2,2-bis(4-hydroxy-3-benzamidephenyl)hexafluoropropane | 144080-77-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-bis(4-hydroxy-3-benzamidephenyl)hexafluoropropane
• 英文别名: N-[5-[2-(3-benzamido-4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropan-2-yl]-2-hydroxyphenyl]benzamide
• CAS: 144080-77-3
• 化学式: C₂₉H₂₀F₆N₂O₄
• 分子量: 574.479
• InChiKey: HZDGKPMDZUEPED-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  41
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  98.7
• 氢给体数：
  4
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  2,2-bis(4-hydroxy-3-benzamidephenyl)hexafluoropropane 、 氯甲基乙醚 在 N,N-二异丙基乙胺 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 24.0h， 以65%的产率得到2,2-bis(4-ethoxymethoxy-3-benzamidephenyl)hexafluoropropane
  参考文献：
  名称：

  (Meth) acrylamide derivative, polymer, chemically amplified photosensitive resin composition, and patterning method

  摘要：

  本发明涉及一种由通式（1）表示的新型（甲基）丙烯酰胺化合物，该化合物的（共）聚合物，以及由聚合物和光酸发生剂组成的化学增感光敏树脂组合物。在该式中，R1代表氢原子或甲基基团；R2代表可分解酸基团；R3至R6独立地代表氢原子、卤素原子或具有1至4个碳原子的烷基基团。

  公开号：

  US20090068587A1
• 作为产物：
  描述：

  苯甲酰氯 、 2,2-双(3-氨基-4-羟基苯基)六氟丙烷 在 N-甲基吡咯烷酮 、 lithium chloride 作用下， 生成 2,2-bis(4-hydroxy-3-benzamidephenyl)hexafluoropropane
  参考文献：
  名称：

  (Meth) acrylamide derivative, polymer, chemically amplified photosensitive resin composition, and patterning method

  摘要：

  本发明涉及一种由通式（1）表示的新型（甲基）丙烯酰胺化合物，该化合物的（共）聚合物，以及由聚合物和光酸发生剂组成的化学增感光敏树脂组合物。在该式中，R1代表氢原子或甲基基团；R2代表可分解酸基团；R3至R6独立地代表氢原子、卤素原子或具有1至4个碳原子的烷基基团。

  公开号：

  US20090068587A1

文献信息

• RESIN COMPOSITION
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20190241716A1

  公开（公告）日：2019-08-08

  The present invention provides a resin composition having a high sensitivity and serving to produce a cured film with a low water absorption rate. The resin composition includes: (a) an alkali-soluble resin and (b1) an amido-phenol compound containing a phenolic hydroxyl group in which a monovalent group as represented by the undermentioned general formula (1) is located at the ortho position and/or (b2) an aromatic amido acid compound containing a carboxy group in which a monovalent group as represented by the undermentioned general formula (2) is located at the ortho position: wherein in general formula (1), X is a monovalent organic group having an alkyl group that contains 2 to 20 carbon atoms and bonds directly to the carbonyl carbon in general formula (1) or a monovalent organic group that has —(YO) n —; and in general formula (2), U is a monovalent organic group that has an alkyl group containing 2 to 20 carbon atoms and bonding directly to the amide nitrogen in general formula (2) or a monovalent organic group that has —(YO) n —; wherein Y is an alkylene group containing 1 to 10 carbon atoms and n is an integer of 1 to 20.

  本发明提供了一种树脂组合物，具有高灵敏度，并用于生产具有低吸水率的固化膜。该树脂组合物包括：(a)可溶于碱的树脂和(b1)含有酚羟基的酰胺酚化合物，其中酚羟基化合物中的单价基在邻位上，和/或(b2)含有羧基的芳香酰胺酸化合物，其中羧基化合物中的单价基在邻位上，其通式如下所示：在通式(1)中，X是一个单价有机基，具有含有2到20个碳原子的烷基，并直接连接到通式(1)中的羰基碳，或具有—(YO)n—的单价有机基；在通式(2)中，U是一个单价有机基，具有含有2到20个碳原子的烷基，并直接连接到通式(2)中的酰胺氮，或具有—(YO)n—的单价有机基；其中Y是含有1到10个碳原子的烷基，n是1到20的整数。
• Resin composition
  申请人：TORAY INDUSTRIES, INC.

  公开号：US11199776B2

  公开（公告）日：2021-12-14

  The present invention provides a resin composition having a high sensitivity and serving to produce a cured film with a low water absorption rate. The resin composition includes: (a) an alkali-soluble resin and (b1) an amido-phenol compound containing a phenolic hydroxyl group in which a monovalent group as represented by the undermentioned general formula (1) is located at the ortho position and/or (b2) an aromatic amido acid compound containing a carboxy group in which a monovalent group as represented by the undermentioned general formula (2) is located at the ortho position: wherein in general formula (1), X is a monovalent organic group having an alkyl group that contains 2 to 20 carbon atoms and bonds directly to the carbonyl carbon in general formula (1) or a monovalent organic group that has —(YO)n—; and in general formula (2), U is a monovalent organic group that has an alkyl group containing 2 to 20 carbon atoms and bonding directly to the amide nitrogen in general formula (2) or a monovalent organic group that has —(YO)n—; wherein Y is an alkylene group containing 1 to 10 carbon atoms and n is an integer of 1 to 20.

  本发明提供了一种具有高灵敏度的树脂组合物，可生成吸水率低的固化膜。该树脂组合物包括(a) 碱溶性树脂和(b1) 含有酚羟基的氨基苯酚化合物，其中由上述通式(1)表示的一价基团位于正位，和/或(b2) 含有羧基的芳香族氨基酸化合物，其中由上述通式(2)表示的一价基团位于正位： 其中，在通式（1）中，X 是含有 2 至 20 个碳原子的烷基并直接与通式（1）中的羰基碳键 合的一价有机基团，或具有-(YO)n-的一价有机基团；在通式（2）中，U 是具有含 2 至 20 个碳原子的烷基并直接与通式（2）中的酰胺氮键合的一价有机基团或具有-(YO)n-的一价有机基团；其中 Y 是含 1 至 10 个碳原子的亚烷基，n 是 1 至 20 的整数。
• PHOTOSENSITIVE RESIN COMPOSITION AND ADHESION ENHANCER
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1909142B1

  公开（公告）日：2015-06-24
• PHOTOSENSITIVE RESIN COMPOSITION AND ADHESION PROMOTER
  申请人：Yuba Tomoyuki

  公开号：US20090123867A1

  公开（公告）日：2009-05-14

  The present invention provides a photosensitive resin composition comprising (a) an alkali-soluble resin, (b) a silicon compound having a secondary aromatic amino group and an alkoxy group, and (c) at least one selected from a photopolymerization initiator, a photo acid generator and a photo base generator. According to the present invention, it is possible to obtain a photosensitive resin composition which remarkably enhances the adhesion property with a substrate after curing without deteriorating storage stability of a solution, and does not cause peeling of a fine pattern even upon development.
• PHOTOSENSITIVE RESIN COMPOSITION, METHOD FOR PRODUCING HEAT-RESISTANT RESIN FILM AND DISPLAY DEVICE
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150301453A1

  公开（公告）日：2015-10-22

  The present invention provides a photosensitive resin composition which uses a polyimide precursor that has excellent solubility in organic solvents and is capable of reducing the viscosity of a resin composition obtained therefrom. The solution according to the present invention is a photosensitive resin composition which contains: an aromatic amide resin that has, as a main repeating unit, a specific structure having an amide group, a trifluoromethyl group and an aromatic ring; (b) a sensitizer; and (c) a solvent.