacrificial layer. The sacrificial layer contains a hotmelt composition at least comprising an amorphous material. The amorphous material is a resin being a reaction product of a first monomer A, said first monomer A being a polyhydroxyl alcohol comprising X hydroxyl functional groups, wherein X≧2, monomer A optionally comprises a primary or secondary amine functionality; a second monomer B, being an aromatic monocarboxylic acid; a third monomer C, said third monomer C being able to form an ester linkage with an alcohol and/or an amide linkage with a primary or secondary amine; and optionally, a fourth monomer D, being an aromatic monocarboxylic acid different from the second monomer B. The sacrificial layer including the printed image may be removed from the substrate by applying heat. A new sacrificial layer may be applied such that the reusable print medium is ready to be reused. The present invention also relates to a method of manufacturing a reusable print medium according to the present invention, a method of printing and recycling such a print medium and an apparatus for printing and recycling such a print medium.

  本发明涉及一种可重复使用的印刷介质，包括基底和牺牲层。牺牲层含有至少包括非晶态材料的热熔组合物。该非晶态材料是一种树脂，是第一单体A的反应产物，第一单体A是一种聚羟基醇，包括X个羟基官能团，其中X≥2，单体A可选包括一种主链或侧链氨基官能团；第二单体B是一种芳香单羧酸；第三单体C能够与醇形成酯键和/或与一种主链或侧链氨基形成酰胺键；可选地，第四单体D是一种与第二单体B不同的芳香单羧酸。可以通过施加热量从基底中去除包括印刷图像的牺牲层。可以应用新的牺牲层，使可重复使用的印刷介质准备好被重用。本发明还涉及一种制造可重复使用的印刷介质的方法，一种印刷和回收这样的印刷介质的方法，以及一种印刷和回收这样的印刷介质的装置。
• Reusable print medium and method of manufacturing thereof
  申请人：Océ-Technologies B.V.

  公开号：EP2596960A2

  公开（公告）日：2013-05-29

  The present invention relates to a reusable print medium (200) comprising a substrate (201) and a sacrificial layer (202). The sacrificial layer contains a hotmelt composition at least comprising an amorphous material. The amorphous material is a resin being a reaction product of a first monomer A, said first monomer A being a polyhydroxyl alcohol comprising X hydroxyl functional groups, wherein X ≥ 2, monomer A optionally comprises a primary or secondary amine functionality; a second monomer B, being an aromatic monocarboxylic acid; a third monomer C, said third monomer C being able to form an ester linkage with an alcohol and/or an amide linkage with a primary or secondary amine; and optionally, a fourth monomer D, being an aromatic monocarboxylic acid different from the second monomer B. The sacrificial layer including the printed image may be removed from the substrate by applying heat. A new sacrificial layer may be applied such that the reusable print medium is ready to be reused. The present invention also relates to a method of manufacturing a reusable print medium according to the present invention and a method of printing and recycling such a print medium.

  本发明涉及一种可重复使用的打印介质（200），它包括一个基底（201）和一个牺牲层（202）。牺牲层包含一种热熔胶组合物，至少包括一种非晶材料。无定形材料是一种树脂，是第一单体 A 的反应产物，所述第一单体 A 是一种多羟基醇，包含 X 个羟基官能团，其中 X ≥ 2，单体 A 可选择包含伯胺或仲胺官能团；第二单体 B，为芳香族单羧酸； 第三单体 C，所述第三单体 C 能与醇形成酯连接和/或与伯胺或仲胺形成酰胺连接；以及 第四单体 D，为不同于第二单体 B 的芳香族单羧酸。可通过加热将包括印刷图像的牺牲层从基底上去除。然后再涂上一层新的牺牲层，这样可重复使用的打印介质就可以重复使用了。 本发明还涉及根据本发明制造可重复使用打印介质的方法，以及打印和回收这种打印介质的方法。
• ANTISTATIC AGENT, ANTISTATIC AGENT COMPOSITION, ANTISTATIC RESIN COMPOSITION, AND MOLDED BODY
  申请人：Adeka Corporation

  公开号：EP2949721A1

  公开（公告）日：2015-12-02

  Provided are: an antistatic agent which is capable of imparting excellent antistatic effect in a small amount and has sufficient persistence and wiping resistance; an antistatic agent composition; an antistatic resin composition; and a molded article. The antistatic agent comprises a polymer compound (E) having a structure in which a block polymer (C) and an epoxy compound (D) are bound via an ester bond formed by a carboxyl group of the block polymer (C) and an epoxy group of the epoxy compound (D), the block polymer (C) having a structure comprising carboxyl groups at both ends, in which structure a block constituted by a polyester (A) having carboxyl groups at both ends and a block constituted by a compound (B) having hydroxyl groups at both ends are repeatedly and alternately bound via ester bonds formed by the carboxyl groups and the hydroxyl groups, and the epoxy compound (D) comprising two or more epoxy groups.

  本发明提供了：一种抗静电剂，该抗静电剂能够以少量提供优异的抗静电效果，并具有足够的持久性和耐擦拭性；一种抗静电剂组合物；一种抗静电树脂组合物；以及一种成型制品。抗静电剂包括聚合物化合物（E），其结构是嵌段聚合物（C）和环氧化合物（D）通过由嵌段聚合物（C）的羧基和环氧化合物（D）的环氧基形成的酯键结合在一起，嵌段聚合物（C）具有两端包含羧基的结构、在该结构中，由两端具有羧基的聚酯（A）构成的嵌段和由两端具有羟基的化合物（B）构成的嵌段通过由羧基和羟基形成的酯键反复交替结合，环氧化合物（D）包括两个或多个环氧基团。