3-(undec-10-enyl)thiophene | 162152-27-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 3-(undec-10-enyl)thiophene
• 英文别名: 3-(10-undecenyl)thiophene；3-(Undec-10-EN-1-YL)thiophene；3-undec-10-enylthiophene
• CAS: 162152-27-4
• 化学式: C₁₅H₂₄S
• 分子量: 236.422
• InChiKey: UKPFMHIEKQQXJF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  16
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-(undec-10-enyl)thiophene 在 三氯硅烷 作用下， 生成 11-(3-thienyl)undecyltrichlorosilane
  参考文献：
  名称：

  Polymerization of 3TUTS SAM Formed on ITO Substrates

  摘要：

  DOI：

  10.1080/15421400701548118
• 作为产物：
  描述：

  3-溴噻吩 、 11-溴-1-十一烯 在 碘 、 magnesium 、 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) 作用下， 生成 3-(undec-10-enyl)thiophene
  参考文献：
  名称：

  Polymerization of 3TUTS SAM Formed on ITO Substrates

  摘要：

  DOI：

  10.1080/15421400701548118

文献信息

• Conformational changes in regioregular polythiophenes due to crosslinking
  作者：Kenneth A. Murray、Andrew B. Holmes、Stephen C. Moratti、Garry Rumbles

  DOI：10.1039/a902683e

  日期：——

  Regioregular polythiophene copolymers 10a-d containing hexyl and 11-hydroxyundecyl side chains have been synthesised, by nickel-catalysed cross-coupling of well-defined Grignard intermediates. The hydroxy groups were protected during the polymerisation as tetrahydropyranyl ethers, and subsequently transformed into azide groups. These azide-functionalised copolymers 11a-d were heated under vacuum, leading to azide decomposition, nitrene formation and crosslinking. The resultant polymer films showed decreased solubility (or insolubility) and a shift in the absorption spectrum to shorter wavelengths dependent on the azide content of the polymer. This colour change is rationalised in terms of the conformational change in the polythiophene backbone, associated with thermochromism, which has been partially fixed by the crosslinking at high temperature. This is supported by the modified thermochromism and photoluminescence behaviour of the crosslinked polymer films.

  通过镍催化的精确Grignard中间体的交叉耦合，合成了含有己基和11-羟基十一烷基侧链的规整聚噻吩共聚物10a-d。在聚合过程中，羟基被保护为四氢吡営醚，随后转化为叠氮基团。这些叠氮功能化的共聚物11a-d在真空下加热，导致叠氮分解、氮烯形成和交联。生成的聚合物膜显示出降低的溶解性（或不溶性），并且吸收光谱向短波长偏移，具体取决于聚合物中的叠氮含量。这种颜色变化可以通过聚噻吩主链的构象变化来解释，这种变化与热致变色性相关，并且在高温下的交联部分固定了这种变化。这得到了交联聚合物膜的改性热致变色性和光致发光行为的支持。
• CONDUCTIVE ORGANIC THIN FILM AND PRODUCTION METHOD THEREFOR, ELECTRODE AND ELECTRIC CABLE USING IT
  申请人：Matsushita Electric Industrial Co., Ltd.

  公开号：EP1381058A1

  公开（公告）日：2004-01-14

  A conductive organic thin film is made of organic molecules including a terminal bond group that is covalently bonded to a surface of a substrate material (1) or a surface of a primer layer (2) formed on the substrate material, a conjugated bond group, and an alkyl group between the terminal bond group and the conjugated bond group, wherein the organic molecules are oriented, and the conjugated bond group is polymerized with the conjugated bond groups of other molecules, thus forming a conductive network (34). The conductive network (34) is formed of polypyrrole, polythienylene, polyacetylene, polydiacetylene and polyacene. For the polymerization of the conjugated bond groups, polymerization through electrolytic oxidation, catalytic polymerization or polymerization through energy beam irradiation is used. Thus, a conductive organic thin film with a conductivity that is higher than that of conventional organic thin films is provided, as well as a method of manufacturing the same and an electrode, a conductor and an electronic device using the same.

  导电有机薄膜由有机分子制成，有机分子包括与基底材料（1）表面或形成于基底材料上的底层（2）表面共价键合的端键基、共轭键基和端键基与共轭键基之间的烷基，其中有机分子定向，共轭键基与其他分子的共轭键基聚合，从而形成导电网络（34）。导电网络（34）由聚吡咯、聚噻吩、聚乙炔、聚二乙炔和聚乙炔组成。共轭键基团的聚合可采用电解氧化聚合、催化聚合或能量束辐照聚合。因此，本发明提供了一种导电性高于传统有机薄膜的导电性有机薄膜，以及制造这种薄膜的方法和使用这种薄膜的电极、导体和电子设备。
• Conductive organic thin film, method for manufacturing the same, electrode and electric cable using the same
  申请人：Matsushita Electric Industrial Co., Ltd.

  公开号：US20030099845A1

  公开（公告）日：2003-05-29

  A conductive organic thin film is made of organic molecules including a terminal bond group that is covalently bonded to a surface of a substrate material ( 1 ) or a surface of a primer layer ( 2 ) formed on the substrate material, a conjugated bond group, and an alkyl group between the terminal bond group and the conjugated bond group, wherein the organic molecules are oriented, and the conjugated bond group is polymerized with the conjugated bond groups of other molecules, thus forming a conductive network ( 34 ). The conductive network ( 34 ) is formed of polypyrrole, polythienylene, polyacetylene, polydiacetylene and polyacene. For the polymerization of the conjugated bond groups, polymerization through electrolytic oxidation, catalytic polymerization or polymerization through energy beam irradiation is used. Thus, a conductive organic thin film with a conductivity that is higher than that of conventional organic thin films is provided, as well as a method of manufacturing the same and an electrode, a conductor and an electronic device using the same.

  导电有机薄膜由有机分子构成，其中包括与基底材料表面共价键合的末端键合基团 ( 1 ) 或底层表面 ( 2 )的表面、共轭键基团以及位于端键基团和共轭键基团之间的烷基，其中有机分子是定向的，共轭键基团与其他分子的共轭键基团聚合，从而形成导电网络( 34 ).导电网络 ( 34 由聚吡咯、聚噻吩、聚乙炔、聚二乙炔和聚乙炔组成。共轭键基团的聚合可采用电解氧化聚合、催化聚合或能量束辐照聚合。因此，本发明提供了一种导电性高于传统有机薄膜的导电性有机薄膜，以及制造这种薄膜的方法和使用这种薄膜的电极、导体和电子设备。
• Polymerization of 3TUTS SAM Formed on ITO Substrates
  作者：Sung Jin Choi、Yongkeun Son、Youngkwan Lee、Kyo-Hyeok Kim、Il-Sub Chung

  DOI：10.1080/15421400701548118

  日期：2007.9.4