1,4,7-triazacycloundecane dimer | 60563-32-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,4,7-triazacycloundecane dimer
• 英文别名: 1,4,7-triazacycloundecane
• CAS: 60563-32-8
• 化学式: C₈H₁₉N₃
• 分子量: 157.259
• InChiKey: DBUYWLRSTCZRIX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.1
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 1,4,7-triazacycloundecane dimer 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 以78.5%的产率得到1,4,7-trimethyl-1,4,7-triazacycloundecane
  参考文献：
  名称：

  Synthesis of lipophilic triazacycloalkanes and their platinum(II) complexes

  摘要：

  A series of cyclic lipophilic polyamines: 1,4,7-triethyl-1,4,7-triazacyclodecane, 1,4,7-triethyl-1,4,7-triazacycloundecane, 1,4,7-trimethyl-1,4,7-triazacycloundecane, and 1,4,8-triisopropyl-1,4,8-triazacycloundecane, as well as their complexes with dimethylplatinum(II) were synthesized for the first time. Features of complex formation of triazacyclanes with platinum and their manifestation in NMR spectra were discussed.

  DOI：

  10.1134/s1070363206100239
• 作为产物：
  描述：

  1,4,7-Tris-(4-methylphenyl)sulfonyl-1,4,7-triazacycloundecane 在 氢溴酸 、 溶剂黄146 、 苯酚 作用下， 以 水 为溶剂， 反应 24.0h， 生成 1,4,7-triazacycloundecane dimer
  参考文献：
  名称：

  Gao, Jinzhang; He, Hui; Zhang, Xuan, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2002, vol. 41, # 2, p. 372 - 375

  摘要：

  DOI：

文献信息

• Synthesis and Copper(I) Complexes of a Series of 9- to 13-Membered N₃Macrocycles
  作者：Markus Briellmann、Susan Kaderli、Charles J. Meyer、Andreas D. Zuberbühler

  DOI：10.1002/hlca.19870700318

  日期：1987.5.6

  hexaamines have been isolated and characterized as major by-products. The complexation of Cu(I) by the triamines has been studied potentiometrically in CH3CN/H2O. All ligands L form ternary complexes [Cu(CH3CN)L]+. The corresponding association constants vary between 1011 and 107, decreasing with increasing ring size. In addition, complexes [Cu(CH3CN)yLH]2+, y = 1 or 2, are found as less important species

  通过对甲苯磺酸法合成了8个环大小在9至13之间的环状三胺。开链三胺双（2-氨基乙基）胺（dien）和双（3-氨基丙基）胺（二丙醇）用作起始原料。在某些情况下，相应的二聚环己胺已被分离出来并表征为主要副产物。已经在CH 3 CN / H 2 O中对三胺与Cu（I）的络合物进行了电位分析。所有配体L形成三元络合物[Cu（CH 3 CN）L] +。相应的缔合常数在10 11和10 7之间变化，随环尺寸的增加而减小。此外，络合物[Cu（CH 3 CN）y LH] 2 +， y = 1或2，是次重要的物种，最大浓度为7％至50％。
• High performance laundry powder unit dose and methods of making the same
  申请人：Korex Canada Company

  公开号：US10316277B2

  公开（公告）日：2019-06-11

  A unit dose laundry composition includes from 1 wt. % to 10 wt. % of one or more coated enzymes, from 1 wt. % to 40 wt. % of a bleach composition comprising an oxidizing agent and one or more bleach activators, from 15 wt. % to 80 wt. % of a surfactant composition, and one or more of an alkaline compound, a detergent builder, a chelant, or a polymer composition. The unit dose laundry composition is in the form of a powder, which has a bulk density of from 500 g/L to 1300 g/L, encapsulated a polymer film. A method of making the unit dose laundry composition includes combining one or more liquid active components with one or more high absorbing solid active components to produce a powder intermediate which may be blended with other solid components.

  一种单位剂量的洗衣组合物包括 1 重量份至 10 重量份的一种或多种包衣酶、1 重量份至 40 重量份的漂白组合物（包括氧化剂和一种或多种漂白活化剂）、15 重量份至 80 重量份的表面活性剂组合物，以及一种或多种碱性化合物、洗涤剂增效剂、螯合剂或聚合物组合物。单位剂量的洗衣组合物为粉末状，其体积密度为 500 克/升至 1300 克/升，并包裹一层聚合物薄膜。制造单位剂量洗衣组合物的方法包括将一种或多种液体活性成分与一种或多种高吸收性固体活性成分混合，生产出粉末中间体，该粉末中间体可与其他固体成分混合。
• Graham, Paul G.; Weatherburn, David C., Australian Journal of Chemistry, 1984, vol. 37, p. 2243 - 2248
  作者：Graham, Paul G.、Weatherburn, David C.

  DOI：——

  日期：——
• LAUNDRY DETERGENT
  申请人：Unilever IP Holdings B.V.

  公开号：EP3740554B1

  公开（公告）日：2021-10-13
• High Performance Laundry Powder Unit Dose and Methods of Making the Same
  申请人：Korex Canada Company

  公开号：US20170175056A1

  公开（公告）日：2017-06-22

  A unit dose laundry composition includes from 1 wt. % to 10 wt. % of one or more coated enzymes, from 1 wt. % to 40 wt. % of a bleach composition comprising an oxidizing agent and one or more bleach activators, from 15 wt. % to 80 wt. % of a surfactant composition, and one or more of an alkaline compound, a detergent builder, a chelant, or a polymer composition. The unit dose laundry composition is in the form of a powder, which has a bulk density of from 500 g/L to 1300 g/L, encapsulated a polymer film. A method of making the unit dose laundry composition includes combining one or more liquid active components with one or more high absorbing solid active components to produce a powder intermediate which may be blended with other solid components.