6-(6-Sulfanylidenebenzo[c][2,1]benzoxaphosphinin-6-yl)oxybenzo[c][2,1]benzoxaphosphinine 6-oxide | 1259405-76-9

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 6-(6-Sulfanylidenebenzo[c][2,1]benzoxaphosphinin-6-yl)oxybenzo[c][2,1]benzoxaphosphinine 6-oxide
• 英文别名: 6-(6-sulfanylidenebenzo[c][2,1]benzoxaphosphinin-6-yl)oxybenzo[c][2,1]benzoxaphosphinine 6-oxide
• CAS: 1259405-76-9
• 化学式: C₂₄H₁₆O₄P₂S
• 分子量: 462.402
• InChiKey: ODSSTGLHYCWVIW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  31
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-sulfide 、 10-hydroxy-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide 在 四氯化碳 、 三乙胺 作用下， 以 氯仿 为溶剂， 反应 2.0h， 以64%的产率得到6-(6-Sulfanylidenebenzo[c][2,1]benzoxaphosphinin-6-yl)oxybenzo[c][2,1]benzoxaphosphinine 6-oxide
  参考文献：
  名称：

  使用 atherton-todd 反应作为通用工具合成新的有机磷化合物

  摘要：

  本文讨论了七种有机磷化合物在 Atherton-Todd 条件下的行为。因此，系统研究了不同（苯）氧杂膦、二氧杂膦、二氧杂膦和二苯基氧化膦与三种亲核试剂的反应性和选择性。结果证明了 Atherton-Todd 反应对具有不同磷环境和反应性 PH 键的各种有机磷化合物的多功能性。本文研究的亲核试剂被选为胺类和醇类的模型底物。由于有机磷分子是重要且用途广泛的化合物，因此对于广泛的应用领域，学术界和工业界都对新的合成方法感兴趣。例如，桥接 1 的单步合成，具有潜在阻燃性能的 3-亚苯基双（二苯基次膦酸盐）被添加到该研究中。此外，该反应还用于合成新型有机磷酐。© 2012 Wiley Periodicals, Inc. 杂原子化学 23:216–222, 2012; 在 wileyonlinelibrary.com 上在线查看这篇文章。DOI 10.1002/hc.21006

  DOI：

  10.1002/hc.21006

文献信息

• Flameproof expandable polymerizates
  申请人：Eberstaller Roman

  公开号：US20120184635A1

  公开（公告）日：2012-07-19

  The invention relates to flameproof expandable polymers containing at least one blowing agent, wherein at least one phosphorus compound is contained as a flame retardant. Novel 9,10-dihydro-9-oxa-10-phosphaphenanthrene derivatives, namely 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-thione, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione ammonium salt, 9,10-dihydro-10-mercapto-9-oxa-10-phosphaphenanthrene-10-thione, 9,10-dihydro-10-mercapto-9-oxa-10-phosphaphenanthrene-10-thione triethylammonium salt, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione triethylammonium salt, 9,10-ei-hydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione melaminium salt, 9,10-dihydro-10-hydroxy-9-oxa-10-phosphaphenanthrene-10-thione guanidinium salt, bis(9,10-dihydro-9-oxa-10-oxo-10-phosphaphenanthrene-10-yl)sulfide, 9,10-dihydro-10-(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-ylthio)-9-oxa-10-phosphaphenanthrene-10-one, bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)sulfide, bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)disulfide, bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)tetrasulfide, di(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yl)ether and/or 9,10-dihydro-10-(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthrene-10-yloxy)-9-oxa-10-phosphaphenanthrene-10-one, or ring-opened hydrolyzates thereof, are provided as flame retardants.

  本发明涉及至少含有一种发泡剂的阻燃膨胀聚合物，其中至少含有一种磷化合物作为阻燃剂。提供了新型的9,10-二氢-9-氧-10-磷杂菲衍生物，包括9,10-二氢-9-氧-10-磷杂菲-10-硫酮，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮铵盐，9,10-二氢-10-巯基-9-氧-10-磷杂菲-10-硫酮，9,10-二氢-10-巯基-9-氧-10-磷杂菲-10-硫酮三乙基铵盐，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮三乙基铵盐，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮三聚氰胺盐，9,10-二氢-10-羟基-9-氧-10-磷杂菲-10-硫酮胍盐，双(9,10-二氢-9-氧-10-氧-10-磷杂菲-10-基)硫化物，9,10-二氢-10-(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基硫基)-9-氧-10-磷杂菲-10-酮，双(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)硫化物，双(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)二硫化物，双(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)四硫化物，二(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-基)醚和/或9,10-二氢-10-(9,10-二氢-9-氧-10-磷杂-10-硫氧基菲-10-氧基)-9-氧-10-磷杂菲-10-酮及其开环水解物作为阻燃剂。
• FLAMMGESCHÜTZTE EXPANDIERBARE POLYMERISATE
  申请人：Sunpor Kunststoff GmbH

  公开号：EP2449018A1

  公开（公告）日：2012-05-09
• NEUE DERIVATE VON 9,10-DIHYDRO-9-OXA-10-PHOSPHAPHENANTHREN-10-ON
  申请人：Krems Chemie Chemical Services AG

  公开号：EP2449019A1

  公开（公告）日：2012-05-09
• [DE] FLAMMGESCHÜTZTE EXPANDIERBARE POLYMERISATE<br/>[EN] FLAME-RETARDANT EXPANDABLE POLYMERS<br/>[FR] POLYMÉRISATS EXPANSIBLES, RETARDATEURS DE FLAMME
  申请人：SUNPOR KUNSTSTOFF GMBH

  公开号：WO2011000018A1

  公开（公告）日：2011-01-06

  Die Erfindung betrifft flammgeschützte, zumindest ein Treibmittel enthaltende, expandierbare Polymerisate, wobei als Flammschutzmittel zumindest eine Phosphorverbindung enthalten ist. Als Flammschutzmittel sind neue 9,10 Dihydro-9-oxa-10-phosphaphenanthren-Derivate, nämlich 9,10-Dihydro-9-oxa-10-phosphaphenanthren-10-thion, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion-ammoniumsalz, 9,10-Dihydro-10-mercapto-9-oxa-10-phosphaphenanthren-10-thion, 9,10 Dihydro-10-mercapto-9-oxa-10-phosphaphenanthren-10-thion-triethylammoniumsalz, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion-triethylammoniumsalz, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion-melaminiumsalz, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion-guanidiniumsalz, Bis(9,10-dihydro-9-oxa-10-oxo-10-phosphaphenanthren-10-yl)sulfid, 9,10-Dihydro-10-(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-ylthio)-9-oxa-10-phosphaphenanthren-10-on, Bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yl)sulfid, Bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yl)disulfid, Bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yl)tetrasulfid, Di(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yl)ether und/oder 9,10-Dihydro-10-(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yloxy)-9-oxa-10-phosphaphenanthren-10-on, oder ringgeöffnete Hydrolysate davon vorgesehen.
• [DE] NEUE DERIVATE VON 9,10-DIHYDRO-9-OXA-10-PHOSPHAPHENANTHREN-10-ON<br/>[EN] NOVEL DERIVATIVES OF 9,10-DIHYDRO-9-OXA-10-PHOSPHAPHENANTHREN-10-ONE<br/>[FR] NOUVEAUX DÉRIVÉS DE 9,10-DIHYDRO-9-OXA-10-PHOSPHAPHÉNANTHRÈNE-10-ONE
  申请人：KREMS CHEMIE CHEMICAL SERVICES AG

  公开号：WO2011000019A1

  公开（公告）日：2011-01-06

  Die Erfindung betrifft neue 9,10-Dihydro-9-oxa-10-phosphaphenanthren-Derivate, nämlich 9,10-Dihydro-9-oxa-10-phosphaphenanthren-10-thion, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion-ammoniumsalz, 9, 10-Dihydro-10-mercapto-9-oxa-10-phosphaphenanthren-10-thion, 9,10-Dihydro-10-mercapto-9-oxa-10-phosphaphenan- thren-10-thion-triethylammoniumsalz, 9,10-Dihydro-10-hydroxy-9-oxa-10-phospha-phenanthren-10-thion-triethylammoniumsalz, 9, 10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion-melaminiumsalz, 9,10-Dihydro-10-hydroxy-9-oxa-10-phosphaphenanthren-10-thion-guanidiniumsalz, Bis(9,10-dihydro-9-oxa-10-oxo-10-phosphaphenanthren-10-yl)sulfid, 9,10-Dihydro-10-(9, 10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-ylthio)-9-oxa-10-phosphaphenanthren-10-on, Bis(9, 10-di-hydro-9-oxa-10-phospha-10-thioxophenanthren-10-yl)sulfid, Bis(9,10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yl)disulfιd, Bis(9, 10-dihydro-9-oxa-10-phos-pha-10-thioxophenanthren-10-yl)tetrasulfid, Di(9, 10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yl)ether und 9,10-Dihydro-10-(9, 10-dihydro-9-oxa-10-phospha-10-thioxophenanthren-10-yloxy)-9-oxa-10-phosphaphenanthren-10-on, deren Verwendung als Flammschutzmittel sowie Herstellungsverfahren dafür.