N,N-Bis-(p-diphenylaminophenyl)anilin | 38257-56-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-Bis-(p-diphenylaminophenyl)anilin
• 英文别名: 1-N,1-N,4-N-triphenyl-4-N-[4-(N-phenylanilino)phenyl]benzene-1,4-diamine
• CAS: 38257-56-6
• 化学式: C₄₂H₃₃N₃
• 分子量: 579.744
• InChiKey: QTKPRQHNPOHEAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.6
• 重原子数：
  45
• 可旋转键数：
  9
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  硫酸 、 三苯胺 、 苯甲醛 生成 N,N-Bis-(p-diphenylaminophenyl)anilin
  参考文献：
  名称：

  Haeussermann, Chemische Berichte, 1906, vol. 39, p. 2764

  摘要：

  DOI：

文献信息

• LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AUTHENTICATION DEVICE, AND ELECTRONIC APPARATUS
  申请人：SEIKO EPSON CORPORATION

  公开号：US20170141337A1

  公开（公告）日：2017-05-18

  To provide a light-emitting element which emits light in a near-infrared range and has high efficiency and long life, and a light-emitting device, an authentication device, and an electronic apparatus, each of which includes this light-emitting element. A light-emitting element 1 of the invention includes an anode 3 , a cathode 8 , a light-emitting layer 5 which is provided between the anode 3 and the cathode 8 and emits light in a wavelength range of 700 nm or more by applying a current between the anode 3 and the cathode 8 , and an electron transport layer 6 which is provided between the light-emitting layer 5 and the cathode 8 , and includes a first electron transport layer 6 b located on the cathode 8 side and a second electron transport layer 6 a located on the light-emitting layer 5 side, wherein the first electron transport layer 6 b contains a first anthracene-based compound, which has an anthracene skeleton and a nitrogen-containing heterocyclic skeleton, and has an average thickness of less than 8 nm, and the second electron transport layer 6 a contains a second anthracene-based compound, which has an anthracene skeleton but does not have a heterocyclic skeleton.

  为提供一个在近红外范围内发光并具有高效率和长寿命的发光元件，以及包括该发光元件的发光器件、认证器件和电子设备。该发明的发光元件包括阳极、阴极、位于阳极和阴极之间的发光层，在施加阳极和阴极之间的电流时，在700纳米或更长波长范围内发光，以及位于发光层和阴极之间的电子传输层，包括位于阴极侧的第一电子传输层和位于发光层侧的第二电子传输层。第一电子传输层包含第一蒽衍生物，具有蒽骨架和含氮杂环骨架，并且平均厚度小于8纳米；第二电子传输层包含第二蒽衍生物，具有蒽骨架但没有杂环骨架。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE AND ORGANIC ELECTROLUMINESCENT DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：US20170033289A1

  公开（公告）日：2017-02-02

  A material for an organic electroluminescent device, represented by Formula 1, and an organic electroluminescent device including the same. The material for an organic electroluminescent device according to an embodiment of the present disclosure may be a triamine derivative in which the nitrogen atoms are connected (e.g., coupled) via the meta ring positions of L 1 and L 2 linkers, which may be represented by Formula 2. When the material for an organic EL device according to an embodiment of the present disclosure is used in a hole transport layer adjacent to an emission layer, the charge transport properties may be improved, and the lifetime of the organic EL device may be increased.

  一种用于有机电致发光器件的材料，由公式1表示，以及包括该材料的有机电致发光器件。根据本公开的实施例，用于有机电致发光器件的材料可以是一种三胺衍生物，其中氮原子通过L1和L2连接器的甲基环位置连接（例如偶联），可以用公式2表示。当根据本公开的实施例使用有机EL器件的材料作为紧邻发射层的空穴传输层时，可以提高电荷传输性能，并延长有机EL器件的寿命。
• AROMATIC AMINE DERIVATIVE, AND ORGANIC ELECTROLUMINESCENCE ELEMENT USING THE SAME
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2011790A1

  公开（公告）日：2009-01-07

  Provided are a novel aromatic amine derivative having a specific structure and an organic electroluminescence device in which an organic thin layer comprising a single layer or plural layers including a light emitting layer is interposed between a cathode and an anode, wherein at leas one layer of the above organic thin layer contains the aromatic amine derivative described above in the form of a single component or a mixed component. Thus, the organic electroluminescence device is less liable to be crystallized in molecules, improved in a yield in producing the organic electroluminescence device and extended in a lifetime.

  本发明提供了一种具有特定结构的新型芳香胺衍生物和一种有机电致发光器件，其中在阴极和阳极之间插入了由单层或包括发光层的多层组成的有机薄层，上述有机薄层中至少有一层以单组分或混合组分的形式含有上述芳香胺衍生物。这样，有机电致发光器件就不易在分子中结晶，提高了生产有机电致发光器件的产量，并延长了使用寿命。
• Light-emitting device, electronic apparatus, and inspection method
  申请人：Seiko Epson Corporation

  公开号：US10367148B2

  公开（公告）日：2019-07-30

  To provide a light-emitting element which emits light in a near-infrared region and has high efficiency and long life, and a light-emitting device, an authentication device, and an electronic apparatus, each of which includes this light-emitting element. A light-emitting device 100 of the invention includes a light-emitting element 1A including an anode 3, a cathode 8, and a light-emitting layer 5 which is provided between the anode 3 and the cathode 8 and emits light in a near-infrared region by applying a current between the anode 3 and the cathode 8, wherein the device emits visible light with a luminance of 5 cd/m2 or more when a current is applied between the anode 3 and the cathode 8 at a current density of 300 A/cm2 or less.

  本发明旨在提供一种在近红外区域发光且效率高、寿命长的发光元件，以及包括该发光元件的发光装置、认证装置和电子设备。 本发明的一种发光器件 100 包括一个发光元件 1A，其中包括阳极 3、阴极 8 和发光层 5，发光层 5 设置在阳极 3 和阴极 8 之间，通过在阳极 3 和阴极 8 之间施加电流而在近红外区域发光，其中，当在阳极 3 和阴极 8 之间施加电流，电流密度为 300 A/cm2 或更低时，该器件发出亮度为 5 cd/m2 或更高的可见光。
• Light-emitting element, light-emitting device, authentication device, and electronic apparatus
  申请人：Seiko Epson Corporation

  公开号：US10431761B2

  公开（公告）日：2019-10-01

  To provide a light-emitting element which emits light in a near-infrared range and has high efficiency and long life, and a light-emitting device, an authentication device, and an electronic apparatus, each of which includes this light-emitting element. A light-emitting element 1 of the invention includes an anode 3, a cathode 8, a light-emitting layer 5 which is provided between the anode 3 and the cathode 8 and emits light in a wavelength range of 700 nm or more by applying a current between the anode 3 and the cathode 8, and an electron transport layer 6 which is provided between the light-emitting layer 5 and the cathode 8, and includes a first electron transport layer 6b located on the cathode 8 side and a second electron transport layer 6a located on the light-emitting layer 5 side, wherein the first electron transport layer 6b contains a first anthracene-based compound, which has an anthracene skeleton and a nitrogen-containing heterocyclic skeleton, and has an average thickness of less than 8 nm, and the second electron transport layer 6a contains a second anthracene-based compound, which has an anthracene skeleton but does not have a heterocyclic skeleton.

  提供一种能在近红外范围内发光且效率高、寿命长的发光元件，以及包括该发光元件的发光装置、认证装置和电子设备。 本发明的发光元件 1 包括阳极 3、阴极 8、发光层 5，发光层 5 设置在阳极 3 和阴极 8 之间，通过在阳极 3 和阴极 8 之间施加电流，发光层 5 发出波长范围在 700 纳米以上的光、在发光层 5 和阴极 8 之间设置的电子传输层 6，包括位于阴极 8 侧的第一电子传输层 6b 和位于发光层 5 侧的第二电子传输层 6a、其中，第一电子传输层 6b 含有第一蒽基化合物，该化合物具有蒽骨架和含氮杂环骨架，且平均厚度小于 8 纳米；第二电子传输层 6a 含有第二蒽基化合物，该化合物具有蒽骨架，但不具有杂环骨架。