1-(4-methoxyphenyl)ethyl acrylate | 207983-12-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4-methoxyphenyl)ethyl acrylate
• 英文别名: 1-(4-Methoxyphenyl)ethyl prop-2-enoate
• CAS: 207983-12-8
• 化学式: C₁₂H₁₄O₃
• 分子量: 206.241
• InChiKey: LKMVHLUTELFSDZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(4-methoxyphenyl)ethyl acrylate 在 Lipase Amano AK 作用下， 反应 32.0h， 以47%的产率得到(R)-1-(4-甲氧基苯基)乙醇
  参考文献：
  名称：

  First example of hydrolytic kinetic resolution of acrylate of secondary alcohols by lipase Amano AK

  摘要：

  Lipase Amano AK is found to be extremely efficient catalyst for hydrolytic kinetic resolution of acrylates of secondary alcohols in aqueous phosphate buffer at pH 7.0. Both aliphatic and benzylic secondary alcohols show good to excellent E values. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcatb.2011.06.015
• 作为产物：
  描述：

  4-甲氧基-α-甲基苯甲醇 、 丙烯酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以85%的产率得到1-(4-methoxyphenyl)ethyl acrylate
  参考文献：
  名称：

  First example of hydrolytic kinetic resolution of acrylate of secondary alcohols by lipase Amano AK

  摘要：

  Lipase Amano AK is found to be extremely efficient catalyst for hydrolytic kinetic resolution of acrylates of secondary alcohols in aqueous phosphate buffer at pH 7.0. Both aliphatic and benzylic secondary alcohols show good to excellent E values. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcatb.2011.06.015

文献信息

• COATED BIS(2-PYRIDINETHIOL 1-OXIDE) COPPER SALT
  申请人：Yoshitomi Fine Chemicals, Ltd.

  公开号：EP1080640A1

  公开（公告）日：2001-03-07

  Bis(2-pyridinethiol 1-oxide) copper salt which has been coated with one or more members selected among glycerol, dialkyl phthalates, lubricating oils, acrylic resins, rosins, fatty acid amides, dialkylpolysulfides, polybutene, paraffins, and vaseline. Since the the coated copper salt does not fly off, it has good handleability and is excellent in safety and workability. The coating does not adversely influence the storage stability and antifouling effect inherent in the copper salt. Thus, a ship bottom paint having an excellent antifouling effect and excellent storage stability can be obtained.

  双（2-吡啶硫醇 1-氧化物）铜盐，其表面涂有甘油、邻苯二甲酸二烷基酯、润滑油、丙烯酸树脂、松香、脂肪酸酰胺、二烷基聚硫化物、聚丁烯、石蜡和凡士林中的一种或多种成分。由于铜盐涂层不会飞散，因此具有良好的可操作性、出色的安全性和可加工性。涂层不会对铜盐固有的储存稳定性和防污效果产生不利影响。因此，可以获得防污效果极佳、储存稳定性极佳的船底涂料。
• TRIPHENYLBORON-CONTAINING POLYMERS AND USE THEREOF
  申请人：Yoshitomi Fine Chemicals, Ltd.

  公开号：EP1227111A1

  公开（公告）日：2002-07-31

  A polymer containing a triphenylboron-containing constituting unit of the formula [I]: wherein each symbol is as defined in the specification, shows a superior adhesion-preventive effect against aquatic fouling organisms, such as coelenterates, shellfish, tubicolous polychaetes and the like, for a long time, shows a function of not only an active ingredient but also a binder, the polymer characteristically shows fine miscibility with other coating resins and a less adverse influence on the environment. Therefore, it can be used as a superior preventive of fouling due to the adhesion of aquatic fouling organisms.

  一种含有式[I]的含三苯基硼构成单元的聚合物： 其中各符号如本说明书所定义，对水生污损生物（如腔肠动物、贝类、管状多毛类动物等）具有卓越的长期防污效果，不仅具有活性成分的功能，还具有粘合剂的功能，该聚合物与其他涂层树脂具有良好的混溶性，对环境的不利影响较小。因此，它可用作防止水生污损生物附着造成污损的优质防污剂。
• Coated bis (2-pyridinethiol-1-oxide) copper salt
  申请人：——

  公开号：US20030124085A1

  公开（公告）日：2003-07-03

  The present invention provides a bis(2-pyridinethiol-1-oxide) copper salt coated with one or more compounds selected from glycerin, dialkyl phthalate, lubricating oil, acrylic resin, rosin, fatty acid amide, dialkyl polysulfide, polybutene, paraffin and petrolatum. The coated copper salt does not scatter, so that it is easy to handle, and is superior in safety and workability. In addition, the copper salt does not suffer from any adverse influence on the inherent storage stability or antifouling effect by being coated. Therefore, a coating for the bottom of a ship having a superior antifouling effect and storage stability can be obtained.

  本发明提供了一种双(2-吡啶硫醇-1-氧化物)铜盐，其表面涂有一种或多种选自甘油、邻苯二甲酸二烷基酯、润滑油、丙烯酸树脂、松香、脂肪酸酰胺、聚硫化二烷基酯、聚丁烯、石蜡和凡士林的化合物。涂层铜盐不会散落，因此易于处理，在安全性和可加工性方面也更胜一筹。此外，铜盐的固有储存稳定性和防污效果也不会受到涂层的任何不利影响。因此，可以获得防污效果和储存稳定性都很好的船底涂层。
• COATED BIS(2-PYRIDINETHIOl-1-OXIDE)COPPER SALT
  申请人：API Corporation

  公开号：EP1080640B1

  公开（公告）日：2003-09-10
• HIGH REFRACTIVE INDEX OPHTHALMIC DEVICE MATERIALS
  申请人：Alcon, Inc.

  公开号：EP2225325A2

  公开（公告）日：2010-09-08