1,1-bis-(4-acetoxy-phenyl)-cyclohexane | 75616-05-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1-bis-(4-acetoxy-phenyl)-cyclohexane
• 英文别名: 1,1-Bis-(4-acetoxy-phenyl)-cyclohexan；[4-[1-(4-Acetyloxyphenyl)cyclohexyl]phenyl] acetate
• CAS: 75616-05-6
• 化学式: C₂₂H₂₄O₄
• 分子量: 352.43
• InChiKey: QZIIRLIIPFPQET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  苯酚 在 盐酸 、 sodium acetate 作用下， 生成 1,1-bis-(4-acetoxy-phenyl)-cyclohexane
  参考文献：
  名称：

  Condensations of Ketones with Phenols

  摘要：

  DOI：

  10.1021/ja01871a032

文献信息

• v.Braun, Justus Liebigs Annalen der Chemie, 1929, vol. 472, p. 34
  作者：v.Braun

  DOI：——

  日期：——
• ISLAM A. M.; RASHAD M. E.; WASSEL M. M., EGYPT. J. CHEM., 1977(1980), 20, NO 5, 483-490
  作者：ISLAM A. M.、 RASHAD M. E.、 WASSEL M. M.

  DOI：——

  日期：——
• POLYMERIZABLE LIQUID CRYSTAL COMPOUND, LIQUID CRYSTAL COMPOSITION AND POLYMER
  申请人：ITOH Maiko

  公开号：US20100096591A1

  公开（公告）日：2010-04-22

  The purpose the invention is to provide a polymerizable liquid crystal compound which has an excellent solubility with other compounds, a high homeotropic property, and a spirobiindan-backbone, and a liquid crystal composition comprising this compound. The purpose is attained with a polymerizable liquid crystal compound represented by Formula (1). A polymer which is excellent in many characteristics can be obtained from this compound and a formed body having optical anisotropy, produced from this polymer can be obtained. In Formula (1), G is a single bond or oxygen; R is hydrogen, methyl (Me) or a group represented by Formula (a), wherein at least two of R are groups represented by Formula (a); P is a polymerizable group represented by any of Formula (P1) to Formula (P8). In Formula (a), a desirable A is 1,4-cyclohexylene or 1,4-phenylene; Z is a bonding group; m is an integer of 0 to 3; X 0 is a single bond or alkylene; Z 0 is a single bond, —O—, —OCO—, or —OCOO—; X is a single bond or alkylene.
• Polymerizable liquid crystal composition and homeotropically-aligned liquid crystal film
  申请人：Hirai Yoshiharu

  公开号：US20100151154A1

  公开（公告）日：2010-06-17

  A polymerizable liquid crystal composition is provided that can contains a mixture of polymerizable compounds containing a compound represented by the formula (1-1), a compound represented by the formula (2), a compound represented by the formula (3-1) and a compound represented by the formula (4), and a amine silane coupling agent. The composition can form a polymerizable liquid crystal layer exhibiting a uniform homeotropic alignment by coating the composition on a supporting substrate, independently from the kind of the supporting substrate without a special alignment film. Examples of each of the components are shown below, in which ring T represents triptycen-1,4-diyl.
• POLYMERIZABLE LIQUID CRYSTAL COMPOUND, POLYMERIZABLE LIQUID CRYSTAL COMPOSITION AND ANISOTROPIC POLYMER
  申请人：HIRAI Yoshiharu

  公开号：US20110147657A1

  公开（公告）日：2011-06-23

  The main aim of the invention is to provide a polymerizable compound that is excellent in the stability of a liquid crystal phase, a polymerizable liquid crystal composition, and an anisotropic polymer in which the optical anisotropy can be adjusted and a uniform orientation is excellent. An anisotropic polymer having a uniform orientation formed by polymerization of a paint film that was prepared by application of a polymerizable liquid crystal composition including a compound represented by formula (1) having a benzyl ester moiety in the minor axis direction of the molecule to a supporting substrate; wherein at least one of R a is a polymerizable group, A is a divalent cyclic-structure group, B is phenyl that may have a substituent, Y and Z are a single bond or alkylene, and m and n are an integer from 0 to 5.