2,2,3-Trimethyl-3-phenylbuttersaeure-methylester | 88255-58-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2,3-Trimethyl-3-phenylbuttersaeure-methylester
• 英文别名: methyl 2,2,3,3-tetramethyl-3-phenylpropionate；2,2,3-trimethyl-3-phenyl-butyric acid methyl ester；Methyl 2,2,3-trimethyl-3-phenylbutanoate
• CAS: 88255-58-7
• 化学式: C₁₄H₂₀O₂
• 分子量: 220.312
• InChiKey: ZKCWGZUSLHWJHA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2,3-Trimethyl-3-phenylbuttersaeure-methylester 生成 2,2,3-trimethyl-3-phenylbutanoic acid
  参考文献：
  名称：

  113.烷基化对Friedel-Crafts合成中酸衍生物反应的影响

  摘要：

  DOI：

  10.1039/jr9430000425
• 作为产物：
  描述：

  苯 、 alkaline earth salt of/the/ methylsulfuric acid 在 三氯化铝 作用下， 生成 2,2,3-Trimethyl-3-phenylbuttersaeure-methylester
  参考文献：
  名称：

  113.烷基化对Friedel-Crafts合成中酸衍生物反应的影响

  摘要：

  DOI：

  10.1039/jr9430000425

文献信息

• Synthesis of Alkylbismuths by Regiodivergent Carbobismuthination of Simple Alkenes
  作者：Yoshihiro Nishimoto、Midori Takeuchi、Makoto Yasuda、Akio Baba

  DOI：10.1002/chem.201302194

  日期：2013.10.18

  Switchable regioselectivity: This study represents the first carbobismuthination of alkenes achieved by the treatment of an alkene with a bismuth halide and a ketene silyl acetal. This reaction is particularly noteworthy in that a change in the type of halogen on a bismuth atom very easily switched the regioselectivity (see scheme).

  可切换的区域选择性：这项研究代表了通过卤化铋和乙烯酮甲硅烷基乙缩醛处理烯烃而实现的烯烃的第一次碳羰基甲基化。该反应特别值得注意，因为铋原子上卤素类型的变化很容易改变区域选择性（参见方案）。
• Reetz, Manfred T.; Schwellnus, Konrad; Huebner, Friedhelm, Chemische Berichte, 1983, vol. 116, # 11, p. 3708 - 3724
  作者：Reetz, Manfred T.、Schwellnus, Konrad、Huebner, Friedhelm、Massa, Werner、Schmidt, Roland E.

  DOI：——

  日期：——
• REETZ, M. T.;SCHWELLNUS, K.;HUEBNER, F.;MASSA, W.;SCHMIDT, R. E., CHEM. BER., 1983, 116, N 11, 3708-3724
  作者：REETZ, M. T.、SCHWELLNUS, K.、HUEBNER, F.、MASSA, W.、SCHMIDT, R. E.

  DOI：——

  日期：——
• CONSUMER PRODUCTS HAVING VARYING ODORS
  申请人：MEINE Georg

  公开号：US20080207481A1

  公开（公告）日：2008-08-28

  Conventional perfumed consumer products are characterized by a uniform odor throughout the entire product. Consumer products are described that comprise at least two differently smelling perfume oils which are not evenly distributed in the product in proportion to one another. This allows the consumer to produce, using one and the same product, a variety of odors during applications and overcome the monotony of the olfactory experience associated with conventional perfumed consumer products.
• CONSUMER PRODUCTS HAVING VARYING ODOR PATTERNS
  申请人：MEINE Georg

  公开号：US20080221003A1

  公开（公告）日：2008-09-11

  Consumer products having fragrance that can develop distinguishable odor patterns which are separately detectable. Scent dynamics allow the consumer with one and the same product to experience different scent experiences during a single application. The limited range and monotony of odor associated with the conventional perfumed consumer products is thereby completely broken.