4-t-butyl isophthalic acid | 62722-24-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-t-butyl isophthalic acid
• 英文别名: 4-tert-butyl-1,3-benzenedicarboxylic acid；4-tert-butyl-isophthalic acid；4-tert-Butyl-isophthalsaeure；4-Tert-butylisophthalic acid；4-tert-butylbenzene-1,3-dicarboxylic acid
• CAS: 62722-24-1
• 化学式: C₁₂H₁₄O₄
• 分子量: 222.241
• InChiKey: LKJKDWUEGGOHFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  吡啶 、 乙酸钼(II)二聚体 、 4-t-butyl isophthalic acid 以 further solvent(s) 为溶剂， 生成 [Mo24(4-tert-butyl-1,3-benzenedicarboxylate)24](pyridine)12
  参考文献：
  名称：

  包含十二个四键结合的二钼单元的立方八面体和反八面体笼的合成和结构。

  摘要：

  包含12个Mo-Mo四重键[[Mo（24）（C（12）H（12）O（4））（24）]（C（5）H（5）N）（ 12）和Mo（24）（C（8）H（4）O（4））（24）被报道。12个桨轮构件和24个配体分别自组装成立方八面体和反八面体多面体，具体取决于簇的两半对齐的方式。这些簇包含的二钼单元数量是任何先前报道的簇的两倍。还提出了可能的组装机制。

  DOI：

  10.1021/ic050460z
• 作为产物：
  描述：

  1-(tert-butyl)-2,4-dimethylbenzene 在 吡啶 、 potassium permanganate 作用下， 生成 4-t-butyl isophthalic acid
  参考文献：
  名称：

  Orientation Effects in the Alkylation of m-Xylene by Various Procedures and Reagents

  摘要：

  DOI：

  10.1021/ja01259a054

文献信息

• Reactive polymer-supporting porous film for battery seperator and use thereof
  申请人：Uetani Yoshihiro

  公开号：US20060257727A1

  公开（公告）日：2006-11-16

  The invention provides a reactive polymer-supporting porous film for use as a battery separator which comprises a porous substrate film and a partially crosslinked reactive polymer supported on the porous substrate film, the partially crosslinked reactive polymer being obtained by the reaction of a crosslinkable polymer having at least one reactive group selected from the group consisting of 3-oxetanyl group and epoxy group in the molecule with a polycarboxylic acid. The reactive polymer-supporting porous film for use as a battery separator has a separator and electrodes sufficiently bonded to each other and low inner resistance so that it is suitably used for production of battery excellent in high rate performance. Further, the invention provides a method of producing a battery which comprises placing the electrode/reactive polymer-supporting porous film layered body in a battery container; introducing an electrolytic solution containing a cationic polymerization catalyst into the battery container thereby bonding the porous film and the electrodes together.

  本发明提供一种反应性聚合物支持多孔膜，用于作为电池隔膜，包括多孔基底膜和部分交联的反应性聚合物支持在多孔基底膜上，所述部分交联的反应性聚合物是通过交联性聚合物与多羧酸反应而得到的，所述交联性聚合物在分子中至少具有3-氧杂环基团和环氧基团中的一种反应性基团。作为电池隔膜使用的反应性聚合物支持多孔膜，具有足够紧密结合的隔膜和电极以及低内阻，因此适用于生产高速性能优异的电池。此外，本发明还提供一种电池的制造方法，其中包括将电极/反应性聚合物支持多孔膜层状体放置在电池容器中；向电池容器中引入含有阳离子聚合催化剂的电解液，从而将多孔膜和电极粘合在一起。
• HETEROCYCLIC CETP INHIBITORS
  申请人：Salvati E. Mark

  公开号：US20070135631A1

  公开（公告）日：2007-06-14

  Compounds of formula Ia and Ib wherein A, B, C and R 1 are described herein.

  公式Ia和Ib的化合物，其中A、B、C和R1如下所述。
• REACTIVE POLYMER-SUPPORTING POROUS FILM FOR BATTERY SEPARATOR AND USE THEREOF
  申请人：Uetani Yoshihiro

  公开号：US20110232081A1

  公开（公告）日：2011-09-29

  A reactive polymer-supporting porous film is provided as a battery separator which comprises a porous substrate film and a partially crosslinked reactive polymer supported on the porous substrate film. The partially crosslinked reactive polymer is obtained by the reaction of a crosslinkable polymer having at least one group selected from the 3-oxetanyl group and epoxy group reactive with a polycarboxylic acid. The reactive polymer-supporting porous film has a separator and electrodes sufficiently bonded to each other and with low inner resistance suitably used for production of battery excellent in high rate performance. Further, provided is a method of producing a battery which comprises placing the electrode/reactive polymer-supporting porous film layered body in a battery container; introducing an electrolytic solution containing a cationic polymerization catalyst into the battery container thereby bonding the porous film and electrodes together.

  提供一种反应性聚合物支撑多孔膜作为电池隔膜，包括一个多孔基底膜和部分交联的反应性聚合物支撑在多孔基底膜上。部分交联的反应性聚合物是通过交联聚合物与至少具有3-氧杂环基团和环氧基团之一的可反应羧酸反应而得到的。反应性聚合物支撑多孔膜具有足够粘结的隔膜和电极，内阻低，适用于生产高速性能优异的电池。此外，还提供了一种制造电池的方法，包括将电极/反应性聚合物支撑多孔膜层状体放置在电池容器中；向电池容器中引入含有阳离子聚合催化剂的电解质溶液，从而将多孔膜和电极粘结在一起。
• INCLUSION COMPLEX CONTAINING EPOXY RESIN COMPOSITION FOR SEMICONDUCTOR ENCAPSULATION
  申请人：Ono Kazuo

  公开号：US20100179250A1

  公开（公告）日：2010-07-15

  It is to improve the storage stability of a sealant, to retain the flowability of the sealant when sealing, and to achieve an effective curing rate of the sealant by heating to be applicable as a sealant for delicate semiconductors. It is an epoxy resin composition for sealing a semiconductor, comprising the following component (A) and component (B). (A) an epoxy resin, (B) a clathrate complex comprising (b1) an aromatic carboxylic acid compound, and (b2) at least one imidazole compound represented by formula (II) (wherein R 2 represents a hydrogen atom, etc.; R 3 to R 5 represent a hydrogen atom, etc.).

  这是为了改善密封剂的储存稳定性，保持密封时密封剂的流动性，并通过加热实现密封剂的有效固化速率，以适用于精细半导体的密封剂。它是一种用于密封半导体的环氧树脂组合物，包括以下组分（A）和组分（B）。（A）环氧树脂，（B）包括（b1）芳香羧酸化合物和（b2）至少一种由式（II）表示的咪唑化合物的笼形复合物（其中R2表示氢原子等；R3至R5表示氢原子等）。
• NEW POLYMERS DERIVED FROM RENEWABLY RESOURCED LYSINOL
  申请人：E I DU PONT DE NEMOURS AND COMPANY

  公开号：US20140329924A1

  公开（公告）日：2014-11-06

  Disclosed are salt compositions of lysinol and dicarboxylic acids; and lysinol derived polymers including polyamide, polyimide, polyurea, cross-linked polyurea comprising urethane linkages, polyurea foams, cross-linked polyurea foams, and lysinol-epoxy thermoset.

  本发明涉及的是赖氨醇和二羧酸的盐组成物；以及由赖氨醇衍生的聚合物，包括聚酰胺，聚酰亚胺，聚脲，包含脲链的交联聚脲，聚脲泡沫，交联聚脲泡沫和赖氨醇-环氧热固性树脂。