N,N'-bis(3-pyridylmethyl)-4,4'-biphenylenedimethyleneimine | 873205-99-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis(3-pyridylmethyl)-4,4'-biphenylenedimethyleneimine
• 英文别名: N,N'-bis-(3-pyridylmethyl)-1,4-biphenylenedimethyleneimine；N-(pyridin-3-ylmethyl)-1-[4-[4-(pyridin-3-ylmethyliminomethyl)phenyl]phenyl]methanimine
• CAS: 873205-99-3
• 化学式: C₂₆H₂₂N₄
• 分子量: 390.487
• InChiKey: OVKUGNNGTRHFAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  30
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  50.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N'-bis(3-pyridylmethyl)-4,4'-biphenylenedimethyleneimine 、 cobalt(II) thiocyanate 以 甲醇 为溶剂， 以70%的产率得到Co(N,N'-bis(3-pyridylmethyl)-4,4'-biphenylenedimethyleneimine)2(SCN)2
  参考文献：
  名称：

  Synthesis, structure and optical limiting property of CoII, MnII and CdII complexes with di-Schiff base and reduced di-Schiff base ligands

  摘要：

  Three coordination polymers [Co(L)(2)(SCN)(2)] (1), [Mn(L)(2)(SCN)(2)] (2) and [Cd(H4L)(2)Cl-2] (3), were obtained by the reaction of Co-II, Mn-II, Cd-II salts with di-Schiff base ligand N,N-bis(3-pyridylmethyl)-4,4'-biphenylenedimethyleneimine (L) and its reduced form (H4L), respectively and their structures were determined by X-ray crystallography. In the solid state, complexes 1 and 2 feature 1D hinged chains, while complex 3 has a 2D network structure. Complex 2 was found to show optical limiting property with a 3 ns pulsed laser at 532 nm in DMF solution. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2005.09.074

文献信息

• Novel Layered Organic–Inorganic Networks Assembled From PbI₂and<i>N,N</i>′-bis(3-pyridylmethyl)-1,4-biphenylenedimethyleneimine
  作者：Ling-Yan Kong、Zheng-Hua Zhang、Taka-aki Okamura、Ming-Jian Fei、Wei-Yin Sun、Norikazu Ueyama

  DOI：10.1246/cl.2004.1572

  日期：2004.12

  Two novel metal-organic frameworks with different structures were obtained by reactions of PbI2 with N,N′-bis(3-pyridylmethyl)-1,4-biphenylenedimethyleneimine (L) under different M/L ratios. When the M/L ratio is 1:1, L bridges [PbI2]n chains to form a layered organic–inorganic hybrid compound with the empirical formula [Pb(L)I2] (1). When changing the M/L ratio to 2:1, L bridges the double chains [Pb2I4]n to form networks [Pb2(L)I4] (2), which are further linked by C–H···I hydrogen bonds to give a 3D structure.

  通过 PbI2 与 N,N′-双（3-吡啶基甲基）-1,4-联苯二亚甲基亚胺（L）在不同 M/L 比下的反应，获得了两种结构不同的新型金属有机框架。当 M/L 比为 1:1 时，L 会桥接[PbI2]n 链，形成经验公式为[Pb(L)I2](1)的层状有机-无机杂化化合物。当 M/L 比变为 2:1 时，L 桥接双链 [Pb2I4]n 形成网络 [Pb2(L)I4] (2)，这些网络通过 C-H-I 氢键进一步连接，形成三维结构。