mer-trifluoro-triphenyl-λ⁶-tellane | 99893-86-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: mer-trifluoro-triphenyl-λ⁶-tellane
• 英文别名: [Trifluoro(diphenyl)-lambda6-tellanyl]benzene；[trifluoro(diphenyl)-λ6-tellanyl]benzene
• CAS: 99893-86-4
• 化学式: C₁₈H₁₅F₃Te
• 分子量: 415.912
• InChiKey: IFUUXGLGZHFYRY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.46
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  甲醇 、 mer-trifluoro-triphenyl-λ⁶-tellane 以 氯仿 为溶剂， 生成 (Difluoro-methoxy-diphenyl-lambda6-tellanyl)benzene
  参考文献：
  名称：

  氟化苯基碲（VI）与醇，胺和硅化合物的反应

  摘要：

  描述了氟化苯基碲（VI），PhTeF 5，反式-Ph 2 TeF 4和mer- Ph 3 TeF 3与醇和胺或其三甲基甲硅烷基衍生物的反应。该产品PhTeF 4 X中，Ph 2 TEF 3 X且Ph 3 TEF 2 X（X = OME，NME 2，净2通过其特征在于19 F NMR和异构体结构的它们的NMR谱样品的基础上分配。反式- Ph 2 TeF 4含有少量的顺式-Ph 2 TeF 4。

  DOI：

  10.1016/s0022-1139(00)82747-5
• 作为产物：
  描述：

  triphenyltelluronium azide 在 二氟代氙 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 mer-trifluoro-triphenyl-λ⁶-tellane
  参考文献：
  名称：

  Organotellurium(VI) Azides and Halides

  摘要：

  The reaction of azide with organotellurium(VI) halides Ph5TeBr and cis-(biphen)(2)TeF2 (biphen = 2,2'-biphenyldiyl) resulted in the formation and isolation of Ph5TeN3 (1) and cis-(biphen)(2)Te(N-3)(2) (2), which are the first tellurium(VI)-azide species. In addition to spectroscopic data, both crystal structures have been determined. Furthermore, the stability of possible Te(VI) species with higher azide contents PhxTe(N-3)(6-x) and MexTe(N-3)(6-x) as well as the syntheses and properties of their Ph/MexTeFy precursors was investigated, including the crystal structure determination of trans-Ph2TeF4 (3). Ab initio and density functional studies of all molecules regarding the structures and electronic populations were performed.

  DOI：

  10.1021/ja046637q

文献信息

• Organotellurium(VI) fluorides
  作者：Kohrshed Alam、Alexander F. Janzen

  DOI：10.1016/s0022-1139(00)80916-1

  日期：1985.4

  A series of phenyltellurium(VI) fluorides have been prepared by the oxidative-fluorination of tellurium compounds with xenon difluoride. The compounds were characterized by elemental analysis, fluorine and tellurium nmr, and mass spectrometry.

  通过碲化合物与二氟化氙的氧化氟化反应，制备了一系列的苯基碲（VI）氟化物。化合物通过元素分析，氟和碲核磁共振和质谱法进行表征。
• JANZEN, ALEXANDER F.;ALAM, KOHRSHED;BLACKBURN, BARRY J., J. FLUOR. CHEM., 42,(1989) N, C. 173-178
  作者：JANZEN, ALEXANDER F.、ALAM, KOHRSHED、BLACKBURN, BARRY J.

  DOI：——

  日期：——
• JANZEN, ALEXANDER F.;JANG, MEEHAE, CAN. J. CHEM., 67,(1989) N, C. 71-75
  作者：JANZEN, ALEXANDER F.、JANG, MEEHAE

  DOI：——

  日期：——
• ALAM, K.;JANZEN, A. F., J. FLUOR. CHEM., 1985, 27, N 4, 467-469
  作者：ALAM, K.、JANZEN, A. F.

  DOI：——

  日期：——
• Organotellurium(VI) Azides and Halides
  作者：Thomas M. Klapötke、Burkhard Krumm、Kurt Polborn、Ingo Schwab

  DOI：10.1021/ja046637q

  日期：2004.11.1

  The reaction of azide with organotellurium(VI) halides Ph5TeBr and cis-(biphen)(2)TeF2 (biphen = 2,2'-biphenyldiyl) resulted in the formation and isolation of Ph5TeN3 (1) and cis-(biphen)(2)Te(N-3)(2) (2), which are the first tellurium(VI)-azide species. In addition to spectroscopic data, both crystal structures have been determined. Furthermore, the stability of possible Te(VI) species with higher azide contents PhxTe(N-3)(6-x) and MexTe(N-3)(6-x) as well as the syntheses and properties of their Ph/MexTeFy precursors was investigated, including the crystal structure determination of trans-Ph2TeF4 (3). Ab initio and density functional studies of all molecules regarding the structures and electronic populations were performed.