1-[4-(4-Nitrophenyl)phenyl]-1-phenyl-2-(2,4,6-trinitrophenyl)hydrazine | 1447183-52-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-[4-(4-Nitrophenyl)phenyl]-1-phenyl-2-(2,4,6-trinitrophenyl)hydrazine
• CAS: 1447183-52-9
• 化学式: C₂₄H₁₆N₆O₈
• 分子量: 516.426
• InChiKey: RYVKYPQOELAQBA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  38
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  199
• 氢给体数：
  1
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  1,1-二苯-2-苦基肼 、 4-nitrobenzenediazonium tetrafluoroborate 生成 1-[4-(4-Nitrophenyl)phenyl]-1-phenyl-2-(2,4,6-trinitrophenyl)hydrazine
  参考文献：
  名称：

  Electrografting via Diazonium Chemistry: From Multilayer to Monolayer Using Radical Scavenger

  摘要：

  A simple strategy to avoid the formation of polyaryl layer during the functionalization of carbon surface by diazonium electroreduction is presented. The approach proposes to directly act on the polymerization mechanism by the use of a radical scavenger. The kinetic gap between the surface coupling and the multilayer formation is exploited to prevent the growth of the layer without interfering with the grafting. The well-known 4-nitrobenzenediazonium electrografting was used to demonstrate the possibility of reaching a monolayer surface coverage with an excess of DPPH (2,2-diphenyl-1-picrylhydrazyl). Experimental conditions were varied to validate the efficiency of the grafting limitation and the radical capture was confirmed by isolation of the aryl radical/DPPH coupling product.

  DOI：

  10.1021/cm401512c