4-(n-C12H25)-C6H3-1,3-(OP-iPr2)2 | 1210500-83-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(n-C12H25)-C6H3-1,3-(OP-iPr2)2
• 英文别名: 4-(n-C12H25)-C6H3-1,3-(OPPiPr2)2；[3-Di(propan-2-yl)phosphanyloxy-4-dodecylphenoxy]-di(propan-2-yl)phosphane；[3-di(propan-2-yl)phosphanyloxy-4-dodecylphenoxy]-di(propan-2-yl)phosphane
• CAS: 1210500-83-6
• 化学式: C₃₀H₅₆O₂P₂
• 分子量: 510.721
• InChiKey: LSMYIQVKXWEMDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  34
• 可旋转键数：
  19
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 4-(n-C12H25)-C6H3-1,3-(OP-iPr2)2 以 甲苯 为溶剂， 以96.5%的产率得到[PdCl(4-(n-C12H25)-C6H2-1,3-(OPiPr2)2)]
  参考文献：
  名称：

  Group 10 phosphinite POCOP pincer complexes derived from 4-n-dodecylresorcinol: An alternative way to produce non-symmetric pincer compounds

  摘要：

  Phosphinite POCOP pincer compounds 14-(n-C12H25)-C-6-H-3-1,3-(OPR2)(2)] R=Ph (1), Pr-i (2) derived from 4-n-dodecylresorcinol and their group 10 derivatives [MCI{3-(n-C12H25)-C6H2-2,6-(OPR2)(2)}] M(R) = Ni(Ph) (3), Ni(Pr-i) (6), Pd(Ph) (4), Pd(Pr-i) (7) and Pt(Ph) (5), Pt(Pr-i) (8) were synthesized and the catalytic activity of the palladium species explored in the Mizoroki-Heck and Suzuki-Miyaura cross coupling reactions. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.038
• 作为产物：
  描述：

  氯二异丙基膦 、 4-十二烷基间苯二酚 在 三乙胺 作用下， 以 甲苯 为溶剂， 生成 4-(n-C12H25)-C6H3-1,3-(OP-iPr2)2
  参考文献：
  名称：

  Group 10 phosphinite POCOP pincer complexes derived from 4-n-dodecylresorcinol: An alternative way to produce non-symmetric pincer compounds

  摘要：

  Phosphinite POCOP pincer compounds 14-(n-C12H25)-C-6-H-3-1,3-(OPR2)(2)] R=Ph (1), Pr-i (2) derived from 4-n-dodecylresorcinol and their group 10 derivatives [MCI{3-(n-C12H25)-C6H2-2,6-(OPR2)(2)}] M(R) = Ni(Ph) (3), Ni(Pr-i) (6), Pd(Ph) (4), Pd(Pr-i) (7) and Pt(Ph) (5), Pt(Pr-i) (8) were synthesized and the catalytic activity of the palladium species explored in the Mizoroki-Heck and Suzuki-Miyaura cross coupling reactions. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.038

文献信息

• Group 10 phosphinite POCOP pincer complexes derived from 4-n-dodecylresorcinol: An alternative way to produce non-symmetric pincer compounds
  作者：Moisés Agustín Solano-Prado、Fabiola Estudiante-Negrete、David Morales-Morales

  DOI：10.1016/j.poly.2009.07.038

  日期：2010.1

  Phosphinite POCOP pincer compounds 14-(n-C12H25)-C-6-H-3-1,3-(OPR2)(2)] R=Ph (1), Pr-i (2) derived from 4-n-dodecylresorcinol and their group 10 derivatives [MCI3-(n-C12H25)-C6H2-2,6-(OPR2)(2)}] M(R) = Ni(Ph) (3), Ni(Pr-i) (6), Pd(Ph) (4), Pd(Pr-i) (7) and Pt(Ph) (5), Pt(Pr-i) (8) were synthesized and the catalytic activity of the palladium species explored in the Mizoroki-Heck and Suzuki-Miyaura cross coupling reactions. (C) 2009 Elsevier Ltd. All rights reserved.