[(1E)-3,3-dimethylhexa-1,5-dienyl]benzene | 112528-96-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(1E)-3,3-dimethylhexa-1,5-dienyl]benzene
• CAS: 112528-96-8
• 化学式: C₁₄H₁₈
• 分子量: 186.297
• InChiKey: LZWZKMRUHWRATL-ZRDIBKRKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  烯丙基三甲基硅烷 、 2-((E)-1,1-Dimethyl-3-phenyl-allyloxy)-tetrahydro-pyran 生成 [(1E)-3,3-dimethylhexa-1,5-dienyl]benzene
  参考文献：
  名称：

  MURAKAMI MASAHIRO; KATO TAKASHI; MUKAIYAMA TERUAKI, CHEM. LETT.,(1987) N 6, 1167-1170

  摘要：

  DOI：

文献信息

• A Facile Synthesis of 1,5-Dienes and β,γ-Unsaturated Nitriles via Trityl Perchlorate-Catalyzed Allylation
  作者：Masahiro Murakami、Takashi Kato、Teruaki Mukaiyama

  DOI：10.1246/cl.1987.1167

  日期：1987.6.5

  In the presence of a catalytic amount of trityl perchlorate, secondary and tertiary allyl ethers smoothly react with allylsilanes and silyl cyanide to give the corresponding 1,5-dienes and β,γ-unsaturated nitriles, respectively, in good yields.

  在一定量的高氯酸三苯甲基酯催化下，仲烯丙基醚和叔烯丙基醚与烯丙基硅烷和氰化硅基顺利反应，分别生成相应的 1,5-二烯和β,γ-不饱和腈，产率良好。
• Lewis acid-catalyzed coupling reactions of allyl trimethylsilyl ethers with allysilanes
  作者：Tsutomu Yokozawa、Koichi Furuhashi、Hiroyuki Natsume

  DOI：10.1016/0040-4039(95)00982-i

  日期：1995.7

  For the simultaneous preparation of molecules having both the nucleophilic and electrophilic sites, allyl trimethylsilyl ethers as eletrophilic allylating reagents are studied. Allyl trimethylsilyl ethers react with allyl trimethylsilanes in the pressence of a catalytic amount of ZnCl2 at room temperature to afford the corresponding 1,5-dienes in good yields.

  为了同时制备具有亲核和亲电子位点的分子，研究了烯丙基三甲基甲硅烷基醚作为亲电子的烯丙基化试剂。在室温下，在催化量的ZnCl 2的压力下，烯丙基三甲基甲硅烷基醚与烯丙基三甲基硅烷反应，以高收率得到相应的1,5-二烯。
• Direct construction of quaternary carbons from carbonyl compounds utilizing low-valent vanadium complexes
  作者：Yasutaka Kataoka、Isamu Makihira、Hiroaki Akiyama、Kazuhide Tani

  DOI：10.1016/s0040-4020(97)00632-7

  日期：1997.7

  Direct geminal diallylation of a carbonyl compound with allyl bromide has been achieved in the presence of a low-valent vanadium complex and zinc. The diallylation has been found to proceed stepwise and the two allyl groups were introduced successively. By applying this method, one-pot synthesis of asymmetric quaternary carbons has been accomplished. As the first alkylating reagent a combination of allyl bromide and zinc, a Grignard reagent, or an alkyllithium can be used. The second one should be the combination of a low-valent vanadium(II) complex and allyl bromide, benzyl bromide, or propargyl bromide. Strong oxophilicity of the low-valent vanadium facilitated the deoxygenative allylation. (C) 1997 Elsevier Science Ltd.
• Bis(fluorosulfuryl)imide: a Brönsted Acid Catalyst for the Coupling of Allylic and Benzylic Alcohols With Allyltrimethylsilane
  作者：Gurmeet Kaur、Monica Kaushik、Sanjay Trehan*

  DOI：10.1016/s0040-4039(97)00390-0

  日期：1997.4

  The Bronsted acid HN(SO2F)(2) catalyses the reaction of allylic and benzylic alcohols with allyltrimethylsilane to give the corresponding coupled products in good yields. (C) 1997 Published by Elsevier Science Ltd.
• MURAKAMI MASAHIRO; KATO TAKASHI; MUKAIYAMA TERUAKI, CHEM. LETT.,(1987) N 6, 1167-1170
  作者：MURAKAMI MASAHIRO、 KATO TAKASHI、 MUKAIYAMA TERUAKI

  DOI：——

  日期：——