dimethyl 5-(prop-2-ynyloxy)isophthalic acid | 203626-78-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dimethyl 5-(prop-2-ynyloxy)isophthalic acid
• 英文别名: 5-(isopropoxy)isophthalic acid；IPOIPA；5-(1-Methylethoxy)-1,3-benzenedicarboxylic acid；5-propan-2-yloxybenzene-1,3-dicarboxylic acid
• CAS: 203626-78-2
• 化学式: C₁₁H₁₂O₅
• 分子量: 224.213
• InChiKey: GAJDKROCTSDMCN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  83.8
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  zinc(II) nitrate hexahydrate 、 dimethyl 5-(prop-2-ynyloxy)isophthalic acid 以 水 、 乙腈 为溶剂， 反应 72.0h， 生成 [Zn₃(IPOIPA)₂(μ₃-OH)(μ₂-OH)]
  参考文献：
  名称：

  Hexanuclear Zn(II)-Induced Dense π-Stacking in a Metal–Organic Framework Featuring Long-Lasting Room Temperature Phosphorescence

  摘要：

  通过在金属-有机框架基质中引入六核Zn(II)簇诱导的致密π堆积，我们开发了一种新的策略来提高室温磷光性能。金属簇的协同效应和π共轭二聚体的大面积重叠促进了磷光发射、迁移和电荷载体的分离，从而实现优异的光催化活性。

  DOI：

  10.1021/acs.inorgchem.0c01415

文献信息

• POROUS POLYMER-METAL COMPLEX, GAS ADSORBENT, AND GAS SEPARATION DEVICE AND GAS STORAGE DEVICE USING SAME
  申请人：Nippon Steel & Sumitomo Metal Corporation

  公开号：EP2915799A1

  公开（公告）日：2015-09-09

  An object of the present invention is to provide a porous polymer metal complex which can be used as a gas adsorbent and contains two or more types of similar ligands. A porous polymer metal complex is provided expressed by [CuX]n(1) (in the Formula, X represents two or more types of isophthalic acid ions selected from the group consisting of isophthalic acid ions and isophthalic acid ions having a substituent at position 5, at least an amount of one type of X is 5 mol% to 95 mol% of the total number of moles of X, and n represents an assembly number of constituent units expressed by Clip and is not particularly limited.).

  本发明的目的是提供一种多孔聚合物金属络合物，它可用作气体吸附剂，并含有两种或两种以上类型的类似配体。本发明提供了一种多孔聚合物金属络合物，用[CuX]n(1)表示（式中，X代表两种或两种以上的间苯二甲酸离子，选自间苯二甲酸离子和在第5位有取代基的间苯二甲酸离子组成的组，至少一种X的量占X的总摩尔数的5摩尔％至95摩尔％，n代表用Clip表示的组成单位的集合数，没有特别限制）。
• “Click” post-synthetic modification of metal−organic frameworks for asymmetric aldol catalysis
  作者：Wenting Zhu、Cheng He、Xiao Wu、Chunying Duan

  DOI：10.1016/j.inoche.2013.10.031

  日期：2014.1

  The reaction of dimethyl 5-(prop-2-ynyloxy)isophthalic acid, meso-alpha, and beta-di (4-pyridyl) glycol with ZnCl2 in a methanol aqueous solution affords MOF Zn-DPPG. The enantiomeric Zn-Fun1 and Zn-Fun2 were obtained through a strategy of in situ click reactions of Zn-DPPG with two opposite chiral adducts. With the L- or D-proline chiral functionality, the two Zn-Funs exhibited remarkable catalytic activities in the relative asymmetric aldol reactions, leading to the formation of opposite enantiomorphs, respectively. (C) 2013 Published by Elsevier B.V.
• POROUS POLYMER METAL COMPLEX, GAS ADSORBENT, GAS SEPARATION DEVICE AND GAS STORAGE DEVICE USING SAME
  申请人：Nippon Steel Corporation

  公开号：EP2915799B1

  公开（公告）日：2019-10-16
• POROUS POLYMER METAL COMPLEX, GAS ADSORBENT, AND GAS SEPARATION DEVICE AND GAS STORAGE DEVICE USING SAME
  申请人：NIPPON STEEL & SUMITOMO METAL CORPORATION

  公开号：US20150290618A1

  公开（公告）日：2015-10-15

  An object of the present invention is to provide a porous polymer metal complex which can be used as a gas adsorbent and contains two or more types of similar ligands. A porous polymer metal complex is provided expressed by [CuX] n (1) (in the Formula, X represents two or more types of isophthalic acid ions selected from the group consisting of isophthalic acid ions and isophthalic acid ions having a substituent at position 5, at least an amount of one type of X is 5 mol % to 95 mol % of the total number of moles of X, and n represents an assembly number of constituent units expressed by CuX and is not particularly limited).
• ASSOCIATIVE POLYMERS FOR USE IN A FLOW AND RELATED COMPOSITIONS, METHODS AND SYSTEMS
  申请人：CALIFORNIA INSTITUTE OF TECHNOLOGY

  公开号：US20170081466A1

  公开（公告）日：2017-03-23

  Described herein are associative polymers capable of controlling a physical and/or chemical property of non-polar compositions that can be used when the non-polar composition is in a flow, and related compositions, methods and systems. Associative polymers herein described have a non-polar backbone with a longest span having a molecular weight that remains substantially unchanged under the flow conditions and functional groups presented at ends of the non-polar backbone, with a number of the functional groups presented at the ends of the non-polar backbone formed by associative functional groups capable of undergoing an associative interaction with another associative functional group with an association constant (k) such that the strength of each associative interaction is less than the strength of a covalent bond between atoms and in particular less than the strength of a covalent bond between backbone atoms.