[copper(II)[(E)-N(1)-(2((2-aminocyclohexydiimino)(phenyl)methyl)-4-chlorophenyl)-N(2)-(2-benzyl-4-chlorophenyl)oxalamido]](methanol) | 864155-16-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [copper(II)[(E)-N(1)-(2((2-aminocyclohexydiimino)(phenyl)methyl)-4-chlorophenyl)-N(2)-(2-benzyl-4-chlorophenyl)oxalamido]](methanol)
• CAS: 864155-16-8
• 化学式: C₃₅H₃₂Cl₂CuN₄O₄
• 分子量: 707.115
• InChiKey: KRELPPYXCUROSM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲醇 、 manganese(II) perchlorate hexahydrate 、 [copper(II)[(E)-N(1)-(2((2-aminocyclohexydiimino)(phenyl)methyl)-4-chlorophenyl)-N(2)-(2-benzyl-4-chlorophenyl)oxalamido]](methanol) 、 sodium azide 以 甲醇 为溶剂， 生成 di[copper(II)[(E)-N(1)-(2((2-aminocyclohexydiimino)(phenyl)methyl)-4-chlorophenyl)-N(2)-(2-benzyl-4-chlorophenyl)oxalamido](azide)][manganaes(II)dimethanol] - methanol - water (1/2/2)
  参考文献：
  名称：

  Synthesis, structures and magnetic properties of oxamido-bridged trinuclear Cu(II)–Mn(II)–Cu(II) complexes

  摘要：

  Based on self-assembly of the dissymmetrical mononuclear entity CuL(CH3OH) [H2L=(E)-N-1-(2-((2-aminocyclohexydiimino)(phenyl)methyl)-4-chlorophenyl)-N-2-(2-benzyl-4-chlorophenyl)oxalamide] with Mn(II), two trinuclear complexes were prepared. They are of the formula [(LCuN3)(2)Mn(CH3OH)(2)]center dot 2CH(3)OH center dot 2H(2)O (1) and [(LCuSCN)(2)Mn(H2O)(2)]center dot 4CH(3)OH (2). Their magnetic properties were studied by susceptibility versus temperature measurement, the best fitting of the experimental data led to J=-14.40 cm(-1) for 1 and J=-15.48 cm(-1) for 2. Hydrogen bonds help complex 1 to produce a novel S type one-dimensional chain-like supramolecular structure. In complex 2, Cl center dot center dot center dot Cl interaction also results in the formation of a one-dimensional structure. (C) 2007 Published by Elsevier B.V.

  DOI：

  10.1016/j.ica.2007.01.008