N-propionyl-3-hydroxyl-2-naphthoylhydrazide | 1206465-51-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-propionyl-3-hydroxyl-2-naphthoylhydrazide
• 英文别名: N-propionyl-3-hydroxy-2-naphthoylhydrazide；3-hydroxy-N'-propanoylnaphthalene-2-carbohydrazide
• CAS: 1206465-51-1
• 化学式: C₁₄H₁₄N₂O₃
• 分子量: 258.277
• InChiKey: BPDSVPFHYCDPFW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  78.4
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-propionyl-3-hydroxyl-2-naphthoylhydrazide 、 水 、 manganese (II) acetate tetrahydrate 、 N,N-二甲基甲酰胺 以 N,N-二甲基甲酰胺 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  A mixed-type of azametallacrown containing [Mn6(pnhz)6(DMF)4(H2O)2] and [Mn6(pnhz)6(DMF)2(H2O)4] constructed by a flexible pentadentate ligand

  摘要：

  A mixed-type of azametallacrown based on a flexible pentadentate N-propionyl ligand was reported, which exhibits not only the completely different arrangement of the metal centers but also diversely geometric configurations of the N-terminal ligands, and this complex can further assemble into a novel 3-D supramolecular structure using two different aza18-MC-6 as secondary building units (SBUs) via the intermolecular C-H center dot center dot center dot pi, pi-pi and C-H center dot center dot center dot O interactions. Temperature-dependent magnetic susceptibility measurements of the title complex indicate that the complex presents significantly antiferromagnetic coupling among metal centers. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.11.005
• 作为产物：
  描述：

  丙酰氯 、 3-羟基-2-萘酸肼 在 丙酸 、 三乙胺 作用下， 以 氯仿 为溶剂， 反应 24.0h， 以92.9%的产率得到N-propionyl-3-hydroxyl-2-naphthoylhydrazide
  参考文献：
  名称：

  A mixed-type of azametallacrown containing [Mn6(pnhz)6(DMF)4(H2O)2] and [Mn6(pnhz)6(DMF)2(H2O)4] constructed by a flexible pentadentate ligand

  摘要：

  A mixed-type of azametallacrown based on a flexible pentadentate N-propionyl ligand was reported, which exhibits not only the completely different arrangement of the metal centers but also diversely geometric configurations of the N-terminal ligands, and this complex can further assemble into a novel 3-D supramolecular structure using two different aza18-MC-6 as secondary building units (SBUs) via the intermolecular C-H center dot center dot center dot pi, pi-pi and C-H center dot center dot center dot O interactions. Temperature-dependent magnetic susceptibility measurements of the title complex indicate that the complex presents significantly antiferromagnetic coupling among metal centers. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.11.005

文献信息

• A mixed-type of azametallacrown containing [Mn6(pnhz)6(DMF)4(H2O)2] and [Mn6(pnhz)6(DMF)2(H2O)4] constructed by a flexible pentadentate ligand
  作者：Yuting Chen、Jianmin Dou、Dacheng Li、Suna Wang

  DOI：10.1016/j.inoche.2009.11.005

  日期：2010.1

  A mixed-type of azametallacrown based on a flexible pentadentate N-propionyl ligand was reported, which exhibits not only the completely different arrangement of the metal centers but also diversely geometric configurations of the N-terminal ligands, and this complex can further assemble into a novel 3-D supramolecular structure using two different aza18-MC-6 as secondary building units (SBUs) via the intermolecular C-H center dot center dot center dot pi, pi-pi and C-H center dot center dot center dot O interactions. Temperature-dependent magnetic susceptibility measurements of the title complex indicate that the complex presents significantly antiferromagnetic coupling among metal centers. (C) 2009 Elsevier B.V. All rights reserved.